Microstructure, crystallization and shape memory behavior of titania and yttria co-doped zirconia

Zeng, Xiao Mei; Du, Zehui; Schuh, Christopher A.; Tamura, Nobumichi; Gan, Chee Lip

doi:10.1016/j.jeurceramsoc.2015.11.042

Title: Microstructure, crystallization and shape memory behavior of titania and yttria co-doped zirconia

Journal Article · Thu Dec 17 00:00:00 EST 2015 · Journal of the European Ceramic Society

DOI:https://doi.org/10.1016/j.jeurceramsoc.2015.11.042· OSTI ID:1379259

Zeng, Xiao Mei ^[1]; Du, Zehui ^[1]; Schuh, Christopher A. ^[2]; Tamura, Nobumichi ^[3];

^[1]

Nanyang Technological Univ. (Singapore)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Small volume zirconia ceramics with few or no grain boundaries have been demonstrated recently to exhibit the shape memory effect. To explore the shape memory properties of yttria doped zirconia (YDZ), it is desirable to develop large, microscale grains, instead of submicron grains that result from typical processing of YDZ. In this paper, we have successfully produced single crystal micro-pillars from microscale grains encouraged by the addition of titania during processing. Titania has been doped into YDZ ceramics and its effect on the grain growth, crystallization and microscale elemental distribution of the ceramics have been systematically studied. With 5 mol% titania doping, the grain size can be increased up to ~4 μm, while retaining a large quantity of the desired tetragonal phase of zirconia. Finally, micro-pillars machined from tetragonal grains exhibit the expected shape memory effects where pillars made from titania-free YDZ would not.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1379259

Alternate ID(s):: OSTI ID: 1250378

Journal Information:: Journal of the European Ceramic Society, Vol. 36, Issue 5; ISSN 0955-2219

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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