A comparative study of N2O formation during the selective catalytic reduction of NOx with NH3 on zeolite supported Cu catalysts

Chen, Hai-Ying; Wei, Zhehao; Kollar, Marton; Gao, Feng; Wang, Yilin; Szanyi, Janos; Peden, Charles H. F.

doi:10.1016/j.jcat.2015.06.016

Title: A comparative study of N2O formation during the selective catalytic reduction of NOx with NH3 on zeolite supported Cu catalysts

Journal Article · Tue Sep 01 00:00:00 EDT 2015 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2015.06.016· OSTI ID:1252812

Chen, Hai-Ying; Wei, Zhehao; Kollar, Marton; Gao, Feng; Wang, Yilin; Szanyi, Janos; Peden, Charles H. F.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI ID:: 1252812

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Vol. 329 Journal Issue: C; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 105 works

Citation information provided by
Web of Science

References (40)

Activity, propene poisoning resistance and hydrothermal stability of copper exchanged chabazite-like zeolite catalysts for SCR of NO with ammonia in comparison to Cu/ZSM-5 Ye, Qing; Wang, Lifeng; Yang, Ralph T. Applied Catalysis A: General, Vol. 427-428 https://doi.org/10.1016/j.apcata.2012.03.026	journal	June 2012
Interaction of NH ₃ with Cu-SSZ-13 Catalyst: A Complementary FTIR, XANES, and XES Study Giordanino, Filippo; Borfecchia, Elisa; Lomachenko, Kirill A. The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500241m	journal	April 2014
The State of the Art in Selective Catalytic Reduction of NO _x by Ammonia Using Metal‐Exchanged Zeolite Catalysts Brandenberger, Sandro; Kröcher, Oliver; Tissler, Arno Catalysis Reviews, Vol. 50, Issue 4 https://doi.org/10.1080/01614940802480122	journal	December 2008
Selective catalytic reduction of NOx over acid-leached mordenite catalysts Andersson, Lars A. H.; Brandin, Jan G. M.; Odenbrand, C. U. Ingemar Catalysis Today, Vol. 4, Issue 2 https://doi.org/10.1016/0920-5861(89)85049-7	journal	January 1989
Identification of the active Cu site in standard selective catalytic reduction with ammonia on Cu-SSZ-13 Bates, Shane A.; Verma, Anuj A.; Paolucci, Christopher Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.004	journal	April 2014
Current Understanding of Cu-Exchanged Chabazite Molecular Sieves for Use as Commercial Diesel Engine DeNOx Catalysts Gao, Feng; Kwak, Ja Hun; Szanyi, Janos Topics in Catalysis, Vol. 56, Issue 15-17 https://doi.org/10.1007/s11244-013-0145-8	journal	August 2013
Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction Borfecchia, E.; Lomachenko, K. A.; Giordanino, F. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02907K	journal	January 2015
Dealumination of zeolites II. Kinetic study of the dealumination by hydrothermal treatment of a NH4NaY zeolite*1 Wang, Q. Journal of Catalysis, Vol. 130, Issue 2 https://doi.org/10.1016/0021-9517(91)90128-Q	journal	August 1991
Kinetic Studies of Reduction of Nitric Oxide with Ammonia on Cu2+-Exchanged Zeolites Komatsu, T.; Nunokawa, M.; Moon, I. S. Journal of Catalysis, Vol. 148, Issue 2 https://doi.org/10.1006/jcat.1994.1229	journal	August 1994
The ammonia selective catalytic reduction activity of copper-exchanged small-pore zeolites Fickel, Dustin W.; D’Addio, Elizabeth; Lauterbach, Jochen A. Applied Catalysis B: Environmental, Vol. 102, Issue 3-4 https://doi.org/10.1016/j.apcatb.2010.12.022	journal	February 2011
In situ DRIFTS and temperature-programmed technology study on NH3-SCR of NO over Cu-SSZ-13 and Cu-SAPO-34 catalysts Ma, Lei; Cheng, Yisun; Cavataio, Giovanni Applied Catalysis B: Environmental, Vol. 156-157 https://doi.org/10.1016/j.apcatb.2014.03.048	journal	September 2014
Nature of active species in copper-based catalysts and their chemistry of transformation of nitrogen oxides Centi, Gabriele; Perathoner, Siglinda Applied Catalysis A: General, Vol. 132, Issue 2 https://doi.org/10.1016/0926-860X(95)00154-9	journal	November 1995
Catalytic activity of transition metal ion exchanged Y zeolites in the reduction of nitric oxide with ammonia Seiyama, T. Journal of Catalysis, Vol. 48, Issue 1-3 https://doi.org/10.1016/0021-9517(77)90072-0	journal	June 1977
Catalytic reduction of nitrogen oxides on mordenite some aspect on the mechanism Brandin, Jan G. M.; Andersson, Lars A. H.; Odenbrand, C. U. Ingemar Catalysis Today, Vol. 4, Issue 2 https://doi.org/10.1016/0920-5861(89)85050-3	journal	January 1989
The role of pore size on the thermal stability of zeolite supported Cu SCR catalysts Blakeman, Philip G.; Burkholder, Eric M.; Chen, Hai-Ying Catalysis Today, Vol. 231 https://doi.org/10.1016/j.cattod.2013.10.047	journal	August 2014
Inhibitory effect of NO2 on the selective catalytic reduction of NOx with NH3 over one-pot-synthesized Cu–SSZ-13 catalyst Xie, Lijuan; Liu, Fudong; Liu, Kuo Catalysis Science & Technology, Vol. 4, Issue 4 https://doi.org/10.1039/c3cy00924f	journal	January 2014
Identification of Neutral and Charged N _x O _y Surface Species by IR Spectroscopy Hadjiivanov, Konstantin I. Catalysis Reviews, Vol. 42, Issue 1-2 https://doi.org/10.1081/CR-100100260	journal	May 2000
91. The decomposition of ammonium nitrate Shah, Madhavlal Sukhlal; Oza, Trambaklal Mohanlal Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9320000725	journal	January 1932
Mechanistic study of the low temperature activity of transition metal exchanged zeolite SCR catalysts Fedeyko, Joseph M.; Chen, Bin; Chen, Hai-Ying Catalysis Today, Vol. 151, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.12.015	journal	June 2010
Copper Coordination in Cu-SSZ-13 and Cu-SSZ-16 Investigated by Variable-Temperature XRD Fickel, Dustin W.; Lobo, Raul F. The Journal of Physical Chemistry C, Vol. 114, Issue 3 https://doi.org/10.1021/jp9105025	journal	December 2009
Detailed kinetic modeling of the NH3–NO/NO2 SCR reactions over a commercial Cu-zeolite catalyst for Diesel exhausts after treatment Colombo, Massimo; Nova, Isabella; Tronconi, Enrico Catalysis Today, Vol. 197, Issue 1 https://doi.org/10.1016/j.cattod.2012.09.002	journal	December 2012
The origin of N2O formation in the selective catalytic reduction of NOx by NH3 in O2 rich atmosphere on Cu-faujasite catalysts Delahay, Gerard; Coq, Bernard; Kieger, Stephane Catalysis Today, Vol. 54, Issue 4 https://doi.org/10.1016/S0920-5861(99)00206-0	journal	December 1999
Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites Kwak, Ja Hun; Tran, Diana; Burton, Sarah D. Journal of Catalysis, Vol. 287 https://doi.org/10.1016/j.jcat.2011.12.025	journal	March 2012
Reaction Pathway Investigation on the Selective Catalytic Reduction of NO with NH ₃ over Cu/SSZ-13 at Low Temperatures Su, Wenkang; Chang, Huazhen; Peng, Yue Environmental Science & Technology, Vol. 49, Issue 1 https://doi.org/10.1021/es503430w	journal	December 2014
The role of NO in the mechanism of reduction with ammonia over a BaNa?Y catalyst Yeom, Y.; Henao, J.; Li, M. Journal of Catalysis, Vol. 231, Issue 1 https://doi.org/10.1016/j.jcat.2005.01.014	journal	April 2005
Evidence for homolytic decomposition of ammonium nitrate at high temperature Brower, K. R.; Oxley, Jimmie C.; Tewari, Mohan The Journal of Physical Chemistry, Vol. 93, Issue 10 https://doi.org/10.1021/j100347a033	journal	May 1989
Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios Giordanino, Filippo; Vennestrøm, Peter N. R.; Lundegaard, Lars F. Dalton Transactions, Vol. 42, Issue 35 https://doi.org/10.1039/c3dt50732g	journal	January 2013
In situ DRIFTS-MS studies on the oxidation of adsorbed NH3 by NOx over a Cu-SSZ-13 zeolite Zhu, Haiyang; Kwak, Ja Hun; Peden, Charles H. F. Catalysis Today, Vol. 205 https://doi.org/10.1016/j.cattod.2012.08.043	journal	April 2013
Copper ion-exchanged zeolite catalysts in deNOx reaction Yahiro, Hidenori; Iwamoto, Masakazu Applied Catalysis A: General, Vol. 222, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00823-7	journal	December 2001
The relation between deactivation of CuZSM-5 in the selective reduction of NO and dealumination of the zeolite Grinsted, R. A.; Jen, H. -W.; Montreuil, C. N. Zeolites, Vol. 13, Issue 8 https://doi.org/10.1016/0144-2449(93)90130-U	journal	November 1993
In-situ DRIFTS measurements for the mechanistic study of NO oxidation over a commercial Cu-CHA catalyst Ruggeri, Maria Pia; Nova, Isabella; Tronconi, Enrico Applied Catalysis B: Environmental, Vol. 166-167 https://doi.org/10.1016/j.apcatb.2014.10.076	journal	May 2015
N2O formation in the selective catalytic reduction of NOx with NH3 at low temperature on CuO-supported monolithic catalysts Suarez, S.; Martin, J.; Yates, M. Journal of Catalysis, Vol. 229, Issue 1 https://doi.org/10.1016/j.jcat.2004.10.019	journal	January 2005
Rearrangement of Cationic Sites in Cuh-ZSM-5 and Reactivity Loss upon High-Temperature Calcination and Steam Aging Kucherov, A. V.; Hubbard, C. P.; Shelef, M. Journal of Catalysis, Vol. 157, Issue 2 https://doi.org/10.1006/jcat.1995.1325	journal	December 1995
A Consistent Reaction Scheme for the Selective Catalytic Reduction of Nitrogen Oxides with Ammonia Janssens, Ton V. W.; Falsig, Hanne; Lundegaard, Lars F. ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/cs501673g	journal	March 2015
Influence of Crystallinity of HZSM-5 Zeolite on Its Dealumination Rate Sano, T.; Ikeya, H.; Kasuno, T. Zeolites, Vol. 19, Issue 1 https://doi.org/10.1016/S0144-2449(97)00052-3	journal	July 1997
The effect of NO2 on the activity of fresh and aged zeolite catalysts in the NH3-SCR reaction Rahkamaa-Tolonen, Katariina; Maunula, Teuvo; Lomma, Mari Catalysis Today, Vol. 100, Issue 3-4 https://doi.org/10.1016/j.cattod.2004.09.056	journal	February 2005
Cu–SSZ-39, an active and hydrothermally stable catalyst for the selective catalytic reduction of NOx Moliner, Manuel; Franch, Cristina; Palomares, Eduardo Chemical Communications, Vol. 48, Issue 66 https://doi.org/10.1039/c2cc33992g	journal	January 2012
Characterization of Cu-SSZ-13 NH3 SCR catalysts: an in situ FTIR study Szanyi, János; Kwak, Ja Hun; Zhu, Haiyang Physical Chemistry Chemical Physics, Vol. 15, Issue 7 https://doi.org/10.1039/c2cp43467a	journal	January 2013
The effect of Cu-loading on different reactions involved in NH3-SCR over Cu-BEA catalysts Mihai, Oana; Widyastuti, Catur R.; Andonova, Stanislava Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.11.016	journal	March 2014
Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NOx with NH3 Kwak, Ja Hun; Tonkyn, Russell G.; Kim, Do Heui Journal of Catalysis, Vol. 275, Issue 2 https://doi.org/10.1016/j.jcat.2010.07.031	journal	October 2010

Similar Records

A Comparative Study of N2O Formation during the Selective Catalytic Reduction of NOx with NH3 on Zeolite Supported Cu Catalysts

Journal Article · Tue Sep 01 00:00:00 EDT 2015 · Journal of Catalysis, 329:490-498 · OSTI ID:1252812

Chen, Hai-Ying; Wei, Zhehao; Kollar, Marton; +4 more

Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts

Journal Article · Tue Jan 01 00:00:00 EST 2013 · Topics in Catalysis · OSTI ID:1252812

Brookshear, D. William; Nguyen, Ke; Toops, Todd J; +2 more

Low Absorption Vitreous Carbon Reactors for Operando XAS: A Case Study on Cu/Zeolites for Selective Catalytic Reduction of NOx by NH3

Journal Article · Sun Jan 01 00:00:00 EST 2012 · Phys. Chem. Chem. Phys. · OSTI ID:1252812

Kispersky, Vincent F.; Kropf, A. Jeremy; Ribeiro, Fabio H.; +1 more

Title: A comparative study of N2O formation during the selective catalytic reduction of NOx with NH3 on zeolite supported Cu catalysts

Citation Formats

References (40)

Similar Records

Related Subjects