Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes’ effects on thermal & cycling stability

Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; Zhou, Yong-Ning; Yang, Xiao-Qing

doi:10.1088/1674-1056/25/1/018205

Title: Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes’ effects on thermal & cycling stability

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Chinese Physics. B

DOI:https://doi.org/10.1088/1674-1056/25/1/018205· OSTI ID:1237737

Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; Zhou, Yong-Ning; Yang, Xiao-Qing

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - OTHER

OSTI ID:: 1237737

Journal Information:: Chinese Physics. B, Vol. 25, Issue 1; ISSN 1674-1056

Country of Publication:: United States

Language:: ENGLISH

References (67)

Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Evolution of Strategies for Modern Rechargeable Batteries Goodenough, John B. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar2002705	journal	June 2012
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Safety mechanisms in lithium-ion batteries Balakrishnan, P. G.; Ramesh, R.; Prem Kumar, T. Journal of Power Sources, Vol. 155, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.12.002	journal	April 2006
Thermal runaway caused fire and explosion of lithium ion battery Wang, Qingsong; Ping, Ping; Zhao, Xuejuan Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.038	journal	June 2012
Runaway risk of forming toxic compounds Hammami, Amer; Raymond, Nathalie; Armand, Michel Nature, Vol. 424, Issue 6949 https://doi.org/10.1038/424635b	journal	August 2003
Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway Yang, Hui; Bang, Hyunjoo; Amine, Khalil Journal of The Electrochemical Society, Vol. 152, Issue 1 https://doi.org/10.1149/1.1836126	journal	January 2005
Accelerating Rate Calorimetry Study on the Thermal Stability of Lithium Intercalated Graphite in Electrolyte. I. Experimental Richard, M. N. Journal of The Electrochemical Society, Vol. 146, Issue 6 https://doi.org/10.1149/1.1391893	journal	June 1999
Accelerating Rate Calorimetry Study on the Thermal Stability of Lithium Intercalated Graphite in Electrolyte. II. Modeling the Results and Predicting Differential Scanning Calorimeter Curves Richard, M. N. Journal of The Electrochemical Society, Vol. 146, Issue 6 https://doi.org/10.1149/1.1391894	journal	June 1999
Battery performances and thermal stability of polyacrylonitrile nano-fiber-based nonwoven separators for Li-ion battery Cho, Tae-Hyung; Tanaka, Masanao; Onishi, Hiroshi Journal of Power Sources, Vol. 181, Issue 1, p. 155-160 https://doi.org/10.1016/j.jpowsour.2008.03.010	journal	June 2008
Separator technologies for lithium-ion batteries Huang, Xiaosong Journal of Solid State Electrochemistry, Vol. 15, Issue 4 https://doi.org/10.1007/s10008-010-1264-9	journal	December 2010
Battery Separators Arora, Pankaj; Zhang, Zhengming (John) Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020738u	journal	October 2004
Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions Sloop, S. E.; Pugh, J. K.; Wang, S. Electrochemical and Solid-State Letters, Vol. 4, Issue 4 https://doi.org/10.1149/1.1353158	journal	January 2001
Design of electrolyte solutions for Li and Li-ion batteries: a review Aurbach, Doron; Talyosef, Yosef; Markovsky, Boris Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.01.090	journal	November 2004
Using a Boron-Based Anion Receptor Additive to Improve the Thermal Stability of LiPF[sub 6]-Based Electrolyte for Lithium Batteries Sun, X.; Lee, H. S.; Yang, X. -Q. Electrochemical and Solid-State Letters, Vol. 5, Issue 11 https://doi.org/10.1149/1.1510321	journal	January 2002
Thermal stability of LiPF6-based electrolyte and effect of contact with various delithiated cathodes of Li-ion batteries Xiang, H. F.; Wang, H.; Chen, C. H. Journal of Power Sources, Vol. 191, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.02.045	journal	June 2009
Thermal stability of LixCoO2 cathode for lithium ion battery Baba, Y. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00067-X	journal	June 2002
A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes MacNeil, D. D.; Lu, Zhonghua; Chen, Zhaohui Journal of Power Sources, Vol. 108, Issue 1-2 https://doi.org/10.1016/S0378-7753(01)01013-8	journal	June 2002
Thermal Stability of Lithium Nickel Oxide Derivatives. Part II: Li _x Ni _0.70 Co _0.15 Al _0.15 O ₂ and Li _x Ni _0.90 Mn _0.10 O ₂ ( x = 0.50 and 0.30). Comparison with Li _x Ni _1.02 O ₂ and Li _x Ni _0.89 Al _0.16 O ₂ Guilmard, M.; Croguennec, L.; Delmas, C. Chemistry of Materials, Vol. 15, Issue 23 https://doi.org/10.1021/cm030340u	journal	November 2003
Thermal Stability of Lithium Nickel Oxide Derivatives. Part I: Li _x Ni _1.02 O ₂ and Li _x Ni _0.89 Al _0.16 O ₂ ( x = 0.50 and 0.30) Guilmard, M.; Croguennec, L.; Denux, D. Chemistry of Materials, Vol. 15, Issue 23 https://doi.org/10.1021/cm030059f	journal	November 2003
Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells Dahn, J.; Fuller, E.; Obrovac, M. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90415-4	journal	August 1994
Thermal behavior of Li1−yNiO2 and the decomposition mechanism Arai, H. Solid State Ionics, Vol. 109, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00075-7	journal	June 1998
Thermal stabilities of delithiated olivine MPO4 (M=Fe, Mn) cathodes investigated using first principles calculations Ong, Shyue Ping; Jain, Anubhav; Hautier, Geoffroy Electrochemistry Communications, Vol. 12, Issue 3 https://doi.org/10.1016/j.elecom.2010.01.010	journal	March 2010
LiMnPO[sub 4] as the Cathode for Lithium Batteries Li, Guohua; Azuma, Hideto; Tohda, Masayuki Electrochemical and Solid-State Letters, Vol. 5, Issue 6 https://doi.org/10.1149/1.1475195	journal	January 2002
Thermal Stability of LiFePO[sub 4]-Based Cathodes Andersson, Anna S. Electrochemical and Solid-State Letters, Vol. 3, Issue 2 https://doi.org/10.1149/1.1390960	journal	January 1999
Safety characteristics of Li(Ni0.8Co0.15Al0.05)O2 and Li(Ni1/3Co1/3Mn1/3)O2 Belharouak, Ilias; Lu, Wenquan; Vissers, Donald Electrochemistry Communications, Vol. 8, Issue 2 https://doi.org/10.1016/j.elecom.2005.12.007	journal	February 2006
Thermal-runaway experiments on consumer Li-ion batteries with metal-oxide and olivin-type cathodes Golubkov, Andrey W.; Fuchs, David; Wagner, Julian RSC Adv., Vol. 4, Issue 7 https://doi.org/10.1039/C3RA45748F	journal	January 2014
A First-Principles Approach to Studying the Thermal Stability of Oxide Cathode Materials Wang, L.; Maxisch, T.; Ceder, G. Chemistry of Materials, Vol. 19, Issue 3 https://doi.org/10.1021/cm0620943	journal	February 2007
Structural Origin of Overcharge-Induced Thermal Instability of Ni-Containing Layered-Cathodes for High-Energy-Density Lithium Batteries Wu, Lijun; Nam, Kyung-Wan; Wang, Xiaojian Chemistry of Materials, Vol. 23, Issue 17 https://doi.org/10.1021/cm201452q	journal	September 2011
Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li _x Ni _0.8 Co _0.15 Al _0.05 O ₂ Cathode Materials Bak, Seong-Min; Nam, Kyung-Wan; Chang, Wonyoung Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303096e	journal	January 2013
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries Nam, Kyung-Wan; Bak, Seong-Min; Hu, Enyuan Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200693	journal	June 2012
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Oxygen-Release-Related Thermal Stability and Decomposition Pathways of Li _x Ni _0.5 Mn _1.5 O ₄ Cathode Materials Hu, Enyuan; Bak, Seong-Min; Liu, Jue Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm403400y	journal	December 2013
Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study Hu, Enyuan; Bak, Seong Min; Senanayake, Sanjaya D. Journal of Power Sources, Vol. 277 https://doi.org/10.1016/j.jpowsour.2014.12.015	journal	March 2015
Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries Yabuuchi, Naoaki; Ohzuku, Tsutomu Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00173-3	journal	June 2003
Synthesis of Vicinal Bis(alkylthio) Derivatives by Reductive Coupling of Dithioacetals Derived from Aromatic Aldehydes with Low Valent Titanium Iodide Species Yoshimura, Naritoshi; Igarashi, Koji; Funasaka, Setsuo Chemistry Letters, Vol. 30, Issue 7 https://doi.org/10.1246/cl.2001.640	journal	July 2001
Positive Electrode Materials for Li-Ion and Li-Batteries ^† Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902696j	journal	February 2010
Synthesis and Electrochemical Properties of Li[Ni[sub 1/3]Co[sub 1/3]Mn[sub (1/3−x)]Mg[sub x]]O[sub 2−y]F[sub y] via Coprecipitation Kim, G. -H.; Myung, S. -T.; Bang, H. J. Electrochemical and Solid-State Letters, Vol. 7, Issue 12 https://doi.org/10.1149/1.1809554	journal	January 2004
The synthesis, characterization and electrochemical behavior of the layered LiNi0.4Mn0.4Co0.2O2 compound Ngala, J. Katana; Chernova, Natasha A.; Ma, Miaomiao Journal of Materials Chemistry, Vol. 14, Issue 2 https://doi.org/10.1039/b309834f	journal	January 2004
Structural and electrochemical properties of layered Li6Ni0.5Mn0.591?xCoxO2 positive materials synthesized by ultrasonic spray pyrolysis method Oh, S. Solid State Ionics, Vol. 171, Issue 3-4 https://doi.org/10.1016/j.ssi.2004.04.012	journal	July 2004
Synthesis and Electrochemistry of LiNi[sub x]Mn[sub 2−x]O[sub 4] Zhong, Qiming Journal of The Electrochemical Society, Vol. 144, Issue 1 https://doi.org/10.1149/1.1837386	journal	January 1997
High-Performance LiNi _0.5 Mn _1.5 O ₄ Spinel Controlled by Mn ³⁺ Concentration and Site Disorder Xiao, Jie; Chen, Xilin; Sushko, Peter V. Advanced Materials, Vol. 24, Issue 16 https://doi.org/10.1002/adma.201104767	journal	March 2012
High-Power Nanostructured LiMn ₂ _- _x Ni _x O ₄ High-Voltage Lithium-Ion Battery Electrode Materials: Electrochemical Impact of Electronic Conductivity and Morphology Kunduraci, Muharrem; Al-Sharab, Jafar F.; Amatucci, Glenn G. Chemistry of Materials, Vol. 18, Issue 15 https://doi.org/10.1021/cm060729s	journal	July 2006
The effect of particle size and morphology on the rate capability of 4.7V LiMn1.5+δNi0.5−δO4 spinel lithium-ion battery cathodes Kunduraci, M.; Amatucci, G. G. Electrochimica Acta, Vol. 53, Issue 12 https://doi.org/10.1016/j.electacta.2007.12.057	journal	May 2008
High voltage spinel oxides for Li-ion batteries: From the material research to the application Patoux, Sébastien; Daniel, Lise; Bourbon, Carole Journal of Power Sources, Vol. 189, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.08.043	journal	April 2009
Role of Cation Ordering and Surface Segregation in High-Voltage Spinel LiMn _1.5 Ni _{0.5– x} M _x O ₄ (M = Cr, Fe, and Ga) Cathodes for Lithium-Ion Batteries Shin, Dong Wook; Bridges, Craig A.; Huq, Ashfia Chemistry of Materials, Vol. 24, Issue 19 https://doi.org/10.1021/cm301844w	journal	September 2012
Comparative Study of LiNi _0.5 Mn _1.5 O ₄ _- _δ and LiNi _0.5 Mn _1.5 O ₄ Cathodes Having Two Crystallographic Structures: Fd 3̄ m and P 4 ₃ 32 Kim, J. -H.; Myung, S. -T.; Yoon, C. S. Chemistry of Materials, Vol. 16, Issue 5 https://doi.org/10.1021/cm035050s	journal	March 2004
Topotactic Two-Phase Reactions of Li[Ni[sub 1/2]Mn[sub 3/2]]O[sub 4] (P4[sub 3]32) in Nonaqueous Lithium Cells Ariyoshi, Kingo; Iwakoshi, Yasunobu; Nakayama, Noriaki Journal of The Electrochemical Society, Vol. 151, Issue 2 https://doi.org/10.1149/1.1639162	journal	January 2004
Thermal stability of Li1-ΔM0.5Mn1.5O4 (M = Fe, Co, Ni) cathodes in different states of delithiation Δ Bhaskar, Aiswarya; Gruner, Wolfgang; Mikhailova, Daria RSC Advances https://doi.org/10.1039/C3RA40356D	journal	January 2013
High voltage nickel manganese spinel oxides for Li-ion batteries Patoux, Sébastien; Sannier, Lucas; Lignier, Hélène Electrochimica Acta, Vol. 53, Issue 12 https://doi.org/10.1016/j.electacta.2007.12.054	journal	May 2008
The Li1+xMn2O4/C rocking-chair system: a review Tarascon, J. M.; Guyomard, D. Electrochimica Acta, Vol. 38, Issue 9 https://doi.org/10.1016/0013-4686(93)80053-3	journal	June 1993
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li _1.2 Ni _0.15 Co _0.1 Mn _0.55 O ₂ Cathode Materials Yu, Xiqian; Lyu, Yingchun; Gu, Lin Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201300950	journal	December 2013
Factors Influencing the Layered to Spinel-like Phase Transition in Layered Oxide Cathodes Choi, S.; Manthiram, A. Journal of The Electrochemical Society, Vol. 149, Issue 9 https://doi.org/10.1149/1.1497171	journal	January 2002
Utilizing Environmental Friendly Iron as a Substitution Element in Spinel Structured Cathode Materials for Safer High Energy Lithium-Ion Batteries Hu, Enyuan; Bak, Seong-Min; Liu, Yijin Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501662	journal	December 2015
Atomic Structure of Li ₂ MnO ₃ after Partial Delithiation and Re-Lithiation Wang, Rui; He, Xiaoqing; He, Lunhua Advanced Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1002/aenm.201200842	journal	June 2013
Direct Observation of Lithium Staging in Partially Delithiated LiFePO ₄ at Atomic Resolution Gu, Lin; Zhu, Changbao; Li, Hong Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja109412x	journal	April 2011
High-energy cathode material for long-life and safe lithium batteries Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun Nature Materials, Vol. 8, Issue 4 https://doi.org/10.1038/nmat2418	journal	March 2009
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R. Electrochemical and Solid-State Letters, Vol. 4, Issue 11 https://doi.org/10.1149/1.1407994	journal	January 2001
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T. Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/B417616M	journal	March 2005
Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction Mohanty, Debasish; Kalnaus, Sergiy; Meisner, Roberta A. Journal of Power Sources, Vol. 229 https://doi.org/10.1016/j.jpowsour.2012.11.144	journal	May 2013
Probing Reversible Multielectron Transfer and Structure Evolution of Li _1.2 Cr _0.4 Mn _0.4 O ₂ Cathode Material for Li-Ion Batteries in a Voltage Range of 1.0–4.8 V Lyu, Yingchun; Zhao, Nijie; Hu, Enyuan Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b01362	journal	July 2015
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries Gu, Meng; Belharouak, Ilias; Zheng, Jianming ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn305065u	journal	December 2012
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Functioning Mechanism of AlF ₃ Coating on the Li- and Mn-Rich Cathode Materials Zheng, Jianming; Gu, Meng; Xiao, Jie Chemistry of Materials, Vol. 26, Issue 22 https://doi.org/10.1021/cm502071h	journal	November 2014

Cited By (4)

Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries de Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten Advanced Materials, Vol. 31, Issue 26 https://doi.org/10.1002/adma.201900985	journal	April 2019
A review on cathode materials for advanced lithium ion batteries: microstructure designs and performance regulations Chen, Zhangxian; Zhang, Weixin; Yang, Zeheng Nanotechnology, Vol. 31, Issue 1 https://doi.org/10.1088/1361-6528/ab4447	journal	October 2019
Impact of Dopants (Al, Mg, Mn, Co) on the Reactivity of Li _x NiO ₂ with the Electrolyte of Li-Ion Batteries Cormier, Marc M. E.; Zhang, Ning; Liu, Aaron Journal of The Electrochemical Society, Vol. 166, Issue 13 https://doi.org/10.1149/2.0491913jes	journal	January 2019
Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries De Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten Karlsruhe https://doi.org/10.5445/ir/1000094297	text	January 2019

Similar Records

Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes’ effects on thermal & cycling stability

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Chinese Physics. B · OSTI ID:1237737

Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; +2 more

Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes' effects on thermal & cycling stability

Journal Article · Mon Dec 07 00:00:00 EST 2015 · Chinese Physics Letters · OSTI ID:1237737

Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; +2 more

Electrochemical Characteristics of Layered Transition Metal Oxide Cathode Materials for Lithium Ion Batteries: Surface, Bulk Behavior, and Thermal Properties

Journal Article · Tue Dec 19 00:00:00 EST 2017 · Accounts of Chemical Research · OSTI ID:1237737

Tian, Chixia; Lin, Feng; Doeff, Marca M.

Title: Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes’ effects on thermal & cycling stability

Citation Formats

References (67)

Cited By (4)

Similar Records

Related Subjects