Cr-doped TiSe2 - A layered dichalcogenide spin glass

Luo, Huixia; Tao, Jing; Krizan, Jason W.; Seibel, Elizabeth M.; Xie, Weiwei; Sahasrabudhe, Girija S.; Bergman, Susanna L.; Phelan, Brendan F.; Wang, Zhen; Zhang, Jiandi; Cava, R. J.

doi:10.1021/acs.chemmater.5b03091

Title: Cr-doped TiSe₂ - A layered dichalcogenide spin glass

Journal Article · Thu Sep 17 00:00:00 EDT 2015 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.5b03091· OSTI ID:1240695

Luo, Huixia ^[1]; Tao, Jing ^[2]; Krizan, Jason W. ^[1]; Seibel, Elizabeth M. ^[1]; Xie, Weiwei ^[1]; Sahasrabudhe, Girija S. ^[1]; Bergman, Susanna L. ^[1]; Phelan, Brendan F. ^[1]; Wang, Zhen ^[3]; Zhang, Jiandi ^[3]; Cava, R. J. ^[1]

Princeton Univ., Princeton, NJ (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Louisiana State Univ., Baton Rouge, LA (United States)

We report the magnetic characterization of the Cr-doped layered dichalcogenide TiSe₂. The temperature dependent magnetic susceptibilities are typical of those seen in geometrically frustrated insulating antiferromagnets. The Cr moment is close to the spin-only value, and the Curie–Weiss temperatures (θ_cw) are between –90 and –230 K. Freezing of the spin system, which is glassy, characterized by peaks in the ac and dc susceptibility and specific heat, does not occur until below T/θ_cw = 0.05. The CDW transition seen in the resistivity for pure TiSe₂ is still present for 3% Cr substitution but is absent by 10% substitution, above which the materials are metallic and p-type. Structural refinements, magnetic characterization, and chemical considerations indicate that the materials are of the type Ti_1–xCr_xSe_2-x/2 for 0 ≤ x ≤ 0.6.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1240695

Report Number(s):: BNL-111838-2016-JA; R&D Project: MA015MACA; KC0201010

Journal Information:: Chemistry of Materials, Vol. 27, Issue 19; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 21 works

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Ti1–xCrxSe2-x/2

Title: Cr-doped TiSe2 - A layered dichalcogenide spin glass

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Title: Cr-doped TiSe₂ - A layered dichalcogenide spin glass