Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; Kent, Paul R. C.; Sumpter, Bobby G.; Mandrus, David G.; Geohegan, David B.; Xiao, Kai

doi:10.1039/C5TC03463A

Title: Ultrathin nanosheets of CrSiTe₃. A semiconducting two-dimensional ferromagnetic material

Journal Article · Fri Nov 27 00:00:00 EST 2015 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/C5TC03463A· OSTI ID:1237632

Lin, Ming -Wei ^[1]; Zhung, Houlong L. ^[1]; Yan, Jiaqiang ^[2]; Ward, Thomas Zac ^[1]; Puretzky, Alexander A. ^[1]; Rouleau, Christopher M. ^[1]; Gai, Zheng ^[1]; Liang, Liangbo ^[3]; Meunier, Vincent ^[4]; Ganesh, Panchapakesan ^[1]; Kent, Paul R. C. ^[1]; Sumpter, Bobby G. ^[1]; Mandrus, David G. ^[2]; Geohegan, David B. ^[1]; Xiao, Kai ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Rensselaer Polytechnic Institute (RPI), Troy, NY (United States)
Rensselaer Polytechnic Institute (RPI), Troy, NY (United States)

Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe₃, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO₂ substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra of 2D CrSiTe₃, giving a strong evidence for the existence of 2D CrSiTe₃ crystals. When the thickness of the CrSiTe₃ crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe₃ crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe₃ indicated here should enable numerous applications in nano-spintronics.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237632

Journal Information:: Journal of Materials Chemistry C, Vol. 4, Issue 2; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 216 works

Citation information provided by
Web of Science

References (55)

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712 https://doi.org/10.1038/nnano.2012.193	journal	November 2012
Van der Waals heterostructures Geim, A. K.; Grigorieva, I. V. Nature, Vol. 499, Issue 7459, p. 419-425 https://doi.org/10.1038/nature12385	journal	July 2013
Liquid Exfoliation of Layered Materials Nicolosi, V.; Chhowalla, M.; Kanatzidis, M. G. Science, Vol. 340, Issue 6139, p. 1226419 https://doi.org/10.1126/science.1226419	journal	June 2013
Ferromagnetic two-dimensional crystals: Single layers of K $_{2}$ CuF $_{4}$ Sachs, B.; Wehling, T. O.; Novoselov, K. S. Physical Review B, Vol. 88, Issue 20 https://doi.org/10.1103/PhysRevB.88.201402	journal	November 2013
Magnetic ground state of semiconducting transition-metal trichalcogenide monolayers Sivadas, Nikhil; Daniels, Matthew W.; Swendsen, Robert H. Physical Review B, Vol. 91, Issue 23 https://doi.org/10.1103/PhysRevB.91.235425	journal	June 2015
Magnetic structure of the new layered ferromagnetic chromium hexatellurosilicate Cr2Si2Te6 Carteaux, V.; Ouvrard, G.; Grenier, J. C. Journal of Magnetism and Magnetic Materials, Vol. 94, Issue 1-2 https://doi.org/10.1016/0304-8853(91)90121-P	journal	March 1991
Strong spin-lattice coupling in CrSiTe ₃ Casto, L. D.; Clune, A. J.; Yokosuk, M. O. APL Materials, Vol. 3, Issue 4 https://doi.org/10.1063/1.4914134	journal	April 2015
A Genuine Two-Dimensional Ising Ferromagnet with Magnetically Driven Re-entrant Transition Kabbour, Houria; David, Rénald; Pautrat, Alain Angewandte Chemie International Edition, Vol. 51, Issue 47 https://doi.org/10.1002/anie.201205843	journal	October 2012
Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI ₃ McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R. Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm504242t	journal	January 2015
Magnetic Properties of K ₂ CuF ₄ –A Transparent Two-Dimensional Ferromagnet– Yamada, Isao Journal of the Physical Society of Japan, Vol. 33, Issue 4 https://doi.org/10.1143/JPSJ.33.979	journal	October 1972
Magnetic properties of MoS2: Existence of ferromagnetism Tongay, Sefaattin; Varnoosfaderani, Sima S.; Appleton, Bill R. Applied Physics Letters, Vol. 101, Issue 12 https://doi.org/10.1063/1.4753797	journal	September 2012
Intrinsic Magnetism of Grain Boundaries in Two-Dimensional Metal Dichalcogenides Zhang, Zhuhua; Zou, Xiaolong; Crespi, Vincent H. ACS Nano, Vol. 7, Issue 12 https://doi.org/10.1021/nn4052887	journal	November 2013
Tuning the Electronic and Magnetic Properties of MoS 2 Nanoribbons by Strain Engineering Pan, Hui; Zhang, Yong-Wei The Journal of Physical Chemistry C, Vol. 116, Issue 21 https://doi.org/10.1021/jp3015782	journal	May 2012
Tuning the Optical, Magnetic, and Electrical Properties of ReSe ₂ by Nanoscale Strain Engineering Yang, Shengxue; Wang, Cong; Sahin, Hasan Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl504276u	journal	February 2015
Large, non-saturating magnetoresistance in WTe2 Ali, Mazhar N.; Xiong, Jun; Flynn, Steven Nature, Vol. 514, Issue 7521 https://doi.org/10.1038/nature13763	journal	September 2014
Vacancy-Induced Ferromagnetism of MoS ₂ Nanosheets Cai, Liang; He, Jingfu; Liu, Qinghua Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja5120908	journal	February 2015
Absence of Ferromagnetism or Antiferromagnetism in One- or Two-Dimensional Isotropic Heisenberg Models Mermin, N. D.; Wagner, H. Physical Review Letters, Vol. 17, Issue 22 https://doi.org/10.1103/PhysRevLett.17.1133	journal	November 1966
Absence of Spontaneous Magnetic Order at Nonzero Temperature in One- and Two-Dimensional Heisenberg and $XY$ Systems with Long-Range Interactions Bruno, P. Physical Review Letters, Vol. 87, Issue 13 https://doi.org/10.1103/PhysRevLett.87.137203	journal	September 2001
Experiments on literally two-dimensional magnets Pomerantz, Melvin Surface Science, Vol. 142, Issue 1-3 https://doi.org/10.1016/0039-6028(84)90362-5	journal	July 1984
Dimensional crossover in ultrathin Ni(111) films on W(110) Li, Yi; Baberschke, K. Physical Review Letters, Vol. 68, Issue 8 https://doi.org/10.1103/PhysRevLett.68.1208	journal	February 1992
Ferromagnetism in two-dimensional ${Ti}_{0.8} {Co}_{0.2} O_{2}$ nanosheets Osada, M.; Ebina, Y.; Fukuda, K. Physical Review B, Vol. 73, Issue 15 https://doi.org/10.1103/PhysRevB.73.153301	journal	April 2006
Half-Metallic Ferromagnetism in Synthetic Co ₉ Se ₈ Nanosheets with Atomic Thickness Zhang, Xiaodong; Zhang, Jiajia; Zhao, Jinyang Journal of the American Chemical Society, Vol. 134, Issue 29 https://doi.org/10.1021/ja3046603	journal	July 2012
Enhanced and Engineered d ⁰ Ferromagnetism in Molecularly-Thin Zinc Oxide Nanosheets Taniguchi, Takaaki; Yamaguchi, Kazuhiro; Shigeta, Ayako Advanced Functional Materials, Vol. 23, Issue 25 https://doi.org/10.1002/adfm.201202704	journal	January 2013
Controlled doping of semiconducting titania nanosheets for tailored spinelectronic materials Osada, Minoru; Yoguchi, Satoshi; Itose, Masayuki Nanoscale, Vol. 6, Issue 23 https://doi.org/10.1039/C4NR04465G	journal	January 2014
Synthesis and crystal structure of a new layered phase: The chromium hexatellurosilicate Cr2Si2Te6 Ouvrard, G.; Sandre, E.; Brec, R. Journal of Solid State Chemistry, Vol. 73, Issue 1 https://doi.org/10.1016/0022-4596(88)90049-7	journal	March 1988
2D Ising-Like Ferromagnetic Behaviour for the Lamellar Cr ₂ Si ₂ Te ₆ Compound: A Neutron Scattering Investigation Carteaux, V.; Moussa, F.; Spiesser, M. Europhysics Letters (EPL), Vol. 29, Issue 3 https://doi.org/10.1209/0295-5075/29/3/011	journal	January 1995
CrXTe ₃ (X = Si, Ge) nanosheets: two dimensional intrinsic ferromagnetic semiconductors Li, Xingxing; Yang, Jinlong Journal of Materials Chemistry C, Vol. 2, Issue 34 https://doi.org/10.1039/C4TC01193G	journal	January 2014
Strain-engineering of magnetic coupling in two-dimensional magnetic semiconductor CrSiTe3: Competition of direct exchange interaction and superexchange interaction Chen, Xiaofang; Qi, Jingshan; Shi, Daning Physics Letters A, Vol. 379, Issue 1-2 https://doi.org/10.1016/j.physleta.2014.10.042	journal	January 2015
Computational discovery of ferromagnetic semiconducting single-layer ${CrSnTe}_{3}$ Zhuang, Houlong L.; Xie, Yu; Kent, P. R. C. Physical Review B, Vol. 92, Issue 3 https://doi.org/10.1103/PhysRevB.92.035407	journal	July 2015
Chemical Vapor Deposition Growth of Crystalline Monolayer MoSe₂ Wang, Xingli; Gong, Yongji; Shi, Gang ACS Nano, Vol. 8, Issue 5, p. 5125-5131 https://doi.org/10.1021/nn501175k	journal	April 2014
Controlled Vapor Phase Growth of Single Crystalline, Two-Dimensional GaSe Crystals with High Photoresponse Li, Xufan; Lin, Ming-Wei; Puretzky, Alexander A. Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05497	journal	June 2014
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
Half-Metallicity in MnPSe ₃ Exfoliated Nanosheet with Carrier Doping Li, Xingxing; Wu, Xiaojun; Yang, Jinlong Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja505097m	journal	July 2014
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators Liechtenstein, A. I.; Anisimov, V. I.; Zaanen, J. Physical Review B, Vol. 52, Issue 8 https://doi.org/10.1103/PhysRevB.52.R5467	journal	August 1995
First-principles Raman spectra of MoS2, WS2 and their heterostructures Liang, Liangbo; Meunier, Vincent Nanoscale, Vol. 6, Issue 10 https://doi.org/10.1039/c3nr06906k	journal	January 2014
First-Principles Determination of the Soft Mode in Cubic ${ZrO}_{2}$ Parlinski, K.; Li, Z. Q.; Kawazoe, Y. Physical Review Letters, Vol. 78, Issue 21 https://doi.org/10.1103/PhysRevLett.78.4063	journal	May 1997
Mobility engineering and a metal–insulator transition in monolayer MoS2 Radisavljevic, Branimir; Kis, Andras Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3687	journal	June 2013
Tuning the Bandgap of Exfoliated InSe Nanosheets by Quantum Confinement Mudd, Garry W.; Svatek, Simon A.; Ren, Tianhang Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302616	journal	August 2013
How Good Can Monolayer MoS ₂ Transistors Be? Yoon, Youngki; Ganapathi, Kartik; Salahuddin, Sayeef Nano Letters, Vol. 11, Issue 9 https://doi.org/10.1021/nl2018178	journal	September 2011
Magnetic Properties of Layered Heisenberg Ferromagnets Du, A.; Wei, Gz Australian Journal of Physics, Vol. 46, Issue 4 https://doi.org/10.1071/PH930571	journal	January 1993
Phase transitions induced by easy-plane anisotropy in the classical Heisenberg antiferromagnet on a triangular lattice: A Monte Carlo simulation Capriotti, Luca; Vaia, Ruggero; Cuccoli, Alessandro Physical Review B, Vol. 58, Issue 1 https://doi.org/10.1103/PhysRevB.58.273	journal	July 1998
Anomalous Magnetic Moments and Transformations in the Ordered Alloy FeRh Kouvel, J. S.; Hartelius, C. C. Journal of Applied Physics, Vol. 33, Issue 3 https://doi.org/10.1063/1.1728721	journal	March 1962
Hall-effect characterization of the metamagnetic transition in FeRh de Vries, M. A.; Loving, M.; Mihai, A. P. New Journal of Physics, Vol. 15, Issue 1 https://doi.org/10.1088/1367-2630/15/1/013008	journal	January 2013
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
A Genuine Two-Dimensional Ising Ferromagnet with Magnetically Driven Re-entrant Transition Kabbour, Houria; David, Rénald; Pautrat, Alain Angewandte Chemie, Vol. 124, Issue 47 https://doi.org/10.1002/ange.201205843	journal	October 2012
Magnetic ground state of semiconducting transition metal trichalcogenide monolayers Sivadas, Nikhil; Daniels, Matthew W.; Swendsen, Robert Carnegie Mellon University https://doi.org/10.1184/r1/6507131.v1	text	January 2015
Experiments on literally two-dimensional magnets Pomerantz, Melvin Surface Science Letters, Vol. 142, Issue 1-3 https://doi.org/10.1016/0167-2584(84)90090-2	journal	July 1984
Mobility engineering and metal-insulator transition in monolayer MoS2 Radisavljevic, Branimir; Kis, Andras arXiv https://doi.org/10.48550/arxiv.1301.4947	text	January 2013
Intrinsic Magnetism of Grain Boundaries in Two-dimensional Metal Dichalcogenides Zhang, Zhuhua; Zou, Xiaolong; Crespi, Vincent H. arXiv https://doi.org/10.48550/arxiv.1308.4355	preprint	January 2013
Magnetic ground state of semiconducting transition metal trichalcogenide monolayers Sivadas, Nikhil; Daniels, Matthew W.; Swendsen, Robert H. arXiv https://doi.org/10.48550/arxiv.1503.00412	text	January 2015
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S.; Geim, A. K.; Morozov, S. V. arXiv https://doi.org/10.48550/arxiv.cond-mat/0410550	text	January 2004
Phase-transitions induced by easy-plane anisotropy in the classical Heisenberg antiferromagnet on a triangular lattice: a Monte Carlo simulation Capriotti, Luca; Vaia, Ruggero; Cuccoli, Alessandro arXiv https://doi.org/10.48550/arxiv.cond-mat/9711104	text	January 1997

Cited By (52)

Robust Above‐Room‐Temperature Ferromagnetism in Few‐Layer Antimonene Triggered by Nonmagnetic Adatoms Tang, Xian; Hu, Liang; Fan, Touwen Advanced Functional Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adfm.201808746	journal	January 2019
Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials Susner, Michael A.; Chyasnavichyus, Marius; McGuire, Michael A. Advanced Materials, Vol. 29, Issue 38 https://doi.org/10.1002/adma.201602852	journal	August 2017
Liquid-Alloy-Assisted Growth of 2D Ternary Ga ₂ In ₄ S ₉ toward High-Performance UV Photodetection Wang, Fakun; Gao, Ting; Zhang, Qi Advanced Materials, Vol. 31, Issue 2 https://doi.org/10.1002/adma.201806306	journal	November 2018
Intrinsic Van Der Waals Magnetic Materials from Bulk to the 2D Limit: New Frontiers of Spintronics Li, Hui; Ruan, Shuangchen; Zeng, Yu‐Jia Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900065	journal	May 2019
Van der Waals 2D Transition Metal Tellurides Su, Jianwei; Liu, Kailang; Wang, Fakun Advanced Materials Interfaces, Vol. 6, Issue 19 https://doi.org/10.1002/admi.201900741	journal	August 2019
2D Ternary Chalcogenides Gao, Ting; Zhang, Qi; Li, Liang Advanced Optical Materials, Vol. 6, Issue 14 https://doi.org/10.1002/adom.201800058	journal	May 2018
Simulation of Transition Metal Dichalcogenides Habib, Mohammad Rezwan; Chen, Wenchao; Yin, Wen-Yan Two Dimensional Transition Metal Dichalcogenides https://doi.org/10.1007/978-981-13-9045-6_5	book	January 2019
The emerging ferroic orderings in two dimensions Zhang, Yupeng; Wang, Hanwen; Li, Feng Science China Information Sciences, Vol. 62, Issue 12 https://doi.org/10.1007/s11432-019-2642-6	journal	November 2019
Tunable electronic structure and magnetic coupling in strained two-dimensional semiconductor MnPSe3 Pei, Qi; Wang, Xiao-Cha; Zou, Ji-Jun Frontiers of Physics, Vol. 13, Issue 4 https://doi.org/10.1007/s11467-018-0796-9	journal	May 2018
Effect of Coulomb Interactions on the Electronic and Magnetic Properties of Two-Dimensional CrSiTe3 and CrGeTe3 Materials Kang, Sungmo; Kang, Seungjin; Yu, Jaejun Journal of Electronic Materials, Vol. 48, Issue 3 https://doi.org/10.1007/s11664-018-6601-2	journal	September 2018
Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén Nature, Vol. 546, Issue 7657 https://doi.org/10.1038/nature22391	journal	June 2017
Hard magnetic properties in nanoflake van der Waals Fe3GeTe2 Tan, Cheng; Lee, Jinhwan; Jung, Soon-Gil Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04018-w	journal	April 2018
Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3 Wang, Zhe; Gutiérrez-Lezama, Ignacio; Ubrig, Nicolas Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04953-8	journal	June 2018
Searching for materials with reduced dimension Eriksson, Olle Nature Nanotechnology, Vol. 13, Issue 3 https://doi.org/10.1038/s41565-017-0060-4	journal	February 2018
Strong room-temperature ferromagnetism in VSe2 monolayers on van der Waals substrates Bonilla, Manuel; Kolekar, Sadhu; Ma, Yujing Nature Nanotechnology, Vol. 13, Issue 4 https://doi.org/10.1038/s41565-018-0063-9	journal	February 2018
Electric-field control of magnetism in a few-layered van der Waals ferromagnetic semiconductor Wang, Zhi; Zhang, Tongyao; Ding, Mei Nature Nanotechnology, Vol. 13, Issue 7 https://doi.org/10.1038/s41565-018-0186-z	journal	July 2018
2DMatPedia, an open computational database of two-dimensional materials from top-down and bottom-up approaches Zhou, Jun; Shen, Lei; Costa, Miguel Dias Scientific Data, Vol. 6, Issue 1 https://doi.org/10.1038/s41597-019-0097-3	journal	June 2019
Probing and controlling magnetic states in 2D layered magnetic materials Mak, Kin Fai; Shan, Jie; Ralph, Daniel C. Nature Reviews Physics, Vol. 1, Issue 11 https://doi.org/10.1038/s42254-019-0110-y	journal	September 2019
Novel two-dimensional ferromagnetic semiconductors: Ga-based transition-metal trichalcogenide monolayers Yu, Maolin; Liu, Xiaofei; Guo, Wanlin Physical Chemistry Chemical Physics, Vol. 20, Issue 9 https://doi.org/10.1039/c7cp07912e	journal	January 2018
Recent advances in ternary two-dimensional materials: synthesis, properties and applications Wang, Lina; Hu, Peng; Long, Yi Journal of Materials Chemistry A, Vol. 5, Issue 44 https://doi.org/10.1039/c7ta06971e	journal	January 2017
Large tunneling magnetoresistance in magnetic tunneling junctions based on two-dimensional CrX ₃ (X = Br, I) monolayers Pan, Longfei; Huang, Le; Zhong, Mianzeng Nanoscale, Vol. 10, Issue 47 https://doi.org/10.1039/c8nr06255b	journal	January 2018
Ferromagnetism in magnesium chloride monolayer with an unusually large spin-up gap Bhattacharyya, Gargee; Choudhuri, Indrani; Bhauriyal, Preeti Nanoscale, Vol. 10, Issue 47 https://doi.org/10.1039/c8nr07429a	journal	January 2018
The direct observation of ferromagnetic domain of single crystal CrSiTe ₃ Wu, Shenghang; Wang, Lihai; Gao, Bin AIP Advances, Vol. 8, Issue 5 https://doi.org/10.1063/1.5024576	journal	May 2018
Magnetic and electronic properties of Cr ₂ Ge ₂ Te ₆ monolayer by strain and electric-field engineering Wang, Kangying; Hu, Tao; Jia, Fanhao Applied Physics Letters, Vol. 114, Issue 9 https://doi.org/10.1063/1.5083992	journal	March 2019
Surface-vacancy-induced metallicity and layer-dependent magnetic anisotropy energy in Cr2Ge2Te6 Song, Changsheng; Liu, Xin; Wu, Xiaoping Journal of Applied Physics, Vol. 126, Issue 10 https://doi.org/10.1063/1.5109875	journal	September 2019
Revealing antiferromagnetic transition of van der Waals MnPS ₃ via vertical tunneling electrical resistance measurement Luong, Dinh Hoa; Phan, Thanh Luan; Ghimire, Ganesh APL Materials, Vol. 7, Issue 8 https://doi.org/10.1063/1.5112130	journal	August 2019
Two-dimensional van der Waals spinterfaces and magnetic-interfaces Dayen, Jean-Francois; Ray, Soumya J.; Karis, Olof Applied Physics Reviews, Vol. 7, Issue 1 https://doi.org/10.1063/1.5112171	journal	March 2020
Opportunities and challenges of 2D magnetic van der Waals materials: magnetic graphene? Park, Je-Geun Journal of Physics: Condensed Matter, Vol. 28, Issue 30 https://doi.org/10.1088/0953-8984/28/30/301001	journal	June 2016
Two dimensional ferromagnetic semiconductor: monolayer CrGeS ₃ Ren, Yulu; Ge, Yanfeng; Wan, Wenhui Journal of Physics: Condensed Matter, Vol. 32, Issue 1 https://doi.org/10.1088/1361-648x/ab4395	journal	October 2019
First-principles study the single-layer transition metal trihalide CrXSe ₃ (X = Sn, Ge, Si) as monolayer ferromagnetic semiconductor Shen, Zihan; Fan, Xiaoli; Yang, Danxi Journal of Physics: Condensed Matter, Vol. 32, Issue 8 https://doi.org/10.1088/1361-648x/ab462a	journal	November 2019
Efficient band structure modulations in two-dimensional MnPSe ₃ /CrSiTe ₃ van der Waals heterostructures Pei, Qi; Wang, Xiaocha; Zou, Jijun Nanotechnology, Vol. 29, Issue 21 https://doi.org/10.1088/1361-6528/aab5ab	journal	March 2018
Electrically tunable exchange splitting in bilayer graphene on monolayer Cr ₂ X ₂ Te ₆ with X = Ge, Si, and Sn Zollner, Klaus; Gmitra, Martin; Fabian, Jaroslav New Journal of Physics, Vol. 20, Issue 7 https://doi.org/10.1088/1367-2630/aace51	journal	July 2018
Magneto-elastic coupling in a potential ferromagnetic 2D atomic crystal Tian, Yao; Gray, Mason J.; Ji, Huiwen 2D Materials, Vol. 3, Issue 2 https://doi.org/10.1088/2053-1583/3/2/025035	journal	June 2016
Raman spectroscopy of atomically thin two-dimensional magnetic iron phosphorus trisulfide (FePS ₃ ) crystals Wang, Xingzhi; Du, Kezhao; Fredrik Liu, Yu Yang 2D Materials, Vol. 3, Issue 3 https://doi.org/10.1088/2053-1583/3/3/031009	journal	August 2016
Two-dimensional multiferroics in monolayer group IV monochalcogenides Wang, Hua; Qian, Xiaofeng 2D Materials, Vol. 4, Issue 1 https://doi.org/10.1088/2053-1583/4/1/015042	journal	January 2017
Electric field effect in multilayer Cr ₂ Ge ₂ Te ₆ : a ferromagnetic 2D material Xing, Wenyu; Chen, Yangyang; Odenthal, Patrick M. 2D Materials, Vol. 4, Issue 2 https://doi.org/10.1088/2053-1583/aa7034	journal	May 2017
First-principles design of spintronics materials Li, Xingxing; Yang, Jinlong National Science Review, Vol. 3, Issue 3 https://doi.org/10.1093/nsr/nww026	journal	April 2016
Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan Science, Vol. 360, Issue 6394 https://doi.org/10.1126/science.aar4851	journal	May 2018
Ab Initio Study of Optoelectronic and Magnetic Properties of Ternary Chromium Chalcogenides Ong, Marc; Hammouri, Mahmoud; Jishi, Radi A. Advances in Materials Science and Engineering, Vol. 2018 https://doi.org/10.1155/2018/3762451	journal	November 2018
Magnetic Properties of Proton Irradiated Mn3Si2Te6 van der Waals Single Crystals Martinez, L. M.; Saiz, C. L.; Cosio, A. MRS Advances, Vol. 4, Issue 40 https://doi.org/10.1557/adv.2019.260	journal	January 2019
Magnetic 2D materials and heterostructures Gibertini, M.; Koperski, M.; Morpurgo, A. F. Nature Nanotechnology, Vol. 14, Issue 5 https://doi.org/10.1038/s41565-019-0438-6	journal	May 2019
Determining the phase diagram of atomically thin layered antiferromagnet CrCl3 Wang, Zhe; Gibertini, Marco; Dumcenco, Dumitru Nature Nanotechnology, Vol. 14, Issue 12 https://doi.org/10.1038/s41565-019-0565-0	journal	November 2019
Long range intrinsic ferromagnetism in two dimensional materials and dissipationless future technologies Shabbir, Babar; Nadeem, Muhammad; Dai, Zhigao Applied Physics Reviews, Vol. 5, Issue 4 https://doi.org/10.1063/1.5040694	journal	December 2018
Strain induced electronic and magnetic properties of 2D magnet CrI ₃ : a DFT approach Mukherjee, Tista; Chowdhury, Suman; Jana, Debnarayan Journal of Physics: Condensed Matter, Vol. 31, Issue 33 https://doi.org/10.1088/1361-648x/ab1fcf	journal	May 2019
Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3 Wang, Zhe; Gutiérrez-Lezama, Ignacio; Ubrig, Nicolas ETH Zurich https://doi.org/10.3929/ethz-b-000275019	text	January 2018
Gate-controllable magneto-optic Kerr effect in layered collinear antiferromagnets Sivadas, Nikhil; Okamoto, Satoshi; Xiao, Di arXiv https://doi.org/10.48550/arxiv.1607.02156	text	January 2016
Layer-dependent Ferromagnetism in a van der Waals Crystal down to the Monolayer Limit Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren arXiv https://doi.org/10.48550/arxiv.1703.05892	text	January 2017
Giant Tunneling Magnetoresistance in Spin-Filter van der Waals Heterostructures Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan arXiv https://doi.org/10.48550/arxiv.1801.08679	text	January 2018
Hard magnetic properties in nanoflake van der Waals Fe3GeTe2 Tan, Cheng; Lee, Jinhwan; Jung, Soon-Gil arXiv https://doi.org/10.48550/arxiv.1803.02934	text	January 2018
Effect of Coulomb Interactions on the Electronic and Magnetic Properties of Two-Dimensional CrSiTe$_3$ and CrGeTe$_3$ Materials Kang, Sungmo; Kang, Seungjin; Yu, Jaejun arXiv https://doi.org/10.48550/arxiv.1807.10686	text	January 2018
Long Range Intrinsic Ferromagnetism in Two Dimensional Materials and Dissipationless Future Technologies Shabbir, Babar; Nadeem, Muhammad; Dai, Zhigao arXiv https://doi.org/10.48550/arxiv.1810.09053	text	January 2018
Two Dimensional Ferromagnetic Semiconductor: Monolayer CrGeS$_3$ Ren, Yulu; Ge, Yanfeng; Wan, Wenhui arXiv https://doi.org/10.48550/arxiv.1906.07396	text	January 2019

Similar Records

Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting Ferromagnet CrSiTe₃

Journal Article · Fri Oct 02 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1237632

Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; +4 more

Two-dimensional itinerant ferromagnetism in atomically thin Fe₃GeTe₂

Journal Article · Mon Aug 13 00:00:00 EDT 2018 · Nature Materials · OSTI ID:1237632

Fei, Zaiyao; Huang, Bevin; Malinowski, Paul; +11 more

Above-Room-Temperature Ferromagnetism in Thin van der Waals Flakes of Cobalt-Substituted Fe₅GeTe₂

Journal Article · Thu Jan 05 00:00:00 EST 2023 · ACS Applied Materials and Interfaces · OSTI ID:1237632

Chen, Hang; Asif, Shahidul; Dolui, Kapildeb; +16 more

Related Subjects

36 MATERIALS SCIENCE

Title: Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

Citation Formats

References (55)

Cited By (52)

Similar Records

Related Subjects

Title: Ultrathin nanosheets of CrSiTe₃. A semiconducting two-dimensional ferromagnetic material