An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Popa, Tiberiu; Zhang, Yulong; Jin, Erlei; Fan, Maohong

doi:10.1016/j.apcata.2015.07.026

Title: An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Journal Article · Tue Sep 01 00:00:00 EDT 2015 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2015.07.026· OSTI ID:1250106

Popa, Tiberiu; Zhang, Yulong; Jin, Erlei; Fan, Maohong

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1250106

Journal Information:: Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Vol. 505 Journal Issue: C; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

Citation Metrics:

Cited by: 37 works

Citation information provided by
Web of Science

References (37)

Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation−Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis Huang, Zhiwei; Cui, Fang; Kang, Haixiao Chemistry of Materials, Vol. 20, Issue 15 https://doi.org/10.1021/cm8006233	journal	August 2008
Study of extraction-oxidation desulfurization of model oil by acidic ionic liquid Zhang, Cun; Wang, Feng; Pan, Xiao-yu Journal of Fuel Chemistry and Technology, Vol. 39, Issue 9 https://doi.org/10.1016/S1872-5813(11)60041-8	journal	September 2011
Unravelling the properties of supported copper oxide: can the particle size induce acidic behaviour? Zaccheria, Federica; Scotti, Nicola; Marelli, Marcello Dalton Trans., Vol. 42, Issue 5 https://doi.org/10.1039/C2DT32454G	journal	January 2013
A new aerogel based CO ₂ adsorbent developed using a simple sol–gel method along with supercritical drying Kong, Yong; Jiang, Guodong; Fan, Maohong Chem. Commun., Vol. 50, Issue 81 https://doi.org/10.1039/C4CC06424K	journal	January 2014
Effect of feedstock solvent on the stability of Cu/SiO ₂ catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol Lin, Jingdong; Zhao, Xiaoqin; Cui, Yunhe Chem. Commun., Vol. 48, Issue 8 https://doi.org/10.1039/C1CC15783C	journal	January 2012
Cu/SiO2 hybrid catalysts containing HZSM-5 with enhanced activity and stability for selective hydrogenation of dimethyl oxalate to ethylene glycol Lin, Haiqiang; Zheng, Xinlei; He, Zhe Applied Catalysis A: General, Vol. 445-446 https://doi.org/10.1016/j.apcata.2012.08.025	journal	November 2012
Reaction processes and mechanism of supercritical transesterification in situ ATR infrared spectrum Chen, Wen; Wang, Cun-wen; Liu, Shao-wen Journal of Fuel Chemistry and Technology, Vol. 39, Issue 11 https://doi.org/10.1016/S1872-5813(11)60047-9	journal	November 2011
Cu/SiO2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol Chen, L.; Guo, P.; Qiao, M. Journal of Catalysis, Vol. 257, Issue 1 https://doi.org/10.1016/j.jcat.2008.04.021	journal	July 2008
The effect of the amount of ammonia on the Cu0/Cu+ ratio of Cu/SiO2 catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol Li, Feng; Lu, Chun-Shan; Li, Xiao-Nian Chinese Chemical Letters, Vol. 25, Issue 11 https://doi.org/10.1016/j.cclet.2014.05.050	journal	November 2014
A nanostructured CeO ₂ promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability Jin, Erlei; He, Leilei; zhang, Yulong RSC Adv., Vol. 4, Issue 90 https://doi.org/10.1039/C4RA08170F	journal	January 2014
Temperature dependent microstructure of MTES modified hydrophobic silica aerogels Cui, Sheng; Liu, Yu; Fan, Mao-hong Materials Letters, Vol. 65, Issue 4 https://doi.org/10.1016/j.matlet.2010.11.026	journal	February 2011
A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions Yue, Hairong; Zhao, Yujun; Zhao, Shuo Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3339	journal	September 2013
Silver-modulated SiO2-supported copper catalysts for selective hydrogenation of dimethyl oxalate to ethylene glycol Huang, Ying; Ariga, Hiroko; Zheng, Xinlei Journal of Catalysis, Vol. 307 https://doi.org/10.1016/j.jcat.2013.07.006	journal	November 2013
Effect of the Cu/SBA-15 catalyst preparation method on methyl acetate hydrogenation for ethanol production Wang, Shurong; Guo, Wenwen; Wang, Haixia New Journal of Chemistry, Vol. 38, Issue 7 https://doi.org/10.1039/c4nj00134f	journal	January 2014
Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol Wen, Chao; Cui, Yuanyuan; Dai, Wei-Lin Chemical Communications, Vol. 49, Issue 45 https://doi.org/10.1039/c3cc40570b	journal	January 2013
Remarkable Improvement of Catalytic Performance for a New Cobalt-Decorated Cu/HMS Catalyst in the Hydrogenation of Dimethyloxalate Wen, Chao; Cui, Yuanyuan; Yin, Anyuan ChemCatChem, Vol. 5, Issue 1 https://doi.org/10.1002/cctc.201200444	journal	October 2012
Highly active and selective copper-containing HMS catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol Yin, Anyuan; Guo, Xiuying; Dai, Wei-Lin Applied Catalysis A: General, Vol. 349, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.07.020	journal	October 2008
Characterization and catalytic performance of sol–gel derived Cu/SiO2 catalysts for hydrogenolysis of diethyl oxalate to ethylene glycol He, Liming; Chen, Xiaochun; Ma, Jingsheng Journal of Sol-Gel Science and Technology, Vol. 55, Issue 3 https://doi.org/10.1007/s10971-010-2247-0	journal	May 2010
Cu/SiO2 Catalysts Prepared by the Sol-Gel Method for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol Lin, Ling; Pan, Pengbin; Zhou, Zhangfeng Chinese Journal of Catalysis, Vol. 32, Issue 6-8 https://doi.org/10.1016/S1872-2067(10)60223-9	journal	January 2011
Ag/MCM-41 as a highly efficient mesostructured catalyst for the chemoselective synthesis of methyl glycolate and ethylene glycol Yin, Anyuan; Wen, Chao; Dai, Wei-Lin Applied Catalysis B: Environmental, Vol. 108-109 https://doi.org/10.1016/j.apcatb.2011.08.013	journal	October 2011
The influence of different precipitants on the copper-based catalysts for hydrogenation of ethyl acetate to ethanol Zhong, Kaili; Wang, Xin International Journal of Hydrogen Energy, Vol. 39, Issue 21 https://doi.org/10.1016/j.ijhydene.2014.05.045	journal	July 2014
Why Urea Eliminates Ammonia Rather than Hydrolyzes in Aqueous Solution Alexandrova, Anastassia N.; Jorgensen, William L. The Journal of Physical Chemistry B, Vol. 111, Issue 4 https://doi.org/10.1021/jp066478s	journal	February 2007
Highly active and selective Cu/SiO2 catalysts prepared by the urea hydrolysis method in dimethyl oxalate hydrogenation Wang, Shurong; Li, Xinbao; Yin, Qianqian Catalysis Communications, Vol. 12, Issue 13 https://doi.org/10.1016/j.catcom.2011.04.019	journal	July 2011
Urea thermolysis studied under flow reactor conditions using DSC and FT-IR Lundström, Andreas; Andersson, Bengt; Olsson, Louise Chemical Engineering Journal, Vol. 150, Issue 2-3 https://doi.org/10.1016/j.cej.2009.03.044	journal	August 2009
Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability Yue, Hairong; Zhao, Yujun; Zhao, Li AIChE Journal, Vol. 58, Issue 9 https://doi.org/10.1002/aic.12785	journal	November 2011
Preparation of silica-supported copper catalysts by means of deposition-precipitation Van Der Grift, C. J. G.; Elberse, P. A.; Mulder, A. Applied Catalysis, Vol. 59, Issue 1 https://doi.org/10.1016/S0166-9834(00)82204-6	journal	March 1990
Icy: an open bioimage informatics platform for extended reproducible research de Chaumont, Fabrice; Dallongeville, Stéphane; Chenouard, Nicolas Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2075	journal	June 2012
The Influence of Copper Particle Dispersion in Cu/SiO2 Catalysts on the Hydrogenation Synthesis of Ethylene Glycol Zhu, Ying-Ying; Wang, Shu-Rong; Zhu, Ling-Jun Catalysis Letters, Vol. 135, Issue 3-4 https://doi.org/10.1007/s10562-010-0298-z	journal	February 2010
Effect of boric oxide doping on the stability and activity of a Cu–SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol He, Zhe; Lin, Haiqiang; He, Ping Journal of Catalysis, Vol. 277, Issue 1 https://doi.org/10.1016/j.jcat.2010.10.010	journal	January 2011
Detection limits in XPS for more than 6000 binary systems using Al and Mg Kα X-rays: XPS detection limits Shard, Alexander G. Surface and Interface Analysis, Vol. 46, Issue 3 https://doi.org/10.1002/sia.5406	journal	February 2014
Metal Particle Size in Silica-Supported Copper Catalysts. Influence of the Conditions of Preparation and of Thermal Pretreatments Toupance, Thierry; Kermarec, Maggy; Louis, Catherine The Journal of Physical Chemistry B, Vol. 104, Issue 5 https://doi.org/10.1021/jp993399q	journal	February 2000
NIH Image to ImageJ: 25 years of image analysis Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W. Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2089	journal	June 2012
Indirect coal to liquid technologies Jin, Erlei; Zhang, Yulong; He, Leilei Applied Catalysis A: General, Vol. 476 https://doi.org/10.1016/j.apcata.2014.02.035	journal	April 2014
Efficient low-temperature selective hydrogenation of esters on bimetallic Au–Ag/SBA-15 catalyst Zheng, Jianwei; Lin, Haiqiang; Wang, Ya-nan Journal of Catalysis, Vol. 297 https://doi.org/10.1016/j.jcat.2012.09.023	journal	January 2013
Cu Nanoparticles Inlaid Mesoporous Al ₂ O ₃ As a High-Performance Bifunctional Catalyst for Ethanol Synthesis via Dimethyl Oxalate Hydrogenation Zhu, Yifeng; Kong, Xiao; Li, Xianqing ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5009283	journal	September 2014
Effect of initial precipitation temperature on the structural evolution and catalytic behavior of Cu/SiO2 catalyst in the hydrogenation of dimethyloxalate Yin, Anyuan; Guo, Xiaoyang; Dai, Wei-Lin Catalysis Communications, Vol. 12, Issue 6 https://doi.org/10.1016/j.catcom.2010.10.030	journal	February 2011
Synthesis of Ethanol via Syngas on Cu/SiO ₂ Catalysts with Balanced Cu ⁰ –Cu ⁺ Sites Gong, Jinlong; Yue, Hairong; Zhao, Yujun Journal of the American Chemical Society, Vol. 134, Issue 34 https://doi.org/10.1021/ja3034153	journal	May 2012

Similar Records

Highly selective and stable Cu/SiO2 catalysts prepared with a green method for hydrogenation of diethyl oxalate into ethylene glycol

Journal Article · Sat Jul 01 00:00:00 EDT 2017 · Applied Catalysis B: Environmental · OSTI ID:1250106

Ding, Jie; Popa, Tiberiu; Tang, Jinke; +3 more

Dimethyl carbonate production via the oxidative carbonylation ofmethanol over Cu/SiO2 catalysts prepared via molecular precursor graftingand chemical vapor deposition approaches

Journal Article · Mon Sep 27 00:00:00 EDT 2004 · Journal of Catalysis · OSTI ID:1250106

Drake, Ian J; Fujdala, Kyle L; Bell, Alexis T; +1 more

DIMETHYL CARBONATE PRODUCTION VIA THE OXIDATIVE CARBONYLATION OF METHANOL OVER CU/SIO2 CATALYSTS PREPARED VIA MOLECULAR PRECURSOR GRAFTING AND CHEMICAL VAPOR DEPOSITION APPROACHES

Journal Article · Sat Jan 01 00:00:00 EST 2005 · J. MED. CHEM. · OSTI ID:1250106

DRAKE, I; FUJDALA, K; BELL, A; +1 more

Title: An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Citation Formats

References (37)

Similar Records

Related Subjects