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Title: Vitrified chemically bonded phosphate ceramics for immobilization of radioisotopes

Patent ·
OSTI ID:1248483

A method of immobilizing a radioisotope and vitrified chemically bonded phosphate ceramic (CBPC) articles formed by the method are described. The method comprises combining a radioisotope-containing material, MgO, a source of phosphate, and optionally, a reducing agent, in water at a temperature of less than 100.degree. C. to form a slurry; curing the slurry to form a solid intermediate CBPC article comprising the radioisotope therefrom; comminuting the intermediate CBPC article, mixing the comminuted material with glass frits, and heating the mixture at a temperature in the range of about 900 to about 1500.degree. C. to form a vitrified CBPC article comprising the radioisotope immobilized therein.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UCHICAGO ARGONNE, LLC (Chicago, IL)
Patent Number(s):
9,305,672
Application Number:
14/291,980
OSTI ID:
1248483
Resource Relation:
Patent File Date: 2014 May 30
Country of Publication:
United States
Language:
English

References (7)

Low-temperature immobilization of actinides and other components of high-level waste in magnesium potassium phosphate matrices journal March 2009
Magnesium potassium phosphate ceramic for 99Tc immobilization journal February 2006
Method of waste stabilization via chemically bonded phosphate ceramics patent November 1998
Phosphate bonded structural products from high volume wastes patent December 1998
Method for producing chemically bonded phosphate ceramics and for stabilizing contaminants encapsulated therein utilizing reducing agents patent October 2000
Method of waste stabilization with dewatered chemically bonded phosphate ceramics patent June 2010
Method of waste stabilization with dewatered chemically bonded phosphate ceramics patent-application October 2006