Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids

Fan, Fei; Wang, Weiyu; Holt, Adam P.; Feng, Hongbo; Uhrig, David; Lu, Xinyi; Hong, Tao; Wang, Yangyang; Kang, Nam-Goo; Mays, Jimmy; Sokolov, Alexei P.

doi:10.1021/acs.macromol.6b00714

Title: Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids

Journal Article · Tue Jun 07 00:00:00 EDT 2016 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.6b00714· OSTI ID:1271895

Fan, Fei ^[1]; Wang, Weiyu ^[2]; Holt, Adam P. ^[1]; Feng, Hongbo ^[1]; Uhrig, David ^[2]; Lu, Xinyi ^[1]; Hong, Tao ^[1]; Wang, Yangyang ^[2]; Kang, Nam-Goo ^[1]; Mays, Jimmy ^[3]; Sokolov, Alexei P. ^[4]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States) ; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States) ; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The unique properties of ionic liquids (ILs) have made them promising candidates for electrochemical applications. Polymerization of the corresponding ILs results in a new class of materials called polymerized ionic liquids (PolyILs). Though PolyILs offer the possibility to combine the high conductivity of ILs and the high mechanical strength of polymers, their conductivities are typically much lower than that of the corresponding small molecule ILs. In this study, seven PolyILs were synthesized having degrees of polymerization ranging from 1 to 333, corresponding to molecular weights (MW) from 482 to 160 400 g/mol. Depolarized dynamic light scattering, broadband dielectric spectroscopy, rheology, and differential scanning calorimetry were employed to systematically study the influence of MW on the mechanism of ionic transport and segmental dynamics in these materials. Finally, the modified Walden plot analysis reveals that the ion conductivity transforms from being closely coupled with structural relaxation to being strongly decoupled from it as MW increases.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Temperature Materials Lab. (HTML)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1271895

Journal Information:: Macromolecules, Vol. 49, Issue 12; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 108 works

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References (88)

Effect of cation structure on the electrochemical and thermal properties of ion conductive polymers obtained from polymerizable ionic liquids Ogihara, Wataru; Washiro, Satoko; Nakajima, Hiromitsu Electrochimica Acta, Vol. 51, Issue 13 https://doi.org/10.1016/j.electacta.2005.07.043	journal	March 2006
Viscoelastic Behavior of the Polymerized Ionic Liquid Poly(1-ethyl-3-vinylimidazolium bis(trifluoromethanesulfonylimide)) Nakamura, Kenji; Saiwaki, Tatsuya; Fukao, Koji Macromolecules, Vol. 44, Issue 19 https://doi.org/10.1021/ma201611q	journal	October 2011
On the concept of ionicity in ionic liquids MacFarlane, Douglas R.; Forsyth, Maria; Izgorodina, Ekaterina I. Physical Chemistry Chemical Physics, Vol. 11, Issue 25 https://doi.org/10.1039/b900201d	journal	January 2009
Protic Ionic Liquids: Preparation, Characterization, and Proton Free Energy Level Representation ^† Belieres, Jean-Philippe; Angell, C. Austen The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067589u	journal	May 2007
Solvent-Free Electrolytes with Aqueous Solution-Like Conductivities Xu, W. Science, Vol. 302, Issue 5644 https://doi.org/10.1126/science.1090287	journal	October 2003
Development of new class of ion conductive polymers based on ionic liquids Ohno, Hiroyuki; Yoshizawa, Masahiro; Ogihara, Wataru Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.01.091	journal	November 2004
The Glass Transition Temperature of Polymer Melts ^† Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F. The Journal of Physical Chemistry B, Vol. 109, Issue 45 https://doi.org/10.1021/jp0523266	journal	November 2005
Entropy theory of polymer glass formation revisited. I. General formulation Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F. The Journal of Chemical Physics, Vol. 124, Issue 6 https://doi.org/10.1063/1.2166391	journal	February 2006
The glass temperature and related properties of polystyrene. Influence of molecular weight Fox, Thomas G.; Flory, Paul J. Journal of Polymer Science, Vol. 14, Issue 75 https://doi.org/10.1002/pol.1954.120147514	journal	September 1954
Polymer Electrolytes: The Key to Lithium Polymer Batteries Scrosati, B.; Vincent, C. A. MRS Bulletin, Vol. 25, Issue 3 https://doi.org/10.1557/mrs2000.15	journal	March 2000
Recent Advances in Innovative Polymer Electrolytes based on Poly(ionic liquid)s Shaplov, Alexander S.; Marcilla, Rebeca; Mecerreyes, David Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.038	journal	September 2015
Transport Properties of the Solid Polymer Electrolyte System P(EO) _n LiTFSI Edman, Ludvig; Doeff, Marca M.; Ferry, Anders The Journal of Physical Chemistry B, Vol. 104, Issue 15 https://doi.org/10.1021/jp993897z	journal	April 2000
Ionic Liquids: Ion Mobilities, Glass Temperatures, and Fragilities Xu, Wu; Cooper, Emanuel I.; Angell, C. Austen The Journal of Physical Chemistry B, Vol. 107, Issue 25 https://doi.org/10.1021/jp0275894	journal	June 2003
Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process Chiefari, John; Chong, Y. K. (Bill); Ercole, Frances Macromolecules, Vol. 31, Issue 16 https://doi.org/10.1021/ma9804951	journal	August 1998
Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight Fox, Thomas G.; Flory, Paul J. Journal of Applied Physics, Vol. 21, Issue 6 https://doi.org/10.1063/1.1699711	journal	June 1950
Highly ion conductive flexible films composed of network polymers based on polymerizable ionic liquids Washiro, Satoko; Yoshizawa, Masahiro; Nakajima, Hiromitsu Polymer, Vol. 45, Issue 5 https://doi.org/10.1016/j.polymer.2004.01.003	journal	March 2004
Molecular Volume Effects on the Dynamics of Polymerized Ionic Liquids and their Monomers Choi, U. Hyeok; Mittal, Anuj; Price, Terry L. Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2014.12.140	journal	September 2015
Parallel Developments in Aprotic and Protic Ionic Liquids: Physical Chemistry and Applications Angell, C. Austen; Byrne, Nolene; Belieres, Jean-Philippe Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar7001842	journal	November 2007
Correlation between ionic and molecular dynamics in the liquid state of polyethylene oxide/lithium perchlorate complexes Yoshida, Kensuke; Manabe, Hiroyuki; Takahashi, Yoshiyuki Electrochimica Acta, Vol. 57 https://doi.org/10.1016/j.electacta.2011.06.099	journal	December 2011
Dielectric Relaxation Behavior of Polymerized Ionic Liquid Nakamura, Kenji; Saiwaki, Tatsuya; Fukao, Koji Macromolecules, Vol. 43, Issue 14 https://doi.org/10.1021/ma100918e	journal	July 2010
Synthesis of molten salt-type polymer brush and effect of brush structure on the ionic conductivity Yoshizawa, Masahiro; Ohno, Hiroyuki Electrochimica Acta, Vol. 46, Issue 10-11 https://doi.org/10.1016/S0013-4686(00)00777-5	journal	March 2001
Examination of the fundamental relation between ionic transport and segmental relaxation in polymer electrolytes Wang, Yangyang; Fan, Fei; Agapov, Alexander L. Polymer, Vol. 55, Issue 16 https://doi.org/10.1016/j.polymer.2014.06.085	journal	August 2014
Dielectric and Viscoelastic Responses of Imidazolium-Based Ionomers with Different Counterions and Side Chain Lengths Choi, U. Hyeok; Ye, Yuesheng; Salas de la Cruz, David Macromolecules, Vol. 47, Issue 2 https://doi.org/10.1021/ma402263y	journal	January 2014
Alkyl-Substituted N-Vinylimidazolium Polymerized Ionic Liquids: Thermal Properties and Ionic Conductivities Green, Matthew D.; Salas-de la Cruz, David; Ye, Yuesheng Macromolecular Chemistry and Physics, Vol. 212, Issue 23 https://doi.org/10.1002/macp.201100389	journal	October 2011
Poly(1,2,3-triazolium)s: a new class of functional polymer electrolytes Obadia, Mona M.; Drockenmuller, Eric Chemical Communications, Vol. 52, Issue 12 https://doi.org/10.1039/C5CC09861K	journal	January 2016
Variation of Polymer Glass Temperatures with Molecular Weight Boyer, Raymond F. Macromolecules, Vol. 7, Issue 1 https://doi.org/10.1021/ma60037a030	journal	January 1974
Role of Chemical Structure in Fragility of Polymers: A Qualitative Picture Kunal, Kumar; Robertson, Christopher G.; Pawlus, Sebastian Macromolecules, Vol. 41, Issue 19, p. 7232-7238 https://doi.org/10.1021/ma801155c	journal	October 2008
Ionic Liquids: Past, present and future Austen Angell, C.; Ansari, Younes; Zhao, Zuofeng Faraday Discuss., Vol. 154 https://doi.org/10.1039/C1FD00112D	journal	January 2012
Probe Ion Diffusivity Measurements in Salt-in-Polymer Electrolytes: Stokes Radii and the Transport Number Problem McLin, M. G.; Angell, C. A. The Journal of Physical Chemistry, Vol. 100, Issue 4 https://doi.org/10.1021/jp951966d	journal	January 1996
Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids Qin, Qian; McKenna, Gregory B. Journal of Non-Crystalline Solids, Vol. 352, Issue 28-29 https://doi.org/10.1016/j.jnoncrysol.2006.04.014	journal	August 2006
Effect of Polar Interactions on Polymer Dynamics Agapov, Alexander L.; Wang, Yangyang; Kunal, Kumar Macromolecules, Vol. 45, Issue 20 https://doi.org/10.1021/ma301489c	journal	October 2012
Ionicity in ionic liquids: correlation with ionic structure and physicochemical properties Ueno, Kazuhide; Tokuda, Hiroyuki; Watanabe, Masayoshi Physical Chemistry Chemical Physics, Vol. 12, Issue 8 https://doi.org/10.1039/b921462n	journal	January 2010
Decoupling Ionic Conductivity from Structural Relaxation: A Way to Solid Polymer Electrolytes? Agapov, A. L.; Sokolov, A. P. Macromolecules, Vol. 44, Issue 11 https://doi.org/10.1021/ma2001096	journal	June 2011
Effect of Pressure on Decoupling of Ionic Conductivity from Segmental Dynamics in Polymerized Ionic Liquids Wojnarowska, Z.; Knapik, J.; Jacquemin, J. Macromolecules, Vol. 48, Issue 23 https://doi.org/10.1021/acs.macromol.5b02130	journal	November 2015
Developments in Polymer Electrolytes for Lithium Batteries Wright, Peter V. MRS Bulletin, Vol. 27, Issue 8 https://doi.org/10.1557/mrs2002.194	journal	August 2002
Analysis of complex dielectric spectra. I. One-dimensional derivative techniques and three-dimensional modelling Wübbenhorst, Michael; van Turnhout, Jan Journal of Non-Crystalline Solids, Vol. 305, Issue 1-3 https://doi.org/10.1016/S0022-3093(02)01086-4	journal	July 2002
Influence of the anion on the electrical conductivity and glass formation of 1-butyl-3-methylimidazolium ionic liquids Leys, Jan; Rajesh, Ravindran Nair; Menon, Preethy Chirukandath The Journal of Chemical Physics, Vol. 133, Issue 3 https://doi.org/10.1063/1.3455892	journal	July 2010
Frequency-dependent conductivity, relaxation times, and the conductivity/viscosity coupling problem, in polymer-electrolyte solutions: LiClO4 and NaCF3SO3 in PPO 4000 McLin, M. G.; Angell, C. A. Solid State Ionics, Vol. 53-56 https://doi.org/10.1016/0167-2738(92)90286-X	journal	July 1992
Bromide and Hydroxide Conductivity–Morphology Relationships in Polymerized Ionic Liquid Block Copolymers Meek, Kelly M.; Sharick, Sharon; Ye, Yuesheng Macromolecules, Vol. 48, Issue 14 https://doi.org/10.1021/acs.macromol.5b00926	journal	July 2015
Dielectric Relaxation and Viscoelastic Behavior of Polymerized Ionic Liquids with Various Counteranions Nakamura, Kenji; Fukao, Koji; Inoue, Tadashi Macromolecules, Vol. 45, Issue 9 https://doi.org/10.1021/ma300040b	journal	April 2012
Application of the entropy theory of glass formation to poly(α-olefins) Stukalin, Evgeny B.; Douglas, Jack F.; Freed, Karl F. The Journal of Chemical Physics, Vol. 131, Issue 11 https://doi.org/10.1063/1.3216109	journal	September 2009
CHEMISTRY: Ionic Liquids--Solvents of the Future? Rogers, R. D.; Seddon, Kenneth R. Science, Vol. 302, Issue 5646, p. 792-793 https://doi.org/10.1126/science.1090313	journal	October 2003
Ion transport in solvent-free polymers Ratner, Mark A.; Shriver, Duward F. Chemical Reviews, Vol. 88, Issue 1 https://doi.org/10.1021/cr00083a006	journal	January 1988
Synthesis and homopolymerization studies of vinylimidazolium salts Salamone, J. C.; Israel, S. C.; Taylor, P. Polymer, Vol. 14, Issue 12 https://doi.org/10.1016/0032-3861(73)90039-6	journal	December 1973
Galvanostatic bottom-up filling of TSV-like trenches: Choline-based leveler containing two quaternary ammoniums Kim, Myung Jun; Seo, Youngran; Kim, Hoe Chul Electrochimica Acta, Vol. 163 https://doi.org/10.1016/j.electacta.2015.02.173	journal	May 2015
Relaxation in liquids, polymers and plastic crystals — strong/fragile patterns and problems Angell, C. A. Journal of Non-Crystalline Solids, Vol. 131-133 https://doi.org/10.1016/0022-3093(91)90266-9	journal	June 1991
15th anniversary of polymerised ionic liquids Nishimura, Naomi; Ohno, Hiroyuki Polymer, Vol. 55, Issue 16 https://doi.org/10.1016/j.polymer.2014.02.042	journal	August 2014
Ionic Conduction and Dielectric Response of Poly(imidazolium acrylate) Ionomers Choi, U. Hyeok; Lee, Minjae; Wang, Sharon Macromolecules, Vol. 45, Issue 9 https://doi.org/10.1021/ma202784e	journal	April 2012
Phosphonium-based poly(Ionic liquid) membranes: The effect of cation alkyl chain length on light gas separation properties and Ionic conductivity Cowan, Matthew G.; Masuda, Miyuki; McDanel, William M. Journal of Membrane Science, Vol. 498 https://doi.org/10.1016/j.memsci.2015.10.019	journal	January 2016
Room-Temperature Molten Salt Polymers as a Matrix for Fast Ion Conduction Ohno, Hiroyuki; Ito, Kaori Chemistry Letters, Vol. 27, Issue 8 https://doi.org/10.1246/cl.1998.751	journal	August 1998
Ion Conduction in Polymerized Ionic Liquids with Different Pendant Groups Fan, Fei; Wang, Yangyang; Hong, Tao Macromolecules, Vol. 48, Issue 13 https://doi.org/10.1021/acs.macromol.5b00257	journal	June 2015
Detailed comparison of the Williams–Watts and Cole–Davidson functions Lindsey, C. P.; Patterson, G. D. The Journal of Chemical Physics, Vol. 73, Issue 7 https://doi.org/10.1063/1.440530	journal	October 1980
Optimizing the electrochemical performance of imidazolium-based polymeric ionic liquids by varying tethering groups Jia, Zhe; Yuan, Wen; Sheng, Chunjuan Journal of Polymer Science Part A: Polymer Chemistry, Vol. 53, Issue 11 https://doi.org/10.1002/pola.27567	journal	March 2015
Relaxation and Diffusion in Complex Systems Ngai, K. L. Partially Ordered Systems https://doi.org/10.1007/978-1-4419-7649-9	book	January 2011
Lithium Salt Solutions in Mixed Sulfone and Sulfone-Carbonate Solvents: A Walden Plot Analysis of the Maximally Conductive Compositions Lee, Seung-Yul; Ueno, Kazuhide; Angell, C. Austen The Journal of Physical Chemistry C, Vol. 116, Issue 45 https://doi.org/10.1021/jp3067519	journal	November 2012
Comments on the electric modulus function Hodge, I. M.; Ngai, K. L.; Moynihan, C. T. Journal of Non-Crystalline Solids, Vol. 351, Issue 2 https://doi.org/10.1016/j.jnoncrysol.2004.07.089	journal	January 2005
Complexes of alkali metal ions with poly(ethylene oxide) Fenton, D. E.; Parker, J. M.; Wright, P. V. Polymer, Vol. 14, Issue 11 https://doi.org/10.1016/0032-3861(73)90146-8	journal	November 1973
Ionic Transport, Microphase Separation, and Polymer Relaxation in Poly(propylene glycol) and Lithium Perchlorate Mixtures Fan, Fei; Wang, Yangyang; Sokolov, Alexei P. Macromolecules, Vol. 46, Issue 23 https://doi.org/10.1021/ma401238k	journal	November 2013
Viscoelastic Behavior of Polymerized Ionic Liquids with Various Charge Densities Nakamura, Kenji; Fukao, Koji; Inoue, Tadashi Nihon Reoroji Gakkaishi, Vol. 41, Issue 1 https://doi.org/10.1678/rheology.41.21	journal	January 2013
Why many polymers are so fragile Sokolov, A. P.; Novikov, V. N.; Ding, Y. Journal of Physics: Condensed Matter, Vol. 19, Issue 20 https://doi.org/10.1088/0953-8984/19/20/205116	journal	April 2007
Relationship between Ionic Mobility and Segmental Mobility in Polymers in the Liquid State Sasabe, Hiroyuki; Saito, Shogo Polymer Journal, Vol. 3, Issue 5 https://doi.org/10.1295/polymj.3.624	journal	September 1972
Temperature Dependence of Segmental and Terminal Relaxation in Atactic Polypropylene Melts Roland, C. M.; Ngai, K. L.; Santangelo, P. G. Macromolecules, Vol. 34, Issue 18 https://doi.org/10.1021/ma002121p	journal	August 2001
Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C. Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar7000952	journal	November 2007
When Does a Molecule Become a Polymer? Ding, Yifu; Kisliuk, A.; Sokolov, A. P. Macromolecules, Vol. 37, Issue 1 https://doi.org/10.1021/ma035618i	journal	January 2004
Preparation of thermally stable polymer electrolytes from imidazolium-type ionic liquid derivatives Nakajima, Hiromitsu; Ohno, Hiroyuki Polymer, Vol. 46, Issue 25 https://doi.org/10.1016/j.polymer.2005.10.005	journal	November 2005
Anhydrous Proton Transport in Polymerized Ionic Liquid Block Copolymers: Roles of Block Length, Ionic Content, and Confinement Evans, Christopher M.; Sanoja, Gabriel E.; Popere, Bhooshan C. Macromolecules, Vol. 49, Issue 1 https://doi.org/10.1021/acs.macromol.5b02202	journal	December 2015
Design of superionic polymers—New insights from Walden plot analysis Wang, Yangyang; Fan, Fei; Agapov, Alexander L. Solid State Ionics, Vol. 262 https://doi.org/10.1016/j.ssi.2013.09.026	journal	September 2014
Molten salt type polymer electrolytes Ohno, Hiroyuki Electrochimica Acta, Vol. 46, Issue 10-11 https://doi.org/10.1016/S0013-4686(00)00733-7	journal	March 2001
Molecular mobility and Li+ conduction in polyester copolymer ionomers based on poly(ethylene oxide) Fragiadakis, Daniel; Dou, Shichen; Colby, Ralph H. The Journal of Chemical Physics, Vol. 130, Issue 6 https://doi.org/10.1063/1.3063659	journal	February 2009
Self-Diffusion of Supercooled o -Terphenyl near the Glass Transition Temperature Mapes, Marie K.; Swallen, Stephen F.; Ediger, M. D. The Journal of Physical Chemistry B, Vol. 110, Issue 1 https://doi.org/10.1021/jp0555955	journal	January 2006
Superionic solid: composite electrolyte phase – an overview Agrawal, R. C.; Gupta, R. K. Journal of Materials Science, Vol. 34, Issue 6, p. 1131-1162 https://doi.org/10.1023/A:1004598902146	journal	March 1999
Dielectric relaxation behavior of polymerized ionic liquids with various charge densities Nakamura, Kenji; Fukao, Koji Polymer, Vol. 54, Issue 13 https://doi.org/10.1016/j.polymer.2013.04.039	journal	June 2013
Fragility of Glass-Forming Polymer Liquids ^† Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F. The Journal of Physical Chemistry B, Vol. 109, Issue 45 https://doi.org/10.1021/jp053693k	journal	November 2005
Structural Relaxation in Vitreous Materials Moynihan, C. T.; Macedo, P. B.; Montrose, C. J. Annals of the New York Academy of Sciences, Vol. 279, Issue 1 The Glass Tra https://doi.org/10.1111/j.1749-6632.1976.tb39688.x	journal	October 1976
Charge Transport and Glassy Dynamics in Ionic Liquids Sangoro, Joshua R.; Kremer, Friedrich Accounts of Chemical Research, Vol. 45, Issue 4 https://doi.org/10.1021/ar2001809	journal	November 2011
Decoupling charge transport from the structural dynamics in room temperature ionic liquids Griffin, Philip; Agapov, Alexander L.; Kisliuk, Alexander The Journal of Chemical Physics, Vol. 135, Issue 11 https://doi.org/10.1063/1.3638269	journal	September 2011
Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes Mecerreyes, David Progress in Polymer Science, Vol. 36, Issue 12 https://doi.org/10.1016/j.progpolymsci.2011.05.007	journal	December 2011
Segmental Dynamics and Ionic Conduction in Poly(vinyl methyl ether)−Lithium Perchlorate Complexes Zhang, Shihai; Runt, James The Journal of Physical Chemistry B, Vol. 108, Issue 20 https://doi.org/10.1021/jp0499777	journal	May 2004
Anomalous Electrical Conductivity Behavior at Elevated Pressure in the Protic Ionic Liquid Procainamide Hydrochloride Wojnarowska, Z.; Roland, C. M.; Swiety-Pospiech, A. Physical Review Letters, Vol. 108, Issue 1 https://doi.org/10.1103/PhysRevLett.108.015701	journal	January 2012
Self-Catalyzed Degradation of Linear Cationic Poly(2-dimethylaminoethyl acrylate) in Water Truong, Nghia P.; Jia, Zhongfan; Burges, Melinda Biomacromolecules, Vol. 12, Issue 5 https://doi.org/10.1021/bm200219e	journal	May 2011
Design of Ion Conductive Polymers Based on Ionic Liquids Ohno, Hiroyuki Macromolecular Symposia, Vol. 249-250, Issue 1 https://doi.org/10.1002/masy.200750435	journal	April 2007
Ionic liquids as electrolytes Galiński, Maciej; Lewandowski, Andrzej; Stępniak, Izabela Electrochimica Acta, Vol. 51, Issue 26 https://doi.org/10.1016/j.electacta.2006.03.016	journal	August 2006
Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid Sangoro, J.; Iacob, C.; Serghei, A. The Journal of Chemical Physics, Vol. 128, Issue 21 https://doi.org/10.1063/1.2921796	journal	June 2008
Protic Ionic Liquids Based on Decahydroisoquinoline: Lost Superfragility and Ionicity-Fragility Correlation Ueno, Kazuhide; Zhao, Zuofeng; Watanabe, Masayoshi The Journal of Physical Chemistry B, Vol. 116, Issue 1 https://doi.org/10.1021/jp2078727	journal	December 2011
Formation of Glasses from Liquids and Biopolymers Angell, C. A. Science, Vol. 267, Issue 5206 https://doi.org/10.1126/science.267.5206.1924	journal	March 1995
Self-Diffusion of tris -Naphthylbenzene near the Glass Transition Temperature Swallen, Stephen F.; Bonvallet, Paul A.; McMahon, Robert J. Physical Review Letters, Vol. 90, Issue 1 https://doi.org/10.1103/PhysRevLett.90.015901	journal	January 2003
Decoupling of Ionic Transport from Segmental Relaxation in Polymer Electrolytes Wang, Yangyang; Agapov, Alexander L.; Fan, Fei Physical Review Letters, Vol. 108, Issue 8 https://doi.org/10.1103/PhysRevLett.108.088303	journal	February 2012
Über organische Lösungs- und Ionisierungsmittel: III. Teil: Innere Reibung und deren Zusammenhang mit dem Leitvermögen Walden, P. Zeitschrift für Physikalische Chemie, Vol. 55U, Issue 1 https://doi.org/10.1515/zpch-1906-5511	journal	March 1906

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Journal Article · Tue Feb 14 00:00:00 EST 2017 · Journal of Chemical Physics · OSTI ID:1271895

Kumar, Rajeev; Mahalik, Jyoti P.; Bocharova, Vera; +7 more

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids

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