High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2

Wang, Shichao; Xie, Hong; Lin, Yuyuan; Poeppelmeier, Kenneth R.; Li, Tao; Winans, Randall E.; Cui, Yanran; Ribeiro, Fabio H.; Canlas, Christian P.; Elam, Jeffrey W.; Zhang, Hongbo; Marshall, Christopher L.

doi:10.1021/acs.inorgchem.5b02810

Title: High thermal stability of La₂O₃ and CeO₂-stabilized tetragonal ZrO₂

Journal Article · Mon Feb 15 00:00:00 EST 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.5b02810· OSTI ID:1241300

Wang, Shichao ^[1]; Xie, Hong ^[1]; Lin, Yuyuan ^[1]; Poeppelmeier, Kenneth R. ^[1]; Li, Tao ^[2]; Winans, Randall E. ^[2]; Cui, Yanran ^[3]; Ribeiro, Fabio H. ^[3]; Canlas, Christian P. ^[2]; Elam, Jeffrey W. ^[2]; Zhang, Hongbo ^[2]; Marshall, Christopher L. ^[2]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Purdue Univ., West Lafayette, IN (United States)

Catalyst support materials of tetragonal ZrO₂, stabilized by either La₂O₃ (La₂O₃-ZrO₂) or CeO₂ (CeO₂-ZrO₂), were synthesized under hydrothermal conditions at 200 °C with NH₄OH or tetramethylammonium hydroxide as the mineralizer. From In Situ synchrotron powder X-ray diffraction and small-angle X-ray scattering measurements, the calcined La₂O₃-ZrO₂ and CeO₂-ZrO₂ supports were nonporous nanocrystallites that exhibited rectangular shapes with thermal stability up to 1000 °C in air. These supports had an average size of ~10 nm and a surface area of 59-97 m²/g. The catalysts Pt/La₂O₃-ZrO₂ and Pt/CeO₂-ZrO₂ were prepared by using atomic layer deposition with varying Pt loadings from 6.3-12.4 wt %. Mono-dispersed Pt nanoparticles of ~3 nm were obtained for these catalysts. As a result, the incorporation of La₂O₃ and CeO₂ into the t-ZrO₂ structure did not affect the nature of the active sites for the Pt/ZrO₂ catalysts for the water-gas-shift (WGS) reaction.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1241300

Journal Information:: Inorganic Chemistry, Vol. 55, Issue 5; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ALD
La2O3
CeO2
hydrothermal
stabilized
tetragonal ZrO2
water-gas-shift

Title: High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2

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Title: High thermal stability of La₂O₃ and CeO₂-stabilized tetragonal ZrO₂