Photo-oxidation of polymer-like amorphous hydrogenated carbon under visible light illumination

Baxamusa, Salmaan; Laurence, Ted; Worthington, Matthew; Ehrmann, Paul

doi:10.1016/j.polymdegradstab.2015.11.001

Title: Photo-oxidation of polymer-like amorphous hydrogenated carbon under visible light illumination

Journal Article · Tue Nov 10 00:00:00 EST 2015 · Polymer Degradation and Stability

DOI:https://doi.org/10.1016/j.polymdegradstab.2015.11.001· OSTI ID:1240985

Baxamusa, Salmaan ^[1]; Laurence, Ted ^[1]; Worthington, Matthew ^[1]; Ehrmann, Paul ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Materials Science Division

Amorphous hydrogenated carbon (a-C:H), a polymer-like network typically synthesized by plasma chemical vapor deposition, has long been understood to exhibit optical absorption of visible light (λ > 400 nm). In this report we explain that this absorption is accompanied by rapid photo-oxidation (within minutes) that behaves in most respects like classic polymer photo-oxidation with the exception that it occurs under visible light illumination rather than ultraviolet illumination.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1240985

Alternate ID(s):: OSTI ID: 1260425

Report Number(s):: LLNL-JRNL-677678

Journal Information:: Polymer Degradation and Stability, Vol. 122, Issue C; ISSN 0141-3910

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 11 works

Citation information provided by
Web of Science

References (34)

rf‐plasma deposited amorphous hydrogenated hard carbon thin films: Preparation, properties, and applications Bubenzer, A.; Dischler, B.; Brandt, G. Journal of Applied Physics, Vol. 54, Issue 8 https://doi.org/10.1063/1.332613	journal	August 1983
Amorphous hydrogenated carbon films: effects of nitrogen and fluorine incorporation on the film microstructure and mechanical properties: a review Freire, F. L. Journal of Non-Crystalline Solids, Vol. 304, Issue 1-3 https://doi.org/10.1016/S0022-3093(02)01031-1	journal	June 2002
Properties and structure of amorphous hydrogenated carbon films Mckenzie, D. R.; Mcphedran, R. C.; Savvides, N. Philosophical Magazine B, Vol. 48, Issue 4 https://doi.org/10.1080/13642818308246487	journal	October 1983
Amorphous carbon Robertson, J. Advances in Physics, Vol. 35, Issue 4 https://doi.org/10.1080/00018738600101911	journal	January 1986
Growth mechanism of amorphous hydrogenated carbon von Keudell, A.; Meier, M.; Hopf, C. Diamond and Related Materials, Vol. 11, Issue 3-6 https://doi.org/10.1016/S0925-9635(01)00553-2	journal	March 2002
Structure and Thermal Properties of Thin Film Poly(α-methylstyrene) Deposited via Plasma-Enhanced Chemical Vapor Deposition Burkey, D. D.; Gleason, K. K. Chemical Vapor Deposition, Vol. 9, Issue 2 https://doi.org/10.1002/cvde.200390004	journal	March 2003
Deposition conditions influence the postdeposition oxidation of methyl methacrylate plasma polymer films Gengenbach, Thomas R.; Griesser, Hans J. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 36, Issue 6 https://doi.org/10.1002/(SICI)1099-0518(19980430)36:6<985::AID-POLA14>3.0.CO;2-H	journal	April 1998
A multi-technique study of the spontaneous oxidation of N-hexane plasma polymers Gengenbach, Thomas R.; Vasic, Zoran R.; Chatelier, Ronald C. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 32, Issue 8 https://doi.org/10.1002/pola.1994.080320801	journal	June 1994
Composition and Structural Studies of Strong Glow Discharge Polymer Coatings Czechowicz, D. G.; Castillo, E. R.; Nikroo, A. Fusion Science and Technology, Vol. 41, Issue 3P1 https://doi.org/10.13182/FST41-188	journal	May 2002
Fuel gain exceeding unity in an inertially confined fusion implosion Hurricane, O. A.; Callahan, D. A.; Casey, D. T. Nature, Vol. 506, Issue 7488 https://doi.org/10.1038/nature13008	journal	February 2014
Ultrasmooth plasma polymerized coatings for laser fusion targets Letts, S. A.; Myers, D. W.; Witt, L. A. Journal of Vacuum Science and Technology, Vol. 19, Issue 3 https://doi.org/10.1116/1.571142	journal	September 1981
Review of the National Ignition Campaign 2009-2012 Lindl, John; Landen, Otto; Edwards, John Physics of Plasmas, Vol. 21, Issue 2 https://doi.org/10.1063/1.4865400	journal	February 2014
NIF Ignition Campaign Target Performance and Requirements: Status May 2012 Haan, S. W.; Atherton, J.; Clark, D. S. Fusion Science and Technology, Vol. 63, Issue 2 https://doi.org/10.13182/FST13-TFM20-31	journal	April 2013
Instability growth seeded by oxygen in CH shells on the National Ignition Facility Haan, S. W.; Huang, H.; Johnson, M. A. Physics of Plasmas, Vol. 22, Issue 3 https://doi.org/10.1063/1.4916300	journal	March 2015
Polymer Weathering: Photo-Oxidation Feldman, D. Journal of Polymers and the Environment, Vol. 10, Issue 4, p. 163-173 https://doi.org/10.1023/A:1021148205366	journal	October 2002
Photooxidation of polymers: Relating material properties to chemical changes Larché, J. -F.; Bussière, P. -O.; Thérias, S. Polymer Degradation and Stability, Vol. 97, Issue 1 https://doi.org/10.1016/j.polymdegradstab.2011.10.020	journal	January 2012
Photodegradation and photo-oxidation of synthetic polymers Rånby, Bengt Journal of Analytical and Applied Pyrolysis, Vol. 15 https://doi.org/10.1016/0165-2370(89)85037-5	journal	March 1989
Photo-oxidation of Polymers Synthesized by Plasma and Initiated CVD Baxamusa, Salmaan H.; Suresh, Aravind; Ehrmann, Paul Chemical Vapor Deposition, Vol. 21, Issue 10-11-12 https://doi.org/10.1002/cvde.201507173	journal	November 2015
Fabrication of Polymer Shells Using a Depolymerizable Mandrel Letts, Stephan A.; Fearon, Evelyn M.; Buckley, Steven R. Fusion Technology, Vol. 28, Issue 5 https://doi.org/10.13182/FST28-5-1797	journal	December 1995
Metallic-like photoluminescence and absorption in fused silica surface flaws Laurence, Ted A.; Bude, Jeff D.; Shen, Nan Applied Physics Letters, Vol. 94, Issue 15 https://doi.org/10.1063/1.3119622	journal	April 2009
Quasi-continuum photoluminescence: Unusual broad spectral and temporal characteristics found in defective surfaces of silica and other materials Laurence, Ted A.; Bude, Jeff D.; Shen, Nan Journal of Applied Physics, Vol. 115, Issue 8 https://doi.org/10.1063/1.4866422	journal	February 2014
Plasma chemical vapor deposition of hydrocarbon films: The influence of hydrocarbon source gas on the film properties Schwarz-Selinger, T.; von Keudell, A.; Jacob, W. Journal of Applied Physics, Vol. 86, Issue 7 https://doi.org/10.1063/1.371318	journal	October 1999
IR Absorptive Properties of Plastic Materials Used in ICF Capsules Cook, Robert C.; Anthamatten, Mitchell; Letts, Stephan A. Fusion Science and Technology, Vol. 45, Issue 2 https://doi.org/10.13182/FST04-A442	journal	March 2004
Pulsed plasma polymerization of an aromatic perfluorocarbon monomer: Formation of low dielectric constant, high thermal stability films Han, Licheng M.; Timmons, Richard B.; Lee, Wei W. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 18, Issue 2 https://doi.org/10.1116/1.591279	journal	January 2000
The stability of plasma polymers: Part I, A preliminary XPS study of the photostability of plasma polymerised styrene and methyl methacrylate Potter, W.; Ward, A. J.; Short, R. D. Polymer Degradation and Stability, Vol. 43, Issue 3 https://doi.org/10.1016/0141-3910(94)90010-8	journal	January 1994
Photoluminescence of Hydrogenated Amorphous Carbon Films Watanabe, Ichiro; Hasegawa, Seiichi; Kurata, Yoshihiro Japanese Journal of Applied Physics, Vol. 21, Issue Part 1, No. 6 https://doi.org/10.1143/JJAP.21.856	journal	June 1982
Optical constants of a hydrogenated amorphous carbon film Smith, F. W. Journal of Applied Physics, Vol. 55, Issue 3 https://doi.org/10.1063/1.333135	journal	February 1984
π bands and gap states from optical absorption and electron-spin-resonance studies on amorphous carbon and amorphous hydrogenated carbon films Dasgupta, D.; Demichelis, F.; Pirri, C. F. Physical Review B, Vol. 43, Issue 3 https://doi.org/10.1103/PhysRevB.43.2131	journal	January 1991
The Long-Wavelength Edge of Photographic Sensitivity and of the Electronic Absorption of Solids Urbach, Franz Physical Review, Vol. 92, Issue 5 https://doi.org/10.1103/PhysRev.92.1324	journal	December 1953
Optical Properties and Electronic Structure of Amorphous Germanium Tauc, J.; Grigorovici, R.; Vancu, A. physica status solidi (b), Vol. 15, Issue 2 https://doi.org/10.1002/pssb.19660150224	journal	January 1966
Infrared spectra of H-bonded systems: saturated carboxylic acid dimers Excoffon, P.; Marechal, Y. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 28, Issue 2 https://doi.org/10.1016/0584-8539(72)80251-4	journal	February 1972
Correlation of the Nitrogen 1s and Oxygen 1s XPS Binding Energies with Compositional Changes During Oxidation of Ethylene Diamine Plasma Polymers Gengenbach, Thomas R.; Chatelier, Ronald C.; Griesser, Hans J. Surface and Interface Analysis, Vol. 24, Issue 9 https://doi.org/10.1002/(SICI)1096-9918(19960916)24:9<611::AID-SIA169>3.0.CO;2-7	journal	September 1996
Plasma for Modification of Polymers Yasuda, H. Journal of Macromolecular Science: Part A - Chemistry, Vol. 10, Issue 3 https://doi.org/10.1080/00222337608061190	journal	March 1976
Polymerization of organic compounds in an electrodeless glow discharge. VI. Acetylene with unusual comonomers Yasuda, H.; Marsh, H. C.; Bumgarner, M. O. Journal of Applied Polymer Science, Vol. 19, Issue 10 https://doi.org/10.1002/app.1975.070191020	journal	October 1975

Cited By (1)

Probing the seeding of hydrodynamic instabilities from nonuniformities in ablator materials using 2D velocimetry Ali, S. J.; Celliers, P. M.; Haan, S. Physics of Plasmas, Vol. 25, Issue 9 https://doi.org/10.1063/1.5047943	journal	September 2018

Similar Records

Visible-light-induced instability in amorphous metal-oxide based TFTs for transparent electronics

Journal Article · Wed Oct 15 00:00:00 EDT 2014 · AIP Advances · OSTI ID:1240985

Ha, Tae-Jun

Photo-oxidation of Polymers Synthesized by Plasma and Initiated CVD

Journal Article · Mon Nov 09 00:00:00 EST 2015 · Chemical Vapor Deposition · OSTI ID:1240985

Baxamusa, Salmaan H.; Suresh, Aravind; Ehrmann, Paul; +5 more

Indium oxide thin film as potential photoanodes for corrosion protection of stainless steel under visible light

Journal Article · Thu May 01 00:00:00 EDT 2014 · Materials Research Bulletin · OSTI ID:1240985

Zhang, Yan; Yu, Jianqiang; Sun, Kai; +3 more

Related Subjects

36 MATERIALS SCIENCE
Photo-oxidation
Amorphous hydrogenated carbon
Plasma polymer
Visible light
Aging

Title: Photo-oxidation of polymer-like amorphous hydrogenated carbon under visible light illumination

Citation Formats

References (34)

Cited By (1)

Similar Records

Related Subjects