Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts

Chuang, S S.C.; Brundage, M A; Balakos, M W

Title: Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts

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Abstract

Carbon monoxide insertion is a key step toward the formation of higher oxygenates on hydroformylation and the Fischer-Tropsch synthesis. Steady-state isotopic transient and in situ infrared have been employed to determine the effect of partial pressure of reactants on the reactivity and the coverages of IR-observable adsorbates and reaction intermediates leading to the formation of propionaldehyde during ethylene hydroformylation on rhodium/silica.

Authors:

Chuang, S S.C.; Brundage, M A; Balakos, M W ^[1]

Univ. of Akron, OH (United States)

Publication Date:: Fri Dec 01 00:00:00 EST 1995

OSTI Identifier:: 126454

Report Number(s):: CONF-950402-
TRN: 95:006086-0438

Resource Type:: Conference

Resource Relation:: Conference: 209. American Chemical Society (ACS) national meeting, Anaheim, CA (United States), 2-6 Apr 1995; Other Information: PBD: 1995; Related Information: Is Part Of 209th ACS national meeting; PB: 2088 p.

Country of Publication:: United States

Language:: English

Subject:: 01 COAL, LIGNITE, AND PEAT; 10 SYNTHETIC FUELS; ALCOHOLS; CHEMICAL PREPARATION; RHODIUM; CATALYTIC EFFECTS; CARBON MONOXIDE; CATALYSTS; ETHYLENE; FISCHER-TROPSCH SYNTHESIS; PARTIAL PRESSURE; REACTION INTERMEDIATES; SILICA; FUELS; CHEMICAL REACTION KINETICS

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                    Chuang, S S.C., Brundage, M A, and Balakos, M W. Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts.  United States: N. p., 1995. 
        Web.

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                    Chuang, S S.C., Brundage, M A, & Balakos, M W. Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts.  United States.

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                    Chuang, S S.C., Brundage, M A, and Balakos, M W. 1995.  
        "Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts".  United States.

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@article{osti_126454,

  title        = {Kinetics and dynamics of heterogeneous hydroformylation Rh catalysts},

  author       = {Chuang, S S.C. and Brundage, M A and Balakos, M W},

  abstractNote = {Carbon monoxide insertion is a key step toward the formation of higher oxygenates on hydroformylation and the Fischer-Tropsch synthesis. Steady-state isotopic transient and in situ infrared have been employed to determine the effect of partial pressure of reactants on the reactivity and the coverages of IR-observable adsorbates and reaction intermediates leading to the formation of propionaldehyde during ethylene hydroformylation on rhodium/silica.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/126454},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Fri Dec 01 00:00:00 EST 1995},

  month        = {Fri Dec 01 00:00:00 EST 1995}

}

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