Lignin Depolymerization with Nitrate-Intercalated Hydrotalcite Catalysts

Kruger, Jacob S.; Cleveland, Nicholas S.; Zhang, Shuting; Katahira, Rui; Black, Brenna A.; Chupka, Gina M.; Lammens, Tijs; Hamilton, Phillip G.; Biddy, Mary J.; Beckham, Gregg T.

doi:10.1021/acscatal.5b02062

Title: Lignin Depolymerization with Nitrate-Intercalated Hydrotalcite Catalysts

Journal Article · Wed Jan 13 00:00:00 EST 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.5b02062· OSTI ID:1238322

Kruger, Jacob S. ^[1]; Cleveland, Nicholas S. ^[1]; Zhang, Shuting ^[1]; Katahira, Rui ^[1]; Black, Brenna A. ^[1]; Chupka, Gina M. ^[2]; Lammens, Tijs ^[3]; Hamilton, Phillip G. ^[4]; Biddy, Mary J. ^[1]; Beckham, Gregg T. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States). National Bioenergy Center
National Renewable Energy Lab. (NREL), Golden, CO (United States). Hydrogen and Transportation Systems Center
Shell Global Solutions, Inc., Houston, TX (United States). Shell Technology Center
Shell Global Solutions, Inc., Amsterdam (Netherlands). Shell Technology Center

Hydrotalcites (HTCs) exhibit multiple adjustable parameters to tune catalytic activity, including interlayer anion composition, metal hydroxide layer composition, and catalyst preparation methods. Here in this paper, we report the influence of several of these parameters on β-O-4 bond scission in a lignin model dimer, 2-phenoxy-1-phenethanol (PE), to yield phenol and acetophenone. We find that the presence of both basic and NO₃– anions in the interlayer increases the catalyst activity by 2–3-fold. In contrast, other anions or transition metals do not enhance catalytic activity in comparison to blank HTC. The catalyst is not active for C–C bond cleavage on lignin model dimers and has no effect on dimers without an α-OH group. Most importantly, the catalyst is highly active in the depolymerization of two process-relevant lignin substrates, producing a significant amount of low-molecular-weight aromatic species. The catalyst can be recycled until the NO₃– anions are depleted, after which the activity can be restored by replenishing the NO₃– reservoir and regenerating the hydrated HTC structure. These results demonstrate a route to selective lignin depolymerization in a heterogeneous system with an inexpensive, earth-abundant, commercially relevant, and easily regenerated catalyst.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1238322

Report Number(s):: NREL/JA-5100-65864

Journal Information:: ACS Catalysis, Vol. 6, Issue 2; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 55 works

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