Adsorption of small hydrocarbons on rutile TiO2(110)

Chen, Long; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

doi:10.1016/j.susc.2015.11.002

Title: Adsorption of small hydrocarbons on rutile TiO₂(110)

Journal Article · Sat Nov 21 00:00:00 EST 2015 · Surface Science

DOI:https://doi.org/10.1016/j.susc.2015.11.002· OSTI ID:1251558

Chen, Long ^[1]; Smith, R. Scott ^[1]; Kay, Bruce D. ^[1]; Dohnalek, Zdenek ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Here, temperature programmed desorption and molecular beam scattering were used to study the adsorption and desorption of small hydrocarbons (n-alkanes, 1-alkenes and 1-alkynes of C₁–C₄) on rutile TiO₂(110). We show that the sticking coefficients for all the hydrocarbons are close to unity (> 0.95) at an adsorption temperature of 60 K. The desorption energies for hydrocarbons of the same chain length increase from n-alkanes to 1-alkenes and to 1-alkynes. This trend is likely a consequence of additional dative bonding of the alkene and alkyne π system to the coordinatively unsaturated Ti_5c sites. Similar to previous studies on the adsorption of n-alkanes on metal and metal oxide surfaces, we find that the desorption energies within each group (n-alkanes vs. 1-alkenes vs. 1-alkynes) from Ti_5c sites increase linearly with the chain length. The absolute saturation coverages of each hydrocarbon on Ti_5c sites were also determined. The saturation coverage of CH₄, is found to be ~ 2/3 monolayer (ML). The saturation coverages of C₂–C₄ hydrocarbons are found nearly independent of the chain length with values of ~ 1/2 ML for n-alkanes and 1-alkenes and 2/3 ML for 1-alkynes. This result is surprising considering their similar sizes.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: KC0301050-47319; AC05-76RL01830

OSTI ID:: 1251558

Alternate ID(s):: OSTI ID: 1373616

Report Number(s):: PNNL-SA-113158; PII: S003960281500374X

Journal Information:: Surface Science, Vol. 1021, Issue C; ISSN 0039-6028

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 34 works

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References (75)

Oxygen-Activated Combustion of Alkenes on the Pd(100) Surface Guo, Xing-Cai; Madix, Robert J. Journal of the American Chemical Society, Vol. 117, Issue 20 https://doi.org/10.1021/ja00125a013	journal	May 1995
Propene Adsorption on Clean and Oxygen-Covered Au(111) and Au(100) Surfaces Davis, Kent A.; Goodman, D. Wayne The Journal of Physical Chemistry B, Vol. 104, Issue 35 https://doi.org/10.1021/jp001699y	journal	September 2000
Determination of the bonding and orientation of ethylene on palladium(111) by near-edge x-ray absorption fine structure and photoelectron spectroscopy Wang, Lu Ping.; Tysoe, Wilfred T.; Ormerod, R. Mark. The Journal of Physical Chemistry, Vol. 94, Issue 10 https://doi.org/10.1021/j100373a066	journal	May 1990
On the Mechanism for the Hydrogenation of Olefins on Transition-Metal Surfaces: The Chemistry of Ethylene on Pt(111) Zaera, Francisco Langmuir, Vol. 12, Issue 1 https://doi.org/10.1021/la9407020	journal	January 1996
Pathways and kinetics of methane and ethane C–H bond cleavage on PdO(101) Antony, Abbin; Asthagiri, Aravind; Weaver, Jason F. The Journal of Chemical Physics, Vol. 139, Issue 10 https://doi.org/10.1063/1.4819909	journal	September 2013
A comparison of weak molecular adsorption of organic molecules on clean copper and platinum surfaces Sexton, B. A.; Hughes, A. E. Surface Science, Vol. 140, Issue 1 https://doi.org/10.1016/0039-6028(84)90394-7	journal	May 1984
Molecular beam investigation of adsorption kinetics on bulk metal targets: Nitrogen on tungsten King, David A.; Wells, Michael G. Surface Science, Vol. 29, Issue 2 https://doi.org/10.1016/0039-6028(72)90232-4	journal	February 1972
n-alkanes on Pt(111) and on C(0001)∕Pt(111): Chain length dependence of kinetic desorption parameters Tait, Steven L.; Dohnálek, Zdenek; Campbell, Charles T. The Journal of Chemical Physics, Vol. 125, Issue 23 https://doi.org/10.1063/1.2400235	journal	December 2006
The Adsorption Dynamics of Molecular Methane, Propane, and Neopentane on Pd(111): Theory and Experiment ^† Kao, Chia-Ling; Madix, Robert J. The Journal of Physical Chemistry B, Vol. 106, Issue 33 https://doi.org/10.1021/jp020706a	journal	August 2002
Ethene Adsorption, Dehydrogenation and Reaction with Pd(110): Pd as a Carbon ‘Sponge' ^† Bowker, Michael; Morgan, Chris; Perkins, Neil The Journal of Physical Chemistry B, Vol. 109, Issue 6 https://doi.org/10.1021/jp0402232	journal	February 2005
Alkane Trapping onto Structured Alkane Monolayers on Pt(111) at Low Temperature Carlsson, A. F.; Madix, R. J. The Journal of Physical Chemistry B, Vol. 104, Issue 51 https://doi.org/10.1021/jp001655p	journal	December 2000
n-alkanes on MgO(100). II. Chain length dependence of kinetic desorption parameters for small n-alkanes Tait, Steven L.; Dohnálek, Zdenek; Campbell, Charles T. The Journal of Chemical Physics, Vol. 122, Issue 16 https://doi.org/10.1063/1.1883630	journal	April 2005
Enthalpies and Entropies of Adsorption on Well-Defined Oxide Surfaces: Experimental Measurements Campbell, Charles T.; Sellers, Jason R. V. Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300329s	journal	December 2012
Photooxidation and Photodesorption in the Photochemistry of Isobutene on TiO ₂ (110) Henderson, Michael A. The Journal of Physical Chemistry C, Vol. 117, Issue 27 https://doi.org/10.1021/jp404625c	journal	June 2013
Dynamics of molecular adsorption of ethane with platinum(111): a supersonic molecular beam study Arumainayagam, Christopher R.; Schoofs, Gregory R.; McMaster, Mark C. The Journal of Physical Chemistry, Vol. 95, Issue 3 https://doi.org/10.1021/j100156a005	journal	February 1991
Quantification of the selective activation of C–H bonds in short chain alkanes: The reactivity of ethane, propane, isobutane, n ‐butane, and neopentane on Ir(111) Johnson, Dale F.; Weinberg, W. Henry The Journal of Chemical Physics, Vol. 103, Issue 13 https://doi.org/10.1063/1.470463	journal	October 1995
Thermodynamic Investigation of Thin Films of Ethane Adsorbed on Magnesium Oxide Arnold, Thomas; Cook, Richard E.; Larese, J. Z. The Journal of Physical Chemistry B, Vol. 109, Issue 18 https://doi.org/10.1021/jp046065w	journal	May 2005
Propylene on Pt(111) Zaera, Francisco; Chrysostomou, Demetrius Surface Science, Vol. 457, Issue 1-2 https://doi.org/10.1016/S0039-6028(00)00337-X	journal	June 2000
Phenylacetylene on Cu(111): Adsorption Geometry, Interfacial Electronic Structures and Thermal Chemistry Sohn, Y.; Wei, W.; White, J. M. The Journal of Physical Chemistry C, Vol. 111, Issue 13 https://doi.org/10.1021/jp068398u	journal	April 2007
Molecular adsorption and growth of n-butane adlayers on Pt(111) Weaver, Jason F.; Ikai, Masamichi; Carlsson, Anders Surface Science, Vol. 470, Issue 3 https://doi.org/10.1016/S0039-6028(00)00863-3	journal	January 2001
The interaction of ethane, propane, isobutane, and neopentane with the (110) surface of iridium Wittrig, T. S.; Szuromi, P. D.; Weinberg, W. H. The Journal of Chemical Physics, Vol. 76, Issue 6 https://doi.org/10.1063/1.443327	journal	March 1982
Surface Structure and Reactivity in the Cyclization of Acetylene to Benzene with Pd Overlayers and Pd/Au Surface Alloys on Au{111} Baddeley, Christopher J.; Ormerod, R. Mark; Stephenson, Andrew W. The Journal of Physical Chemistry, Vol. 99, Issue 14 https://doi.org/10.1021/j100014a039	journal	April 1995
Adsorption, Desorption, and Displacement Kinetics of H ₂ O and CO ₂ on TiO ₂ (110) Smith, R. Scott; Li, Zhenjun; Chen, Long The Journal of Physical Chemistry B, Vol. 118, Issue 28 https://doi.org/10.1021/jp501131v	journal	April 2014
Structural Sensitivity in the Dissociation of Water on TiO ₂ Single-Crystal Surfaces Henderson, Michael A. Langmuir, Vol. 12, Issue 21 https://doi.org/10.1021/la960360t	journal	January 1996
Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO ₂ (110) Chen, Long; Li, Zhenjun; Smith, R. Scott Journal of the American Chemical Society, Vol. 136, Issue 15 https://doi.org/10.1021/ja500992b	journal	April 2014
Surface diffusion of n ‐alkanes on Ru(001) Brand, J. L.; Arena, M. V.; Deckert, A. A. The Journal of Chemical Physics, Vol. 92, Issue 8 https://doi.org/10.1063/1.458547	journal	April 1990
Physisorption of CO on the MgO(100) Surface ^† Dohnálek, Z.; Kimmel, Greg A.; Joyce, S. A. The Journal of Physical Chemistry B, Vol. 105, Issue 18 https://doi.org/10.1021/jp003174b	journal	May 2001
Geometric structure and chemical bonding of acetylene adsorbed on Cu(110) Öström, H.; Nordlund, D.; Ogasawara, H. Surface Science, Vol. 565, Issue 2-3 https://doi.org/10.1016/j.susc.2004.07.012	journal	September 2004
Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910–2001 Chickos, James S.; Acree, William E. Journal of Physical and Chemical Reference Data, Vol. 31, Issue 2 https://doi.org/10.1063/1.1475333	journal	June 2002
Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO ₂ Surfaces Pang, Chi Lun; Lindsay, Robert; Thornton, Geoff Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300409r	journal	December 2012
Desorption Kinetics and Adlayer Sticking Model of n-Butane, n-Hexane, and n-Octane on Al2O3(0001) Slayton, R. M.; Aubuchon, C. M.; Camis, T. L. The Journal of Physical Chemistry, Vol. 99, Issue 7 https://doi.org/10.1021/j100007a053	journal	February 1995
Temperature independent physisorption kinetics and adsorbate layer compression for Ar adsorbed on Pt(111) Kimmel, Greg A.; Persson, Mats; Dohnálek, Z. The Journal of Chemical Physics, Vol. 119, Issue 13 https://doi.org/10.1063/1.1604111	journal	October 2003
Thermodynamic and Modeling Study of Thin n -Heptane Films Adsorbed on Magnesium Oxide (100) Surfaces Fernández-Cañoto, D.; Larese, J. Z. The Journal of Physical Chemistry C, Vol. 118, Issue 7 https://doi.org/10.1021/jp407651t	journal	February 2014
The surface science of titanium dioxide Diebold, Ulrike Surface Science Reports, Vol. 48, Issue 5-8 https://doi.org/10.1016/S0167-5729(02)00100-0	journal	January 2003
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides Sattler, Jesper J. H. B.; Ruiz-Martinez, Javier; Santillan-Jimenez, Eduardo Chemical Reviews, Vol. 114, Issue 20 https://doi.org/10.1021/cr5002436	journal	August 2014
Multilayer Adsorption of Methane and Chloromethane on the Molybdenum (100) Surface Leuty, Gary M.; Abu-Nada, Ali; Tsige, Mesfin The Journal of Physical Chemistry C, Vol. 116, Issue 27 https://doi.org/10.1021/jp3042445	journal	June 2012
Pentane Adsorbed on MgO(100) Surfaces: A Thermodynamic, Neutron, and Modeling Study Cook, Richard E.; Arnold, Thomas; Strange, Nicholas The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp509129d	journal	December 2014
Energetics and Kinetics of the Physisorption of Hydrocarbons on Au(111) Wetterer, S. M.; Lavrich, D. J.; Cummings, T. The Journal of Physical Chemistry B, Vol. 102, Issue 46 https://doi.org/10.1021/jp982338+	journal	October 1998
Facile C−H Bond Cleavage and Deep Oxidation of Propane on a PdO(101) Thin Film Weaver, Jason F.; Devarajan, Sunil P.; Hakanoglu, Can The Journal of Physical Chemistry C, Vol. 113, Issue 22 https://doi.org/10.1021/jp9013114	journal	May 2009
Van der Waals Radii of Elements Batsanov, S. S. Inorganic Materials, Vol. 37, Issue 9, p. 871-885 https://doi.org/10.1023/A:1011625728803	journal	September 2001
Structural Models and Thermal Desorption Energetics for Multilayer Assemblies of the n -Alkanes on Pt(111) Bishop, Adeana R.; Girolami, Gregory S.; Nuzzo, Ralph G. The Journal of Physical Chemistry B, Vol. 104, Issue 4 https://doi.org/10.1021/jp9926488	journal	January 2000
Pathways for C–H bond cleavage of propane σ-complexes on PdO(101) Antony, Abbin; Asthagiri, Aravind; Weaver, Jason F. Physical Chemistry Chemical Physics, Vol. 14, Issue 35 https://doi.org/10.1039/c2cp41900a	journal	January 2012
Physisorption of N ₂ , O ₂ , and CO on Fully Oxidized TiO ₂ (110) Dohnálek, Zdenek; Kim, Jooho; Bondarchuk, Oleksandr The Journal of Physical Chemistry B, Vol. 110, Issue 12 https://doi.org/10.1021/jp0564905	journal	March 2006
Thermally-driven processes on rutile TiO2(110)-(1×1): A direct view at the atomic scale Dohnálek, Zdenek; Lyubinetsky, Igor; Rousseau, Roger Progress in Surface Science, Vol. 85, Issue 5-8 https://doi.org/10.1016/j.progsurf.2010.03.001	journal	May 2010
Cyclotrimerization of Alkynes on Reduced TiO2(001) Surfaces Pierce, Keith G.; Barteau, Mark A. The Journal of Physical Chemistry, Vol. 98, Issue 14 https://doi.org/10.1021/j100065a052	journal	April 1994
Adsorption Dynamics and Desorption Kinetics of Argon and Methane on MgO(100) ^† Dohnálek, Z.; Smith, R. Scott; Kay, Bruce D. The Journal of Physical Chemistry B, Vol. 106, Issue 33 https://doi.org/10.1021/jp025890e	journal	August 2002
Structure and Dynamics of CO ₂ on Rutile TiO ₂ (110)-1×1 Lin, Xiao; Yoon, Yeohoon; Petrik, Nikolay G. The Journal of Physical Chemistry C, Vol. 116, Issue 50 https://doi.org/10.1021/jp308061j	journal	October 2012
Molecular-Level Insights into Photocatalysis from Scanning Probe Microscopy Studies on TiO ₂ (110) Henderson, Michael A.; Lyubinetsky, Igor Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300315m	journal	December 2012
Conversion of 1,3-Propylene Glycol on Rutile TiO ₂ (110) Chen, Long; Li, Zhenjun; Smith, R. Scott The Journal of Physical Chemistry C, Vol. 118, Issue 40 https://doi.org/10.1021/jp507787m	journal	September 2014
Molecular mechanisms in the cyclotrimerization of acetylene to benzene on palladium (111) Patterson, Charles H.; Lambert, Richard M. The Journal of Physical Chemistry, Vol. 92, Issue 5 https://doi.org/10.1021/j100316a051	journal	March 1988
Thermodynamic Investigation of n -Hexane Thin Films Adsorbed on Magnesium Oxide Yaron, Peter N.; Telling, Mark T. F.; Larese, J. Z. Langmuir, Vol. 22, Issue 17 https://doi.org/10.1021/la060996c	journal	August 2006
High Selectivity for Primary C–H Bond Cleavage of Propane σ-Complexes on the PdO(101) Surface Weaver, Jason F.; Hakanoglu, Can; Antony, Abbin Journal of the American Chemical Society, Vol. 133, Issue 40 https://doi.org/10.1021/ja206599k	journal	October 2011
Scanning Tunneling Microscopy of the RuO ₂ (110) Surface at Ambient Oxygen Pressure Rössler, M.; Günther, S.; Wintterlin, J. The Journal of Physical Chemistry C, Vol. 111, Issue 5 https://doi.org/10.1021/jp065182j	journal	February 2007
Molecular adsorption of small alkanes on a PdO(101) thin film: Evidence of σ-complex formation Weaver, Jason F.; Hakanoglu, Can; Hawkins, Jeffery M. The Journal of Chemical Physics, Vol. 132, Issue 2 https://doi.org/10.1063/1.3277672	journal	January 2010
Selectivity in the initial C–H bond cleavage of n-butane on PdO(101) Hakanoglu, Can; Zhang, Feng; Antony, Abbin Physical Chemistry Chemical Physics, Vol. 15, Issue 29 https://doi.org/10.1039/c3cp50659b	journal	January 2013
Investigation of Cyclooctatetraene on Reduced TiO ₂ (001) as a Possible Intermediate in Alkyne Cyclotrimerization Sherrill, Adrian B.; Lusvardi, Victor S.; Barteau, Mark A. Langmuir, Vol. 15, Issue 22 https://doi.org/10.1021/la990119p	journal	October 1999
The adsorption and reaction of low molecular weight alkanes on metallic single crystal surfaces Weaver, J. Surface Science Reports, Vol. 50, Issue 4-5 https://doi.org/10.1016/S0167-5729(03)00031-1	journal	June 2003
Propane σ-Complexes on PdO(101): Spectroscopic Evidence of the Selective Coordination and Activation of Primary CH Bonds Zhang, Feng; Pan, Li; Choi, Juhee Angewandte Chemie International Edition, Vol. 54, Issue 47 https://doi.org/10.1002/anie.201505237	journal	September 2015
Ethyne Cyclization to Benzene over Cu(110) Lomas, Julian R.; Baddeley, Christopher J.; Tikhov, Mintcho S. Langmuir, Vol. 11, Issue 8 https://doi.org/10.1021/la00008a033	journal	August 1995
Comparison of the Photodesorption Activities of cis -Butene, trans -Butene, and Isobutene on the Rutile TiO ₂ (110) Surface Henderson, Michael A. The Journal of Physical Chemistry C, Vol. 117, Issue 45 https://doi.org/10.1021/jp408426y	journal	October 2013
Conversion of 1,2-Propylene Glycol on Rutile TiO ₂ (110) Chen, Long; Li, Zhenjun; Smith, R. Scott The Journal of Physical Chemistry C, Vol. 118, Issue 28 https://doi.org/10.1021/jp504770f	journal	July 2014
Acetylene Coupling on Cu(111): Formation of Butadiene, Benzene, and Cyclooctatetraene Kyriakou, Georgios; Kim, Jisu; Tikhov, Mintcho S. The Journal of Physical Chemistry B, Vol. 109, Issue 21 https://doi.org/10.1021/jp044213c	journal	June 2005
Ensemble Effects in the Coupling of Acetylene to Benzene on a Bimetallic Surface: A Study with Pd{111}/Au Baddeley, Christopher J.; Tikhov, Mintcho; Hardacre, Christopher The Journal of Physical Chemistry, Vol. 100, Issue 6 https://doi.org/10.1021/jp9517054	journal	January 1996
n-alkanes on MgO(100). I. Coverage-dependent desorption kinetics of n-butane Tait, Steven L.; Dohnálek, Zdenek; Campbell, Charles T. The Journal of Chemical Physics, Vol. 122, Issue 16 https://doi.org/10.1063/1.1883629	journal	April 2005
NEXAFS and TPD studies of molecular adsorption of hydrocarbons on Cu(100): segmental correlations with the heats of adsorption Teplyakov, Andrew V.; Gurevich, Alejandra B.; Yang, Michael X. Surface Science, Vol. 396, Issue 1-3 https://doi.org/10.1016/S0039-6028(97)00688-2	journal	January 1998
Ethylene on Cu( 110 ) and Ni( 110 ): electronic structure and bonding derived from X-ray spectroscopy and theory Öström, H.; Föhlisch, A.; Nyberg, M. Surface Science, Vol. 559, Issue 2-3 https://doi.org/10.1016/j.susc.2004.04.041	journal	June 2004
Cyclotrimerization of sterically hindered alkynes in ultrahigh vacuum: TPD of tert-butylacetylene on the reduced TiO2(001) surface Pierce, Keith G.; Barteau, Mark A. Surface Science, Vol. 326, Issue 3 https://doi.org/10.1016/0039-6028(95)00006-2	journal	March 1995
Bonding and dehydrogenation of ethylene on palladium metal. Vibrational spectra and temperature-programed reaction studies on palladium(100) Stuve, E. M.; Madix, Robert J. The Journal of Physical Chemistry, Vol. 89, Issue 1 https://doi.org/10.1021/j100247a026	journal	January 1985
Adsorption and Cyclotrimerization Kinetics of C ₂ H ₂ at a Cu(110) Surface Öberg, H.; Nestsiarenka, Y.; Matsuda, A. The Journal of Physical Chemistry C, Vol. 116, Issue 17 https://doi.org/10.1021/jp300514f	journal	April 2012
Alkane activation on crystalline metal oxide surfaces Weaver, Jason F.; Hakanoglu, Can; Antony, Abbin Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60420A	journal	January 2014
Adsorption of ethylene on stoichiometric RuO2(110) Paulus, U. A.; Wang, Y.; Bonzel, H. P. Surface Science, Vol. 566-568 https://doi.org/10.1016/j.susc.2004.06.041	journal	September 2004
Determination of Absolute Coverages for Small Aliphatic Alcohols on TiO ₂ (110) Li, Zhenjun; Smith, R. Scott; Kay, Bruce D. The Journal of Physical Chemistry C, Vol. 115, Issue 45 https://doi.org/10.1021/jp208228f	journal	October 2011
Catalytic Reactions of Acetylene: A Feedstock for the Chemical Industry Revisited Trotuş, Ioan-Teodor; Zimmermann, Tobias; Schüth, Ferdi Chemical Reviews, Vol. 114, Issue 3 https://doi.org/10.1021/cr400357r	journal	November 2013
The reaction of saturated and unsaturated hydrocarbons with the (110)‐(1×2) and (111) surfaces of iridium Szuromi, P. D.; Engstrom, J. R.; Weinberg, W. H. The Journal of Chemical Physics, Vol. 80, Issue 1 https://doi.org/10.1063/1.446422	journal	January 1984
Dispersion-corrected density functional theory calculations of the molecular binding of n -alkanes on Pd(111) and PdO(101) Antony, Abbin; Hakanoglu, Can; Asthagiri, Aravind The Journal of Chemical Physics, Vol. 136, Issue 5 https://doi.org/10.1063/1.3679167	journal	February 2012

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