Temperature effects on nanostructure and mechanical properties of single-nanoparticle thick membranes.

Salerno, Kenneth Michael; Grest, Gary S.

doi:10.1039/C4FD00249K

Title: Temperature effects on nanostructure and mechanical properties of single-nanoparticle thick membranes.

Journal Article · Thu Apr 30 00:00:00 EDT 2015 · Faraday Discussions

DOI:https://doi.org/10.1039/C4FD00249K· OSTI ID:1235364

Salerno, Kenneth Michael ^[1]; Grest, Gary S. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

In this study, the properties of mechanically stable single-nanoparticle (NP)-thick membranes have largely been studied at room temperature. How these membranes soften as nanoparticle ligands disorder with increasing temperature is unknown. Molecular dynamics simulations are used to probe the temperature dependence of the mechanical and nanostructural properties of nanoparticle membranes made of 6 nm diameter Au nanoparticles coated with dodecanethiol ligands and terminated with either methyl (CH₃) or carboxyl (COOH) terminal groups. For methyl-terminated ligands, interactions along the alkane chain provide mechanical stiffness, with a Young's modulus of 1.7 GPa at 300 K. For carboxyl-terminated chains, end-group interactions are significant, producing stiffer membranes at all temperatures, with a Young's modulus of 3.8 GPa at 300 K. For both end-group types, membrane stiffness is reduced to zero at about 400 K. Ligand structure and mechanical properties of membranes at 300 K that have been annealed at 400 K are comparable to samples that do not undergo thermal annealing.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1235364

Report Number(s):: SAND-2015-0563J; FDISE6; 562455

Journal Information:: Faraday Discussions, Vol. 181, Issue 69; ISSN 1359-6640

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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