Conduction below 100 °C in nominal Li6ZnNb4O14

Li, Yunchao; Paranthaman, Mariappan Parans; Gill, Lance W.; Wang, Yangyang; Sokolov, Alexei P.; Dai, Sheng; Ma, Cheng; Chi, Miaofang; Veith, Gabriel M.; Manthiram, Arumugam; Goodenough, John B.

doi:10.1007/s10853-015-9408-z

Title: Conduction below 100 °C in nominal Li₆ZnNb₄O₁₄

Journal Article · Tue Sep 15 00:00:00 EDT 2015 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-015-9408-z· OSTI ID:1237633

Li, Yunchao ^[1]; Paranthaman, Mariappan Parans ^[1]; Gill, Lance W. ^[2]; Wang, Yangyang ^[2]; Sokolov, Alexei P. ^[2]; Dai, Sheng ^[2]; Ma, Cheng ^[2]; Chi, Miaofang ^[2]; Veith, Gabriel M. ^[2]; Manthiram, Arumugam ^[3]; Goodenough, John B. ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Texas, Austin, TX (United States)

The increasing demand for a safe rechargeable battery with a high energy density per cell is driving a search for a novel solid electrolyte with a high Li⁺ or Na⁺ conductivity that is chemically stable in a working Li-ion or Na-ion battery. Li₆ZnNb₄O₁₄ has been reported to exhibit a σ _Li > 10^-2 S cm^-1 at 250 °C, but to disproportionate into multiple phases on cooling from 850 °C to room temperature. An investigation of the room-temperature Li-ion conductivity in a porous pellet of a multiphase product of a nominal Li₆ZnNb₄O₁₄ composition is shown to have bulk σ _Li 3.3 x 10^-5 S cm^-1 at room temperature that increases to 1.4 x 10^-4 S cm^-1 by 50 °C. 7Li MAS NMR spectra were fitted to two Lorentzian lines, one of which showed a dramatic increase with increasing temperature. As a result, a test for water stability indicates that Li⁺ may move to the particle and grain surfaces to react with adsorbed water as occurs in the garnet Li⁺ conductors.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237633

Journal Information:: Journal of Materials Science, Vol. 51, Issue 1; ISSN 0022-2461

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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