An air-stable Na3SbS4 superionic conductor prepared by a rapid and economic synthetic procedure

Wang, Hui; Chen, Yan; Hood, Zachary D.; Samuthira Pandian, Amaresh; Keum, Jong Kahk; An, Ke; Sahu, Gayatri; Liang, Chengdu

doi:10.1002/anie.201601546

Title: An air-stable Na₃SbS₄ superionic conductor prepared by a rapid and economic synthetic procedure

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201601546· OSTI ID:1266853

Wang, Hui ^[1]; Chen, Yan ^[1]; Hood, Zachary D. ^[2]; Samuthira Pandian, Amaresh ^[1]; Keum, Jong Kahk ^[1]; An, Ke ^[1]; Sahu, Gayatri ^[1]; Liang, Chengdu ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)

All-solid-state sodium batteries, using abundant sodium resources and solid electrolyte, hold much promise for safe, low cost, large-scale energy storage. To realize the practical applications of all solid Na-ion batteries at ambient temperature, the solid electrolytes are required to have high ionic conductivity, chemical stability, and ideally, easy preparation. Ceramic electrolytes show higher ionic conductivity than polymers, but they often require extremely stringent synthesis conditions, either high sintering temperature above 1000 C or long-time, low-energy ball milling. Herein, we report a new synthesis route for Na₃SbS₄, a novel Na superionic conductor that needs much lower processing temperature below 200 C and easy operation. This new solid electrolyte exhibits a remarkable ionic conductivity of 1.05 mS cm^-1 at 25 °C and is chemically stable under ambient atmosphere. In conclusion, this synthesis process provides unique insight into the current state-of-the-art solid electrolyte preparation and opens new possibilities for the design of similar materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1266853

Journal Information:: Angewandte Chemie (International Edition), Vol. 55, Issue 30; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 163 works

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Title: An air-stable Na3SbS4 superionic conductor prepared by a rapid and economic synthetic procedure

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Title: An air-stable Na₃SbS₄ superionic conductor prepared by a rapid and economic synthetic procedure