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Title: The meaning of the “universal” WLF parameters of glass-forming polymer liquids

Journal Article · · The Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4905216· OSTI ID:1228469
 [1];  [2];  [1]
  1. The James Franck Institute and the Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA
  2. Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
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Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0008631
OSTI ID:
1228469
Journal Information:
The Journal of Chemical Physics, Journal Name: The Journal of Chemical Physics Vol. 142 Journal Issue: 1; ISSN 0021-9606
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 33 works
Citation information provided by
Web of Science

References (19)

Low-Temperature Relaxation and Entropic Barriers in Supercooled Liquids journal October 1994
Advances in the generalized entropy theory of glass-formation in polymer melts journal December 2014
Adam-Gibbs Formulation of Nonlinear Enthalpy Relaxation journal January 1990
Molecular Weight Dependence of Fragility in Polymers journal September 2009
Die Abhängigkeit der Viscosität von der Temperatur bie unterkühlten Flüssigkeiten journal October 1926
Glass temperature of copolymers journal October 1959
Analysis of Recent Measurements of the Viscosity of Glasses journal June 1925
Entropy and fragility in supercooling liquids journal March 1997
Fragilities of liquids predicted from the random first order transition theory of glasses journal March 2000
The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids journal July 1955
On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids journal July 1965
Effects of annealing and prior history on enthalpy relaxation in glassy polymers. 6. Adam-Gibbs formulation of nonlinearity journal November 1987
Adam-Gibbs formulation of non-linear enthalpy relaxation journal June 1991
Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids journal August 2006
Application of the entropy theory of glass formation to poly(α-olefins) journal September 2009
Communication: Towards first principles theory of relaxation in supercooled liquids formulated in terms of cooperative motion journal October 2014
Correlation of polymer segmental chain dynamics with temperature-dependent time-scale shifts journal September 1991
Why C1 = 16–17 in the WLF equation is physical—and the fragility of polymers journal January 1997
Lattice cluster theory for polymer melts with specific interactions journal July 2014

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