Characteristic Features of Water Dynamics in Restricted Geometries Investigated with Quasi-Elastic Neutron Scattering

Osti, Naresh C.; Mamontov, Eugene; Ramirez-cuesta, A.; Wesolowski, David J.; Diallo, S. O.

doi:10.1016/j.chemphys.2015.11.008

Title: Characteristic Features of Water Dynamics in Restricted Geometries Investigated with Quasi-Elastic Neutron Scattering

Journal Article · Thu Dec 10 00:00:00 EST 2015 · Chemical Physics

DOI:https://doi.org/10.1016/j.chemphys.2015.11.008· OSTI ID:1261371

Osti, Naresh C. ^[1]; Mamontov, Eugene ^[1]; Ramirez-cuesta, A. ^[1]; Wesolowski, David J. ^[1]; Diallo, S. O. ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Ames Lab., Ames, IA (United States)

Understanding the molecular behavior of water in spatially restricted environments is important to better understanding its role in many biological, chemical and geological processes. Here we examine the translational diffusion of water confined to a variety of substrates, from flat surfaces to nanoporous media, in the context of a recently proposed universal scaling law (Chiavazzo 2014) [1]. Using over a dozen previous neutron scattering results, we test the validity of this law, evaluating separately the influence of the hydration amount, and the effects of the size and morphology of the confining medium. Additionally, we investigate the effects of changing instrument resolutions and fitting models on the applicability of this law. Finally, we perform quasi-elastic neutron scattering measurements on water confined inside nanoporous silica to further evaluate this predictive law, in the temperature range 250≤T≤290 K.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261371

Alternate ID(s):: OSTI ID: 1358943

Journal Information:: Chemical Physics, Vol. 465-466; ISSN 0301-0104

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 43 works

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Vibrational dynamics of confined supercooled water Stefanutti, E.; Bove, L. E.; Alabarse, F. G. The Journal of Chemical Physics, Vol. 150, Issue 22 https://doi.org/10.1063/1.5094147	journal	June 2019
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