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Title: A versatile synthetic route for the preparation of titanium metal–organic frameworks

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/C5SC03620H· OSTI ID:1236869

Through a versatile synthetic strategy, High Valence Metathesis and Oxidation (HVMO), a series of Ti-MOFs with predesigned topologies and structures were synthesized.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office; USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001015
OSTI ID:
1236869
Alternate ID(s):
OSTI ID: 1386963
Journal Information:
Chemical Science, Vol. 7, Issue 2; ISSN 2041-6520
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
ENGLISH
Citation Metrics:
Cited by: 89 works
Citation information provided by
Web of Science

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Explosives in the Cage: Metal-Organic Frameworks for High-Energy Materials Sensing and Desensitization journal July 2017
Titanium(IV) Inclusion as a Versatile Route to Photoactivity in Metal–Organic Frameworks journal August 2019
Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster journal October 2018
Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping journal June 2018
Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster journal October 2018
A Porphyrin-Based Porous rtl Metal-Organic Framework as an Efficient Catalyst for the Cycloaddition of CO 2 to Epoxides journal October 2016
Designed Cluster Assembly of Multidimensional Titanium Coordination Polymers: Syntheses, Crystal Structure and Properties journal February 2018
Synthetic Strategies and Structural Arrangements of Isoreticular Mixed‐Component Metal–Organic Frameworks journal January 2019
Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst journal October 2018
Robust Ti- and Zr-Based Metal-Organic Frameworks for Photocatalysis journal February 2017
Recent Advances in Photocatalysis over Metal–Organic Frameworks‐Based Materials journal December 2019
A Co II -based metal–organic framework based on [Co 63 -OH) 4 ] units exhibiting selective sorption of C 2 H 2 over CO 2 and CH 4 journal January 2016
[Ti 12 In 6 O 18 (OOCC 6 H 5 ) 30 ]: a multifunctional hetero-polyoxotitanate nanocluster with high stability and visible photoactivity journal January 2017
Self-assembly of two supramolecular indium( iii ) metal–organic frameworks for reversible iodine capture and large band gap change semiconductor behavior journal January 2016
Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO 2 under blue light journal January 2017
A dual-functional indium–organic framework towards organic pollutant decontamination via physically selective adsorption and chemical photodegradation journal January 2017
Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal–organic framework via the hetero-metal doping of the linear trimetallic secondary building unit journal January 2018
An anionic metal–organic framework: metathesis of zinc( ii ) with copper( ii ) for efficient C 3 /C 2 hydrocarbon and organic dye separation journal January 2018
De novo synthesis of mesoporous photoactive titanium( iv )–organic frameworks with MIL-100 topology journal January 2019
The photo-, electro- and photoelectro-catalytic properties and application prospects of porous coordinate polymers journal January 2018
A novel route for the generation of Co/CoZn/CoNi layered double hydroxides at ambient temperature journal January 2019
A new post-synthetic polymerization strategy makes metal–organic frameworks more stable journal January 2019
Syntheses, structures and properties of two zinc(II) coordination complexes based on two bis(pyridyl)-bis(amide) ligands and 1,2-phenylenediacetic acid journal December 2019
Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping journal June 2018

Figures / Tables (6)