Structural dynamics inside a functionalized metal–organic framework probed by ultrafast 2D IR spectroscopy

Nishida, Jun; Tamimi, Amr; Fei, Honghan; Pullen, Sonja; Ott, Sascha; Cohen, Seth M.; Fayer, Michael D.

doi:10.1073/pnas.1422194112

Title: Structural dynamics inside a functionalized metal–organic framework probed by ultrafast 2D IR spectroscopy

Journal Article · Mon Dec 15 00:00:00 EST 2014 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1422194112· OSTI ID:1235140

Nishida, Jun ^[1]; Tamimi, Amr ^[1]; Fei, Honghan ^[2]; Pullen, Sonja ^[3]; Ott, Sascha ^[3]; Cohen, Seth M. ^[2]; Fayer, Michael D. ^[1]

Department of Chemistry, Stanford University, Stanford, CA 94305,
Department of Chemistry and Biochemistry, University of California, San Diego, CA 92093, and
Department of Chemistry, Ångström Laboratory, Uppsala University, 75120 Uppsala, Sweden

One key property of metal-organic frameworks (MOFs) are their structural elasticity. IHere we show that 2D IR spectroscopy with pulse-shaping techniques can probe the ultrafast structural fluctuations of MOFs. 2D IR data, obtained from a vibrational probe attached to the linkers of UiO-66 MOF in low concentration, revealed that the structural fluctuations have time constants of 7 and 670 ps with no solvent. Filling the MOF pores with dimethylformamide (DMF) slows the structural fluctuations by reducing the ability of the MOF to undergo deformations, and the dynamics of the DMF molecules are also greatly restricted. Finally, methodology advances were required to remove the severe light scattering caused by the macroscopic-sized MOF particles, eliminate interfering oscillatory components from the 2D IR data, and address Förster vibrational excitation transfer.

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Research Organization:: Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG03-84ER13251

OSTI ID:: 1235140

Alternate ID(s):: OSTI ID: 1347956

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Vol. 111 Journal Issue: 52; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 66 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
2D IR spectroscopy
metal–organic framework
UiO-66 MOF
ultrafast structural fluctuations
solvent confinement effect

Title: Structural dynamics inside a functionalized metal–organic framework probed by ultrafast 2D IR spectroscopy

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