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Title: Valley excitons in two-dimensional semiconductors

Journal Article · · National Science Review
DOI:https://doi.org/10.1093/nsr/nwu078· OSTI ID:1441158
 [1];  [2];  [3];  [1]
  1. Univ. of Hong Kong (China). Dept. of Physics and Center of Theoretical and Computational Physics
  2. Univ. of Hong Kong (China). Dept. of Physics
  3. Univ. of Washington, Seattle, WA (United States). Dept. of Physics and Dept. of Material Science and Engineering

Monolayer group-VIB transition metal dichalcogenides have recently emerged as a new class of semiconductors in the two-dimensional limit. The attractive properties include: the visible range direct band gap ideal for exploring optoelectronic applications; the intriguing physics associated with spin and valley pseudospin of carriers which implies potentials for novel electronics based on these internal degrees of freedom; the exceptionally strong Coulomb interaction due to the two-dimensional geometry and the large effective masses. The physics of excitons, the bound states of electrons and holes, has been one of the most actively studied topics on these two-dimensional semiconductors, where the excitons exhibit remarkably new features due to the strong Coulomb binding, the valley degeneracy of the band edges, and the valley dependent optical selection rules for interband transitions. Here we give a brief overview of the experimental and theoretical findings on excitons in two-dimensional transition metal dichalcogenides, with focus on the novel properties associated with their valley degrees of freedom.

Research Organization:
Univ. of Washington, Seattle, WA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
Grant/Contract Number:
SC0008145; AC05-00OR22725
OSTI ID:
1441158
Alternate ID(s):
OSTI ID: 1261335
Journal Information:
National Science Review, Vol. 2, Issue 1; ISSN 2095-5138
Publisher:
China Science PublishingCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 233 works
Citation information provided by
Web of Science

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Cited By (57)

Ultrafast Laser Spectroscopy of Two-Dimensional Materials Beyond Graphene journal December 2016
Spatial variations of valley splitting in monolayer transition metal dichalcogenide journal November 2019
Dynamics of Free and Localized Excitons in Two‐Dimensional Transition Metal Dichalcogenides journal February 2019
Recent Advances in Quantum Effects of 2D Materials journal April 2019
Simulation of Transition Metal Dichalcogenides book January 2019
Valleytronics in transition metal dichalcogenides materials journal August 2019
Valleytronics in 2D materials journal August 2016
Directional interlayer spin-valley transfer in two-dimensional heterostructures journal December 2016
Coulomb engineering of the bandgap and excitons in two-dimensional materials journal May 2017
Direct measurement of exciton valley coherence in monolayer WSe2 journal February 2016
Diversity of trion states and substrate effects in the optical properties of an MoS2 monolayer journal December 2017
Negative circular polarization emissions from WSe2/MoSe2 commensurate heterobilayers journal April 2018
Evidence for line width and carrier screening effects on excitonic valley relaxation in 2D semiconductors journal July 2018
The valley Zeeman effect in inter- and intra-valley trions in monolayer WSe2 journal May 2019
Interlayer valley excitons in heterobilayers of transition metal dichalcogenides journal August 2018
Spin-polarized electrons in monolayer MoS2 journal March 2019
Dark trions and biexcitons in WS2 and WSe2 made bright by e-e scattering journal April 2017
Robust room temperature valley polarization in monolayer and bilayer WS 2 journal January 2016
Unveiling exceptionally robust valley contrast in AA- and AB-stacked bilayer WS 2 journal January 2019
Strong interfacial interactions induced a large reduction in lateral thermal conductivity of transition-metal dichalcogenide superlattices journal January 2019
Band gap temperature-dependence and exciton-like state in copper antimony sulphide, CuSbS 2 journal August 2018
Influence of Coulomb interaction effect on the electrical transport for few-layered PtSe 2 films journal December 2019
Spin–flip processes and radiative decay of dark intravalley excitons in transition metal dichalcogenide monolayers journal August 2016
Brightened spin-triplet interlayer excitons and optical selection rules in van der Waals heterobilayers journal May 2018
Probing the exciton k-space dynamics in monolayer tungsten diselenides journal March 2019
Charged excitons in two-dimensional transition metal dichalcogenides: Semiclassical calculation of Berry curvature effects journal September 2019
Multiphonon Raman scattering mediated by the exciton states in monolayer transition metal chalcogenides journal September 2019
Two-dimensional spin-valley locking spin valve journal October 2019
Ultrafast dynamics of bright and dark positive trions for valley polarization in monolayer WS e 2 journal June 2019
Transient exciton-polariton dynamics in WSe 2 by ultrafast near-field imaging journal February 2019
Guiding and binding of cavity photons with patterned two-dimensional semiconductors journal January 2018
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Coherent steering of nonlinear chiral valley photons with a synthetic Au–WS2 metasurface journal April 2019
Room-temperature exciton-polaritons with two-dimensional WS2 journal September 2016
Negative effective excitonic diffusion in monolayer transition metal dichalcogenides journal January 2020
Optically dark excitonic states mediated exciton and biexciton valley dynamics in monolayer WSe 2 journal June 2018
Auger recombination of dark excitons in WS 2 and WSe 2 monolayers journal August 2016
2D materials advances: from large scale synthesis and controlled heterostructures to improved characterization techniques, defects and applications journal December 2016
Valley polarized relaxation and upconversion luminescence from Tamm-plasmon trion–polaritons with a MoSe 2 monolayer journal May 2017
Magnetic field mixing and splitting of bright and dark excitons in monolayer MoSe 2 journal November 2019
Valley polarized current and resonant electronic transport in a nonuniform MoS 2 zigzag nanoribbon journal February 2020
Coulomb engineering of the bandgap and excitons in two-dimensional materials text January 2017
Exciton Diffusion and Halo Effects in Monolayer Semiconductors text January 2018
Dark-exciton valley dynamics in transition metal dichalcogenide alloy monolayers journal March 2019
Coulomb engineering of the bandgap and excitons in two-dimensional materials text January 2017
Self-energy effect and Coulomb potential modulation of the exciton in monolayer MoS 2 on polar substrate journal October 2017
Valley qubit in a gated MoS 2 monolayer quantum dot journal April 2018
Valley dynamics of different trion species in monolayer WSe 2 journal August 2019
Laser Synthesis, Processing, and Spectroscopy of Atomically-Thin Two Dimensional Materials book January 2018
Exciton-phonon relaxation bottleneck and radiative decay of thermal exciton reservoir in two-dimensional materials text January 2016
Directional Interlayer Spin-Valley Transfer in Two-Dimensional Heterostructures text January 2016
Brightened spin-triplet interlayer excitons and optical selection rules in van der Waals heterobilayers text January 2018
Exciton diffusion and halo effects in monolayer semiconductors text January 2018
Charged exctions in two-dimensional transition-metal dichalcogenides - semiclassical calculation of Berry-curvature effects text January 2018

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