Bifunctional application of sodium cobaltate as a catalyst and captor through CO oxidation and subsequent CO2 chemisorption processes

Vera, Elizabeth; Alcántar-Vázquez, Brenda; Duan, Yuhua; Pfeiffer, Heriberto

doi:10.1039/C5RA22749F

Title: Bifunctional application of sodium cobaltate as a catalyst and captor through CO oxidation and subsequent CO₂ chemisorption processes

Journal Article · Mon Dec 21 00:00:00 EST 2015 · RSC Advances

DOI:https://doi.org/10.1039/C5RA22749F· OSTI ID:1239127

Vera, Elizabeth ^[1]; Alcántar-Vázquez, Brenda ^[1]; Duan, Yuhua ^[2]; Pfeiffer, Heriberto ^[1]

Univ. Nacional Autonoma de Mexico (UNAM), Mexico City (Mexico). Inst. de Investigaciones en Materiales
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

The potential bifunctional mechanism of sodium cobaltate (NaCoO₂) in the catalysis of CO oxidation and subsequent CO₂ chemisorption was systematically analysed. Different catalytic and gravimetric experiments were performed dynamically and isothermally at multiple temperatures. Initially, the CO oxidation process was evaluated using a catalytic reactor connected to a gas chromatograph. Once the production of CO₂ was confirmed, its chemisorption capacity with NaCoO₂ was studied gravimetrically. Catalytic and gravimetric analysis products were studied by XRD, FTIR and SEM to elucidate the double reaction mechanism. Sodium cobaltate exhibited interesting catalytic properties over a wide temperature range, although the NaCoO₂ crystalline structure and chemical composition changed during the CO₂ capture process. Furthermore, all the experiments were theoretically supported by first-principles density functional theory thermodynamic calculations. Finally, the calculated thermodynamic properties of the CO oxidation and CO₂ capture reactions with NaCoO₂ under different oxidation conditions were in good agreement with the experimental measurements.

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

OSTI ID:: 1239127

Report Number(s):: NETL-PUB-20095; RSCACL

Journal Information:: RSC Advances, Vol. 6, Issue 3; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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Title: Bifunctional application of sodium cobaltate as a catalyst and captor through CO oxidation and subsequent CO₂ chemisorption processes