Materials Data on Sb4IrC5ClO5F22 by Materials Project
IrCl(CO)5(Sb2F11)2 crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of ten formaldehyde molecules, two IrCl clusters, and four Sb2F11 clusters. In each IrCl cluster, Ir5+ is bonded in a single-bond geometry to one Cl1- atom. The Ir–Cl bond length is 2.37 Å. Cl1- is bonded in a distorted single-bond geometry to one Ir5+ atom. In each Sb2F11 cluster, there are two inequivalent Sb2+ sites. In the first Sb2+ site, Sb2+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 28°. There are a spread of Sb–F bond distances ranging from 1.89–2.06 Å. In the second Sb2+ site, Sb2+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 28°. There are a spread of Sb–F bond distances ranging from 1.89–2.09 Å. There are eleven inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the seventh F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the eighth F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the ninth F1- site, F1- is bonded in a bent 150 degrees geometry to two Sb2+ atoms. In the tenth F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom. In the eleventh F1- site, F1- is bonded in a single-bond geometry to one Sb2+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1268907
- Report Number(s):
- mp-555612
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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