Influence of Microstructure and Surface Activation of Dual-Phase Membrane Ce 0.8 Gd 0.2 O 2-δ -FeCo 2 O 4 on Oxygen Permeation

Ramasamy, Madhumidha; Baumann, Stefan; Palisaitis, Justinas; Schulze-Küppers, Falk; Balaguer, Maria; Kim, Daejin; Meulenberg, Wilhelm A.; Mayer, Jochim; Bhave, Ramesh; Guillon, Olivier; Bram, Martin; Stevenson, J.

doi:10.1111/jace.13938

Title: Influence of Microstructure and Surface Activation of Dual-Phase Membrane Ce _0.8 Gd _0.2 O _2-δ -FeCo ₂ O ₄ on Oxygen Permeation

Journal Article · Thu Sep 24 00:00:00 EDT 2015 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.13938· OSTI ID:1261498

Ramasamy, Madhumidha ^[1]; Baumann, Stefan ^[1]; Palisaitis, Justinas ^[1]; Schulze-Küppers, Falk ^[1]; Balaguer, Maria ^[1]; Kim, Daejin ^[2]; Meulenberg, Wilhelm A. ^[1]; Mayer, Jochim ^[1]; Bhave, Ramesh ^[3]; Guillon, Olivier ^[1]; Bram, Martin ^[1]; Stevenson, J.

Julich Research Centre (Germany); Julich Aachen Research Alliance (Germany)
Julich Research Centre (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In dual-phase oxygen transport membranes we noticed that there is fast-growing interest in research for oxyfuel combustion process application. One such potential candidate is CGO-FCO (60wt% Ce_0.8Gd_0.2O_2-δ-40wt% FeCo₂O4) identified to provide good oxygen permeation flux with substantial stability in harsh atmosphere. Dense CGO-FCO membranes of 1mm thickness were fabricated by sintering dry pellets pressed from powders synthesized by one-pot method (modified Pechini process) at 1200 degrees C for 10h. Microstructure analysis indicates presence of a third orthorhombic perovskite phase in the sintered composite. We also identified that the spinel phase tends to form an oxygen deficient phase at the grain boundary of spinel and CGO phases. Surface exchange limitation of the membranes was overcome by La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) porous layer coating over the composite. Moreover, the oxygen permeation flux of the CGO-FCO screen printed with a porous layer of 10mthick LSCF is 0.11mL/cm² per minute at 850 degrees C with argon as sweep and air as feed gas at the rates of 50 and 250mL/min.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725; 608524

OSTI ID:: 1261498

Journal Information:: Journal of the American Ceramic Society, Vol. 99, Issue 1; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 37 works

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Assessment of the Effect of Transition Metal Oxide Addition on the Conductivity of Commercial Gd-Doped Ceria Neuhaus, Kerstin; Dolle, Raimund; Wiemhöfer, Hans-Dieter Journal of The Electrochemical Society, Vol. 165, Issue 7 https://doi.org/10.1149/2.1111807jes	journal	January 2018

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