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Title: Nanosecond formation of diamond and lonsdaleite by shock compression of graphite

Here, the shock-induced transition from graphite to diamond has been of great scientific and technological interest since the discovery of microscopic diamonds in remnants of explosively driven graphite. Furthermore, shock synthesis of diamond and lonsdaleite, a speculative hexagonal carbon polymorph with unique hardness, is expected to happen during violent meteor impacts. Here, we show unprecedented in situ X-ray diffraction measurements of diamond formation on nanosecond timescales by shock compression of pyrolytic as well as polycrystalline graphite to pressures from 19 GPa up to 228 GPa. While we observe the transition to diamond starting at 50 GPa for both pyrolytic and polycrystalline graphite, we also record the direct formation of lonsdaleite above 170 GPa for pyrolytic samples only. Our experiment provides new insights into the processes of the shock-induced transition from graphite to diamond and uniquely resolves the dynamics that explain the main natural occurrence of the lonsdaleite crystal structure being close to meteor impact sites.
 [1] ;  [2] ;  [2] ;  [3] ;  [4] ;  [5] ;  [5] ;  [2] ;  [5] ;  [2] ;  [1] ;  [6] ;  [2] ;  [2] ;  [2] ;  [7] ;  [2] ;  [8] ;  [2] ;  [6] more »;  [1] ;  [2] ;  [5] « less
  1. Univ. of California, Berkeley, CA (United States)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. Univ. of Warwick, Coventry (United Kingdom)
  4. Max-Planck-Institut fur Physik Komplexer Systeme, Dresden (Germany); Institute of Radiation Physics, Dresden (Germany)
  5. Technische Univ. Darmstadt, Darmstadt (Germany)
  6. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  7. Univ. of Oxford, Oxford (United Kingdom)
  8. GSI Helmholtzzentrum fur Schwerionenforschung GmbH, Darmstadt (Germany)
Publication Date:
OSTI Identifier:
Report Number(s):
Journal ID: ISSN 2041-1723; ncomms10970
Grant/Contract Number:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Nature Publishing Group
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
US DOE Office of Science (DOE SC)
Country of Publication:
United States