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Title: Formulation and preparation of Hanford Waste Treatment Plant direct feed low activity waste Effluent Management Facility core simulant

Abstract

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Melter Off-Gas Condensate, LMOGC) from the off-gas system. The baseline plan for disposition of this stream during full WTP operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. However, during the Direct Feed LAW (DFLAW) scenario, planned disposition of this stream is to evaporate it in a new evaporator in the Effluent Management Facility (EMF) and then return it to the LAW melter. It is important to understand the composition of the effluents from the melter and new evaporator so that the disposition of these streams can be accurately planned and accommodated. Furthermore, alternate disposition of the LMOGC stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Alternate disposition would also eliminate this stream from recycling within WTP when it begins operations and would decrease the LAW vitrification mission duration and quantity of glass waste, amongst the other problems such a recycle stream present. This LAW Melter Off-Gasmore » Condensate stream will contain components that are volatile at melter temperatures and are problematic for the glass waste form, such as halides and sulfate. Because this stream will recycle within WTP, these components accumulate in the Melter Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Diverting the stream reduces the halides and sulfate in the recycled Condensate and is a key outcome of this work. This overall program examines the potential treatment and immobilization of this stream to enable alternative disposal. The objective of this task was to formulate and prepare a simulant of the LAW Melter Off-gas Condensate expected during DFLAW operations. That simulant can be used in evaporator testing to predict the composition of the effluents from the Effluent Management Facility (EMF) evaporator to aid in planning for their disposition. This document describes the method used to formulate a simulant of this LAW Melter Off-Gas Condensate stream, which, after pH adjustment, is the feed to the evaporator in the EMF.« less

Authors:
 [1];  [2];  [2]
  1. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
  2. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL
Publication Date:
Research Org.:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1256684
Report Number(s):
SRNL-STI-2016-00313
TRN: US1700213
DOE Contract Number:  
AC09-08SR22470
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; WASTE FORMS; RADIOACTIVE WASTE PROCESSING; EVAPORATORS; HALIDES; SULFATES; GLASS; VITRIFICATION; EVAPORATION; OFF-GAS SYSTEMS; OPERATION; PLANNING; TESTING; HANFORD RESERVATION; RADIOACTIVE WASTE FACILITIES; LOW-LEVEL RADIOACTIVE WASTES; SIMULATION; RADIOACTIVE EFFLUENTS

Citation Formats

McCabe, Daniel J., Nash, Charles A., and Adamson, Duane J. Formulation and preparation of Hanford Waste Treatment Plant direct feed low activity waste Effluent Management Facility core simulant. United States: N. p., 2016. Web. doi:10.2172/1256684.
McCabe, Daniel J., Nash, Charles A., & Adamson, Duane J. Formulation and preparation of Hanford Waste Treatment Plant direct feed low activity waste Effluent Management Facility core simulant. United States. https://doi.org/10.2172/1256684
McCabe, Daniel J., Nash, Charles A., and Adamson, Duane J. 2016. "Formulation and preparation of Hanford Waste Treatment Plant direct feed low activity waste Effluent Management Facility core simulant". United States. https://doi.org/10.2172/1256684. https://www.osti.gov/servlets/purl/1256684.
@article{osti_1256684,
title = {Formulation and preparation of Hanford Waste Treatment Plant direct feed low activity waste Effluent Management Facility core simulant},
author = {McCabe, Daniel J. and Nash, Charles A. and Adamson, Duane J.},
abstractNote = {The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Melter Off-Gas Condensate, LMOGC) from the off-gas system. The baseline plan for disposition of this stream during full WTP operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. However, during the Direct Feed LAW (DFLAW) scenario, planned disposition of this stream is to evaporate it in a new evaporator in the Effluent Management Facility (EMF) and then return it to the LAW melter. It is important to understand the composition of the effluents from the melter and new evaporator so that the disposition of these streams can be accurately planned and accommodated. Furthermore, alternate disposition of the LMOGC stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Alternate disposition would also eliminate this stream from recycling within WTP when it begins operations and would decrease the LAW vitrification mission duration and quantity of glass waste, amongst the other problems such a recycle stream present. This LAW Melter Off-Gas Condensate stream will contain components that are volatile at melter temperatures and are problematic for the glass waste form, such as halides and sulfate. Because this stream will recycle within WTP, these components accumulate in the Melter Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Diverting the stream reduces the halides and sulfate in the recycled Condensate and is a key outcome of this work. This overall program examines the potential treatment and immobilization of this stream to enable alternative disposal. The objective of this task was to formulate and prepare a simulant of the LAW Melter Off-gas Condensate expected during DFLAW operations. That simulant can be used in evaporator testing to predict the composition of the effluents from the Effluent Management Facility (EMF) evaporator to aid in planning for their disposition. This document describes the method used to formulate a simulant of this LAW Melter Off-Gas Condensate stream, which, after pH adjustment, is the feed to the evaporator in the EMF.},
doi = {10.2172/1256684},
url = {https://www.osti.gov/biblio/1256684}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun May 01 00:00:00 EDT 2016},
month = {Sun May 01 00:00:00 EDT 2016}
}