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Title: Electrochemical fluorination for processing of used nuclear fuel

Patent ·
OSTI ID:1260245

A galvanic cell and methods of using the galvanic cell is described for the recovery of uranium from used nuclear fuel according to an electrofluorination process. The galvanic cell requires no input energy and can utilize relatively benign gaseous fluorinating agents. Uranium can be recovered from used nuclear fuel in the form of gaseous uranium compound such as uranium hexafluoride, which can then be converted to metallic uranium or UO.sub.2 and processed according to known methodology to form a useful product, e.g., fuel pellets for use in a commercial energy production system.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States). Savannah River Technology Center (SRTC)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC09-08SR22470
Assignee:
Savannah River Nuclear Solutions, LLC (Aiken, SC)
Patent Number(s):
9,382,632
Application Number:
14/312,098
OSTI ID:
1260245
Resource Relation:
Patent File Date: 2014 Jun 23
Country of Publication:
United States
Language:
English

References (29)

Fluoride Volatility Process for the Recovery of Uranium patent April 1958
Electrolysis of Thorium and Uranium patent September 1960
Method of Irreversibly Darkening a Bis (p-Aminophenyl) Vinyl Carbonium Poly-Methine Leuco Dye patent September 1966
Process for Recovering Palladium from Acid Solutions patent December 1966
Irradiated Nuclear Fuel Recovery patent December 1967
Process for the electrolytic reduction of fissionable elements patent April 1975
Electrochemical cell with alkali and alkaline earth metal containing electrolyte patent January 1977
Irradiated fuel reprocessing patent March 1977
Potentiostat for use with electrochemical cells patent October 1980
Process and apparatus for continuously producing multivalent metals patent June 1985
Electrolysis cell for reprocessing plutonium reactor fuel patent June 1986
Dendrite inhibitor patent August 1989
Electrorefining process and apparatus for recovery of uranium and a mixture of uranium and plutonium from spent fuels patent November 1989
Apparatus and process for the electrolytic reduction of uranium and plutonium oxides patent February 1991
Process and apparatus for recovery of fissionable materials from spent reactor fuel by anodic dissolution patent April 1991
Process for the selective electrofluorination of alloys or metallic mixtures based on uranium patent August 1994
Recovery of UO.sub.2 /Pu O.sub.2 in IFR electrorefining process patent October 1994
Electrochemical method of producing eutectic uranium alloy and apparatus patent January 1995
Method and apparatus of treating waste from nuclear fuel handling facility patent October 2001
Method of treating waste from nuclear fuel handling facility and apparatus for carrying out the same patent May 2004
Apparatus for generating fluorine gas patent November 2004
Method for reprocessing spent nuclear fuel patent February 2007
Porous membrane electrochemical cell for uranium and transuranic recovery from molten salt electrolyte patent September 2007
Method of reprocessing spent nuclear fuel patent November 2008
Uranium dioxide electrolysis patent December 2009
Gas diffusion electrode material and production method thereof patent October 2012
Ionic liquids as templating agents in formation of uranium-containing nanomaterials patent June 2014
Electrolytic systems and methods for making metal halides and refining metals patent May 2015
Electrochemical cell for metal production patent-application June 2005