Revealing the mechanism of the viscous-to-elastic crossover in liquids

Bolmatov, Dima; Zhernenkov, Mikhail; Zav'yalov, Dmitry; Stoupin, Stanislav; Cai, Yong Q.; Cunsolo, Alessandro

doi:10.1021/acs.jpclett.5b01338

Title: Revealing the mechanism of the viscous-to-elastic crossover in liquids

Journal Article · Sat Jul 18 00:00:00 EDT 2015 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.5b01338· OSTI ID:1237164

Bolmatov, Dima ^[1]; Zhernenkov, Mikhail ^[1]; Zav'yalov, Dmitry ^[2]; Stoupin, Stanislav ^[3]; Cai, Yong Q. ^[1]; Cunsolo, Alessandro ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Volgograd State Technical Univ. (Russia)
Argonne National Lab. (ANL), Argonne, IL (United States)

In our work, we report on inelastic X-ray scattering experiments combined with the molecular dynamics simulations on deeply supercritical Ar. Our results unveil the mechanism and regimes of sound propagation in the liquid matter and provide compelling evidence for the adiabatic-to-isothermal longitudinal sound propagation transition. We introduce a Hamiltonian predicting low-frequency transverse sound propagation gaps, which is confirmed by experimental findings and molecular dynamics calculations. As a result, a universal link is established between the positive sound dispersion (PSD) phenomenon and the origin of transverse sound propagation revealing the viscous-to-elastic crossover in liquids. The PSD and transverse phononic excitations evolve consistently with theoretical predictions. Both can be considered as a universal fingerprint of the dynamic response of a liquid, which is also observable in a subdomain of supercritical phase. Furthermore, the simultaneous disappearance of both these effects at elevated temperatures is a manifestation of the Frenkel line. We expect that these findings will advance the current understanding of fluids under extreme thermodynamic conditions.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC00112704

OSTI ID:: 1237164

Report Number(s):: BNL-108218-2015-JA; R&D Project: LS001

Journal Information:: Journal of Physical Chemistry Letters, Vol. 6, Issue 15; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 40 works

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References (28)

Microscopic relaxation in supercritical and liquid neon Cunsolo, A.; Pratesi, G.; Verbeni, R. The Journal of Chemical Physics, Vol. 114, Issue 5 https://doi.org/10.1063/1.1334613	journal	February 2001
Structural and Collisional Relaxations in Liquids and Supercritical Fluids Bencivenga, F.; Cunsolo, A.; Krisch, M. Physical Review Letters, Vol. 98, Issue 8 https://doi.org/10.1103/PhysRevLett.98.085501	journal	February 2007
The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids Simeoni, G. G.; Bryk, T.; Gorelli, F. A. Nature Physics, Vol. 6, Issue 7 https://doi.org/10.1038/nphys1683	journal	June 2010
Symmetry breaking gives rise to energy spectra of three states of matter Bolmatov, Dima; Musaev, Edvard T.; Trachenko, K. Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02794	journal	September 2013
Thermodynamic behaviour of supercritical matter Bolmatov, Dima; Brazhkin, V. V.; Trachenko, K. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3331	journal	August 2013
Evidence for structural crossover in the supercritical state Bolmatov, Dima; Brazhkin, V. V.; Fomin, Yu. D. The Journal of Chemical Physics, Vol. 139, Issue 23 https://doi.org/10.1063/1.4844135	journal	December 2013
Structural Evolution of Supercritical CO ₂ across the Frenkel Line Bolmatov, Dima; Zav’yalov, D.; Gao, M. The Journal of Physical Chemistry Letters, Vol. 5, Issue 16 https://doi.org/10.1021/jz5012127	journal	August 2014
Short-Wavelength Sound Modes in Liquid Argon de Schepper, I. M.; Verkerk, P.; van Well, A. A. Physical Review Letters, Vol. 50, Issue 13 https://doi.org/10.1103/PhysRevLett.50.974	journal	March 1983
Liquid argon: Monte carlo and molecular dynamics calculations Barker, J. A.; Fisher, R. A.; Watts, R. O. Molecular Physics, Vol. 21, Issue 4 https://doi.org/10.1080/00268977100101821	journal	January 1971
Microscopic sound waves in dense Lennard-Jones fluids de Schepper, I. M.; van Rijs, J. C.; van Well, A. A. Physical Review A, Vol. 29, Issue 3 https://doi.org/10.1103/PhysRevA.29.1602	journal	March 1984
Water Phase Diagram Is Significantly Altered by Imidazolium Ionic Liquid Chaban, Vitaly V.; Prezhdo, Oleg V. The Journal of Physical Chemistry Letters, Vol. 5, Issue 10 https://doi.org/10.1021/jz500563q	journal	April 2014
Vapor–Liquid Coexistence and Critical Behavior of Ionic Liquids via Molecular Simulations Rai, Neeraj; Maginn, Edward J. The Journal of Physical Chemistry Letters, Vol. 2, Issue 12 https://doi.org/10.1021/jz200526z	journal	May 2011
Liquid–Liquid Phase Transition and Its Phase Diagram in Deeply-Cooled Heavy Water Confined in a Nanoporous Silica Matrix Wang, Zhe; Ito, Kanae; Leão, Juscelino B. The Journal of Physical Chemistry Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acs.jpclett.5b00827	journal	May 2015
Liquid-Phase Vibrational Strong Coupling George, Jino; Shalabney, Atef; Hutchison, James A. The Journal of Physical Chemistry Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acs.jpclett.5b00204	journal	March 2015
The phonon theory of liquid thermodynamics Bolmatov, D.; Brazhkin, V. V.; Trachenko, K. Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00421	journal	May 2012
Liquid heat capacity in the approach from the solid state: Anharmonic theory Bolmatov, Dima; Trachenko, Kostya Physical Review B, Vol. 84, Issue 5 https://doi.org/10.1103/PhysRevB.84.054106	journal	August 2011
Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions Mártin, Daniel A.; Cavagna, Andrea; Grigera, Tomás S. Physical Review Letters, Vol. 114, Issue 22 https://doi.org/10.1103/PhysRevLett.114.225901	journal	June 2015
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements Kantor, I.; Prakapenka, V.; Kantor, A. Review of Scientific Instruments, Vol. 83, Issue 12, Article No. 125102 https://doi.org/10.1063/1.4768541	journal	December 2012
The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source Rivers, Mark; Prakapenka, Vitali; Kubo, Atsushi High Pressure Research, Vol. 28, Issue 3 https://doi.org/10.1080/08957950802333593	journal	September 2008
Temperature-induced ruby fluorescence shifts up to a pressure of 15 GPa in an externally heated diamond anvil cell Rekhi, Sandeep; Dubrovinsky, Leonid; Saxena, Surendra High Temperatures-High Pressures, Vol. 31, Issue 3 https://doi.org/10.1068/htrt161	journal	January 1999
Quantum effects in the dynamics of He probed by inelastic x-ray scattering Verbeni, R.; Cunsolo, A.; Pratesi, G. Physical Review E, Vol. 64, Issue 2 https://doi.org/10.1103/PhysRevE.64.021203	journal	July 2001
Signatures of quantum behavior in the microscopic dynamics of liquid hydrogen and deuterium Cunsolo, A.; Colognesi, D.; Sampoli, M. The Journal of Chemical Physics, Vol. 123, Issue 11 https://doi.org/10.1063/1.2033807	journal	September 2005
Adiabatic and isothermal sound waves: The case of supercritical nitrogen Bencivenga, F.; Cunsolo, A.; Krisch, M. Europhysics Letters (EPL), Vol. 75, Issue 1 https://doi.org/10.1209/epl/i2006-10091-y	journal	July 2006
Mixing of Longitudinal and Transverse Dynamics in Liquid Water Sampoli, M.; Ruocco, G.; Sette, F. Physical Review Letters, Vol. 79, Issue 9 https://doi.org/10.1103/PhysRevLett.79.1678	journal	September 1997
Liquidlike Behavior of Supercritical Fluids Gorelli, F.; Santoro, M.; Scopigno, T. Physical Review Letters, Vol. 97, Issue 24 https://doi.org/10.1103/physrevlett.97.245702	journal	December 2006
Liquid heat capacity in the approach from the solid state: anharmonic theory Bolmatov, Dima; Trachenko, Kostya arXiv https://doi.org/10.48550/arxiv.1103.4011	text	January 2011
Thermodynamic behavior of supercritical matter Bolmatov, Dima; Brazhkin, V. V.; Trachenko, K. arXiv https://doi.org/10.48550/arxiv.1303.3153	text	January 2013
Adiabatic and isothermal sound waves: the case of supercritical nitrogen Bencivenga, F.; Cunsolo, A.; Krisch, M. arXiv https://doi.org/10.48550/arxiv.cond-mat/0512383	text	January 2005

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Revealing the mechanism of passive transport in lipid bilayers via phonon-mediated nanometre-scale density fluctuations Zhernenkov, Mikhail; Bolmatov, Dima; Soloviov, Dmitry Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11575	journal	May 2016
Continuum mechanics and thermodynamics in the Hamilton and the Godunov-type formulations Peshkov, Ilya; Pavelka, Michal; Romenski, Evgeniy Continuum Mechanics and Thermodynamics, Vol. 30, Issue 6 https://doi.org/10.1007/s00161-018-0621-2	journal	January 2018
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A Unified Hyperbolic Formulation for Viscous Fluids and Elastoplastic Solids Dumbser, Michael; Peshkov, Ilya; Romenski, Evgeniy Theory, Numerics and Applications of Hyperbolic Problems II https://doi.org/10.1007/978-3-319-91548-7_34	book	January 2018
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Thermally triggered phononic gaps in liquids at THz scale Bolmatov, Dima; Zhernenkov, Mikhail; Zav’yalov, Dmitry Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19469	journal	January 2016
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