Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds

Nguyen, T. B.; Crounse, J. D.; Schwantes, R. H.; Teng, A. P.; Bates, K. H.; Zhang, X.; St. Clair, J. M.; Brune, W. H.; Tyndall, G. S.; Keutsch, F. N.; Seinfeld, J. H.; Wennberg, P. O.

doi:10.5194/acp-14-13531-2014

Title: Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds

Journal Article · Fri Dec 19 00:00:00 EST 2014 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-14-13531-2014· OSTI ID:1227793

Nguyen, T. B.; Crounse, J. D.; Schwantes, R. H.; Teng, A. P.; Bates, K. H.; Zhang, X.;

; Brune, W. H.; Tyndall, G. S.; Keutsch, F. N.; Seinfeld, J. H.; Wennberg, P. O.

The Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT) was a collaborative atmospheric chamber campaign that occurred during January 2014. FIXCIT is the laboratory component of a synergistic field and laboratory effort aimed toward (1) better understanding the chemical details behind ambient observations relevant to the southeastern United States, (2) advancing the knowledge of atmospheric oxidation mechanisms of important biogenic hydrocarbons, and (3) characterizing the behavior of field instrumentation using authentic standards. Approximately 20 principal scientists from 14 academic and government institutions performed parallel measurements at a forested site in Alabama and at the atmospheric chambers at Caltech. During the 4 week campaign period, a series of chamber experiments was conducted to investigate the dark- and photo-induced oxidation of isoprene, α-pinene, methacrolein, pinonaldehyde, acylperoxy nitrates, isoprene hydroxy nitrates (ISOPN), isoprene hydroxy hydroperoxides (ISOPOOH), and isoprene epoxydiols (IEPOX) in a highly controlled and atmospherically relevant manner. Pinonaldehyde and isomer-specific standards of ISOPN, ISOPOOH, and IEPOX were synthesized and contributed by campaign participants, which enabled explicit exploration into the oxidation mechanisms and instrument responses for these important atmospheric compounds. The present overview describes the goals, experimental design, instrumental techniques, and preliminary observations from the campaign. This work provides context for forthcoming publications affiliated with the FIXCIT campaign. Insights from FIXCIT are anticipated to aid significantly in interpretation of field data and the revision of mechanisms currently implemented in regional and global atmospheric models.

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Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0006626

OSTI ID:: 1227793

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Vol. 14 Journal Issue: 24; ISSN 1680-7324

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 52 works

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References (89)

Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds Nguyen, T. B.; Coggon, M. M.; Bates, K. H. Atmospheric Chemistry and Physics, Vol. 14, Issue 7 https://doi.org/10.5194/acp-14-3497-2014	journal	January 2014
Sequential oxidation products from tropospheric isoprene chemistry: MACR and MPAN at a NO _x -rich forest environment in the southeastern United States Nouaime, G.; Bertman, S. B.; Seaver, C. Journal of Geophysical Research: Atmospheres, Vol. 103, Issue D17 https://doi.org/10.1029/98JD00320	journal	September 1998
Product and Mechanistic Study of the Reaction of NO ₃ Radicals with α-Pinene Wängberg, I.; Barnes, I.; Becker, K. H. Environmental Science & Technology, Vol. 31, Issue 7 https://doi.org/10.1021/es960958n	journal	July 1997
Measurement of Gas-Phase Hydroperoxides by Chemical Ionization Mass Spectrometry Crounse, John D.; McKinney, Karena A.; Kwan, Alan J. Analytical Chemistry, Vol. 78, Issue 19 https://doi.org/10.1021/ac0604235	journal	October 2006
Calculation of conformationally weighted dipole moments useful in ion–molecule collision rate estimates Garden, Anna L.; Paulot, Fabien; Crounse, John D. Chemical Physics Letters, Vol. 474, Issue 1-3 https://doi.org/10.1016/j.cplett.2009.04.038	journal	May 2009
A Small, Low Flow, High Sensitivity Reaction Vessel for NO Chemiluminescence Detectors Ridley, B. A.; Grahek, F. E. Journal of Atmospheric and Oceanic Technology, Vol. 7, Issue 2 https://doi.org/10.1175/1520-0426(1990)007<0307:ASLFHS>2.0.CO;2	journal	April 1990
Laser-Induced Phosphorescence for the in Situ Detection of Glyoxal at Part per Trillion Mixing Ratios Huisman, Andrew J.; Hottle, John R.; Coens, Katherine L. Analytical Chemistry, Vol. 80, Issue 15 https://doi.org/10.1021/ac800407b	journal	August 2008
Isoprene oxidation by nitrate radical: alkyl nitrate and secondary organic aerosol yields Rollins, A. W.; Kiendler-Scharr, A.; Fry, J. L. Atmospheric Chemistry and Physics, Vol. 9, Issue 18 https://doi.org/10.5194/acp-9-6685-2009	journal	January 2009
Observational Insights into Aerosol Formation from Isoprene Worton, David R.; Surratt, Jason D.; LaFranchi, Brian W. Environmental Science & Technology, Vol. 47, Issue 20 https://doi.org/10.1021/es4011064	journal	September 2013
Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions Atkinson, Roger; Carter, William P. L. Chemical Reviews, Vol. 84, Issue 5 https://doi.org/10.1021/cr00063a002	journal	October 1984
Peroxy radical chemistry and OH radical production during the NO ₃ -initiated oxidation of isoprene Kwan, A. J.; Chan, A. W. H.; Ng, N. L. Atmospheric Chemistry and Physics, Vol. 12, Issue 16 https://doi.org/10.5194/acp-12-7499-2012	journal	January 2012
Proton transfer reaction mass spectrometry: on-line trace gas analysis at the ppb level Hansel, A.; Jordan, A.; Holzinger, R. International Journal of Mass Spectrometry and Ion Processes, Vol. 149-150 https://doi.org/10.1016/0168-1176(95)04294-U	journal	November 1995
Characterization of Vapor Wall Loss in Laboratory Chambers Loza, Christine L.; Chan, Arthur W. H.; Galloway, Melissa M. Environmental Science & Technology, Vol. 44, Issue 13 https://doi.org/10.1021/es100727v	journal	July 2010
Production of hydrogen peroxide and organic peroxides in the gas phase reactions of ozone with natural alkenes Simonaitis, R.; Olszyna, K. J.; Meagher, J. F. Geophysical Research Letters, Vol. 18, Issue 1 https://doi.org/10.1029/90GL02602	journal	January 1991
The Comparative Reactivity Method – a new tool to measure total OH Reactivity in ambient air Sinha, V.; Williams, J.; Crowley, J. N. Atmospheric Chemistry and Physics, Vol. 8, Issue 8 https://doi.org/10.5194/acp-8-2213-2008	journal	January 2008
Formation of hydroxymethyl hydroperoxide and formic acid in alkene ozonolysis in the presence of water vapour Neeb, Peter; Sauer, Frank; Horie, Osamu Atmospheric Environment, Vol. 31, Issue 10 https://doi.org/10.1016/S1352-2310(96)00322-6	journal	May 1997
Mechanismus der Ozonolyse Criegee, Rudolf Angewandte Chemie, Vol. 87, Issue 21 https://doi.org/10.1002/ange.19750872104	journal	November 1975
Computational Studies of the Isomerization and Hydration Reactions of Acetaldehyde Oxide and Methyl Vinyl Carbonyl Oxide Kuwata, Keith T.; Hermes, Matthew R.; Carlson, Matthew J. The Journal of Physical Chemistry A, Vol. 114, Issue 34 https://doi.org/10.1021/jp105358v	journal	September 2010
Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes: 2. Asymmetric and biogenic alkenes Hasson, Alam S.; Ho, Andy W.; Kuwata, Keith T. Journal of Geophysical Research: Atmospheres, Vol. 106, Issue D24 https://doi.org/10.1029/2001JD000598	journal	December 2001
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
Global modeling of secondary organic aerosol formation from aromatic hydrocarbons: high- vs. low-yield pathways Henze, D. K.; Seinfeld, J. H.; Ng, N. L. Atmospheric Chemistry and Physics, Vol. 8, Issue 9 https://doi.org/10.5194/acp-8-2405-2008	journal	January 2008
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species Atkinson, R.; Baulch, D. L.; Cox, R. A. Atmospheric Chemistry and Physics, Vol. 6, Issue 11 https://doi.org/10.5194/acp-6-3625-2006	journal	January 2006
Newly observed peroxides and the water effect on the formation and removal of hydroxyalkyl hydroperoxides in the ozonolysis of isoprene Huang, D.; Chen, Z. M.; Zhao, Y. Atmospheric Chemistry and Physics, Vol. 13, Issue 11 https://doi.org/10.5194/acp-13-5671-2013	journal	January 2013
Atmospheric Fate of Methacrolein. 2. Formation of Lactone and Implications for Organic Aerosol Production Kjaergaard, Henrik G.; Knap, Hasse C.; Ørnsø, Kristian B. The Journal of Physical Chemistry A, Vol. 116, Issue 24 https://doi.org/10.1021/jp210853h	journal	February 2012
Insights into hydroxyl measurements and atmospheric oxidation in a California forest Mao, J.; Ren, X.; Zhang, L. Atmospheric Chemistry and Physics, Vol. 12, Issue 17 https://doi.org/10.5194/acp-12-8009-2012	journal	January 2012
Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review Atkinson, Roger; Arey, Janet Atmospheric Environment, Vol. 37 https://doi.org/10.1016/S1352-2310(03)00391-1	journal	January 2003
A global model of natural volatile organic compound emissions Guenther, Alex; Hewitt, C. Nicholas; Erickson, David Journal of Geophysical Research, Vol. 100, Issue D5 https://doi.org/10.1029/94JD02950	journal	January 1995
Production of hydrogen peroxide in forest air by reaction of ozone with terpenes Becker, Karl H.; Brockmann, Klaus J.; Bechara, Joseph Nature, Vol. 346, Issue 6281 https://doi.org/10.1038/346256a0	journal	July 1990
Epoxide Pathways Improve Model Predictions of Isoprene Markers and Reveal Key Role of Acidity in Aerosol Formation Pye, Havala O. T.; Pinder, Robert W.; Piletic, Ivan R. Environmental Science & Technology, Vol. 47, Issue 19 https://doi.org/10.1021/es402106h	journal	September 2013
Effects of the substituents on the reactivity of carbonyl oxides. A theoretical study on the reaction of substituted carbonyl oxides with water Anglada, J. M.; González, J.; Torrent-Sucarrat, M. Physical Chemistry Chemical Physics, Vol. 13, Issue 28 https://doi.org/10.1039/c1cp20872a	journal	January 2011
Further IR spectroscopic evidence for the formation of CH2(OH)OOH in the gas-phase reaction of HO2 with CH2O Niki, H.; Maker, P. D.; Savage, C. M. Chemical Physics Letters, Vol. 75, Issue 3 https://doi.org/10.1016/0009-2614(80)80571-9	journal	November 1980
Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review Fuentes, J. D.; Gu, L.; Lerdau, M. Bulletin of the American Meteorological Society, Vol. 81, Issue 7 https://doi.org/10.1175/1520-0477(2000)081<1537:BHITAB>2.3.CO;2	journal	July 2000
Rate Constants and Products of the OH Reaction with Isoprene-Derived Epoxides Jacobs, Michael I.; Darer, Adam I.; Elrod, Matthew J. Environmental Science & Technology, Vol. 47, Issue 22 https://doi.org/10.1021/es403340g	journal	November 2013
Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs) Wolfe, Glenn M.; Crounse, John D.; Parrish, Jonathan D. Physical Chemistry Chemical Physics, Vol. 14, Issue 20 https://doi.org/10.1039/c2cp40388a	journal	January 2012
Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides Lin, Y. -H.; Zhang, H.; Pye, H. O. T. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1221150110	journal	April 2013
Measurement and speciation of gas phase peroxides in the atmosphere Lee, J. H.; Leahy, D. F.; Tang, I. N. Journal of Geophysical Research: Atmospheres, Vol. 98, Issue D2 https://doi.org/10.1029/92JD02514	journal	February 1993
HOx radical regeneration in the oxidation of isoprene Peeters, J.; Nguyen, T. L.; Vereecken, L. Physical Chemistry Chemical Physics, Vol. 11, Issue 28 https://doi.org/10.1039/b908511d	journal	January 2009
Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide Claeys, Magda; Wang, Wu; Ion, Alina C. Atmospheric Environment, Vol. 38, Issue 25 https://doi.org/10.1016/j.atmosenv.2004.06.001	journal	August 2004
Phase Transitions of Aqueous Atmospheric Particles Martin, Scot T. Chemical Reviews, Vol. 100, Issue 9 https://doi.org/10.1021/cr990034t	journal	September 2000
The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere Johnson, David; Marston, George Chemical Society Reviews, Vol. 37, Issue 4 https://doi.org/10.1039/b704260b	journal	January 2008
Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2 Welz, O.; Savee, J. D.; Osborn, D. L. Science, Vol. 335, Issue 6065 https://doi.org/10.1126/science.1213229	journal	January 2012
Gas Phase Production and Loss of Isoprene Epoxydiols Bates, Kelvin H.; Crounse, John D.; St. Clair, Jason M. The Journal of Physical Chemistry A, Vol. 118, Issue 7 https://doi.org/10.1021/jp4107958	journal	February 2014
Hydrogen peroxide and organic hydroperoxide in the troposphere: a review Lee, Meehye; Heikes, Brian G.; O'Sullivan, Daniel W. Atmospheric Environment, Vol. 34, Issue 21 https://doi.org/10.1016/S1352-2310(99)00432-X	journal	January 2000
Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation Liu, Y. J.; Herdlinger-Blatt, I.; McKinney, K. A. Atmospheric Chemistry and Physics, Vol. 13, Issue 11 https://doi.org/10.5194/acp-13-5715-2013	journal	January 2013
Peroxy radical isomerization in the oxidation of isoprene Crounse, John D.; Paulot, Fabien; Kjaergaard, Henrik G. Physical Chemistry Chemical Physics, Vol. 13, Issue 30 https://doi.org/10.1039/c1cp21330j	journal	January 2011
First direct measurements of formaldehyde flux via eddy covariance: implications for missing in-canopy formaldehyde sources DiGangi, J. P.; Boyle, E. S.; Karl, T. Atmospheric Chemistry and Physics, Vol. 11, Issue 20 https://doi.org/10.5194/acp-11-10565-2011	journal	January 2011
Conversion of hydroperoxides to carbonyls in field and laboratory instrumentation: Observational bias in diagnosing pristine versus anthropogenically controlled atmospheric chemistry Rivera‐Rios, J. C.; Nguyen, T. B.; Crounse, J. D. Geophysical Research Letters, Vol. 41, Issue 23 https://doi.org/10.1002/2014GL061919	journal	December 2014
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Evidence for formation of a PAN analogue of pinonic structure and investigation of its thermal stability Nozière, Barbara; Barnes, Ian Journal of Geophysical Research: Atmospheres, Vol. 103, Issue D19 https://doi.org/10.1029/98JD01677	journal	October 1998
Formation of hydrogen peroxide in the ozonolysis of isoprene and simple alkenes under humid conditions Sauer, Frank; Schäfer, Christian; Neeb, Peter Atmospheric Environment, Vol. 33, Issue 2 https://doi.org/10.1016/S1352-2310(98)00152-6	journal	January 1999
Measurement of Absolute Unimolecular and Bimolecular Rate Constants for CH ₃ CHOO Generated by the trans -2-Butene Reaction with Ozone in the Gas Phase Fenske, Jill D.; Hasson, Alam S.; Ho, Andy W. The Journal of Physical Chemistry A, Vol. 104, Issue 44 https://doi.org/10.1021/jp0016636	journal	November 2000
Chemical and microphysical characterization of ambient aerosols with the aerodyne aerosol mass spectrometer Canagaratna, M. R.; Jayne, J. T.; Jimenez, J. L. Mass Spectrometry Reviews, Vol. 26, Issue 2 https://doi.org/10.1002/mas.20115	journal	January 2007
A high-resolution mass spectrometer to measure atmospheric ion composition Junninen, H.; Ehn, M.; Petäjä, T. Atmospheric Measurement Techniques, Vol. 3, Issue 4 https://doi.org/10.5194/amt-3-1039-2010	journal	January 2010
Role of aldehyde chemistry and NO _x concentrations in secondary organic aerosol formation Chan, A. W. H.; Chan, M. N.; Surratt, J. D. Atmospheric Chemistry and Physics, Vol. 10, Issue 15 https://doi.org/10.5194/acp-10-7169-2010	journal	January 2010
Pressure Dependence of Stabilized Criegee Intermediate Formation from a Sequence of Alkenes Drozd, Greg T.; Donahue, Neil M. The Journal of Physical Chemistry A, Vol. 115, Issue 17 https://doi.org/10.1021/jp2001089	journal	May 2011
The Chemistry of Atmosphere-Forest Exchange (CAFE) Model – Part 2: Application to BEARPEX-2007 observations Wolfe, G. M.; Thornton, J. A.; Bouvier-Brown, N. C. Atmospheric Chemistry and Physics, Vol. 11, Issue 3 https://doi.org/10.5194/acp-11-1269-2011	journal	January 2011
An Experimental Protocol for the Determination of OH Radical Rate Constants with Organics Using Methyl Nitrite Photolysis as an OH Radical Source Atkinson, Roger; Carter, William P. L.; Winer, Arthur M. Journal of the Air Pollution Control Association, Vol. 31, Issue 10 https://doi.org/10.1080/00022470.1981.10465331	journal	October 1981
Organic aerosol formation from the oxidation of biogenic hydrocarbons Griffin, Robert J.; Cocker, David R.; Flagan, Richard C. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D3 https://doi.org/10.1029/1998JD100049	journal	February 1999
Measurements of PAN, PPN, and MPAN made during the 1994 and 1995 Nashville Intensives of the Southern Oxidant Study: Implications for regional ozone production from biogenic hydrocarbons Roberts, James M.; Williams, Jonathan; Baumann, Karsten Journal of Geophysical Research: Atmospheres, Vol. 103, Issue D17 https://doi.org/10.1029/98JD01637	journal	September 1998
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer DeCarlo, Peter F.; Kimmel, Joel R.; Trimborn, Achim Analytical Chemistry, Vol. 78, Issue 24 https://doi.org/10.1021/ac061249n	journal	December 2006
A thermal dissociation laser-induced fluorescence instrument for in situ detection of NO ₂ , peroxy nitrates, alkyl nitrates, and HNO ₃ : DETECTION OF NO Day, D. A.; Wooldridge, P. J.; Dillon, M. B. Journal of Geophysical Research: Atmospheres, Vol. 107, Issue D6 https://doi.org/10.1029/2001JD000779	journal	March 2002
A PAN analog from isoprene photooxidation Bertman, Steven B.; Roberts, James M. Geophysical Research Letters, Vol. 18, Issue 8 https://doi.org/10.1029/91GL01852	journal	August 1991
A large source of low-volatility secondary organic aerosol Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard Nature, Vol. 506, Issue 7489 https://doi.org/10.1038/nature13032	journal	February 2014
Eddy covariance fluxes of acyl peroxy nitrates (PAN, PPN and MPAN) above a Ponderosa pine forest Wolfe, G. M.; Thornton, J. A.; Yatavelli, R. L. N. Atmospheric Chemistry and Physics, Vol. 9, Issue 2 https://doi.org/10.5194/acp-9-615-2009	journal	January 2009
Autoxidation of Organic Compounds in the Atmosphere Crounse, John D.; Nielsen, Lasse B.; Jørgensen, Solvejg The Journal of Physical Chemistry Letters, Vol. 4, Issue 20 https://doi.org/10.1021/jz4019207	journal	September 2013
Low-volatility poly-oxygenates in the OH-initiated atmospheric oxidation of α-pinene: impact of non-traditional peroxyl radical chemistry Vereecken, L.; Müller, J. -F.; Peeters, J. Physical Chemistry Chemical Physics, Vol. 9, Issue 38 https://doi.org/10.1039/b708023a	journal	January 2007
Mechanism of HO _x Formation in the Gas-Phase Ozone−Alkene Reaction. 1. Direct, Pressure-Dependent Measurements of Prompt OH Yields ^† Kroll, Jesse H.; Clarke, James S.; Donahue, Neil M. The Journal of Physical Chemistry A, Vol. 105, Issue 9 https://doi.org/10.1021/jp002121r	journal	March 2001
On Rates and Mechanisms of OH and O ₃ Reactions with Isoprene-Derived Hydroxy Nitrates Lee, Lance; Teng, Alex P.; Wennberg, Paul O. The Journal of Physical Chemistry A, Vol. 118, Issue 9 https://doi.org/10.1021/jp4107603	journal	February 2014
Isoprene photooxidation: new insights into the production of acids and organic nitrates Paulot, F.; Crounse, J. D.; Kjaergaard, H. G. Atmospheric Chemistry and Physics, Vol. 9, Issue 4 https://doi.org/10.5194/acp-9-1479-2009	journal	January 2009
Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis Jacobs, M. I.; Burke, W. J.; Elrod, M. J. Atmospheric Chemistry and Physics, Vol. 14, Issue 17 https://doi.org/10.5194/acp-14-8933-2014	journal	January 2014
Importance of biogenic precursors to the budget of organic nitrates: observations of multifunctional organic nitrates by CIMS and TD-LIF during BEARPEX 2009 Beaver, M. R.; Clair, J. M. St.; Paulot, F. Atmospheric Chemistry and Physics, Vol. 12, Issue 13 https://doi.org/10.5194/acp-12-5773-2012	journal	January 2012
Adventures in ozoneland: down the rabbit-hole Donahue, Neil M.; Drozd, Greg T.; Epstein, Scott A. Physical Chemistry Chemical Physics, Vol. 13, Issue 23 https://doi.org/10.1039/c0cp02564j	journal	January 2011
A product study of the isoprene+NO ₃ reaction Perring, A. E.; Wisthaler, A.; Graus, M. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-4945-2009	journal	January 2009
Prompt deliquescence and efflorescence of aerosol nanoparticles Biskos, G.; Paulsen, D.; Russell, L. M. Atmospheric Chemistry and Physics, Vol. 6, Issue 12 https://doi.org/10.5194/acp-6-4633-2006	journal	January 2006
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds Lin, Ying-Hsuan; Zhang, Zhenfa; Docherty, Kenneth S. Environmental Science & Technology, Vol. 46, Issue 1 https://doi.org/10.1021/es202554c	journal	November 2011
Hydroxymethyl hydroperoxide and bis(hydroxymethyl) peroxide from gas-phase ozonolysis of naturally occurring alkenes Gäb, S.; Hellpointner, E.; Turner, W. V. Nature, Vol. 316, Issue 6028 https://doi.org/10.1038/316535a0	journal	August 1985
Chemical ionization tandem mass spectrometer for the in situ measurement of methyl hydrogen peroxide St. Clair, Jason M.; McCabe, David C.; Crounse, John D. Review of Scientific Instruments, Vol. 81, Issue 9 https://doi.org/10.1063/1.3480552	journal	September 2010
Ozonolyses of Acetylenes: Trapping of α-Oxo Carbonyl Oxides by Carbonyl Compounds and Stabilization of α-Oxo Ozonides by Derivatizations Griesbaum, Karl; Dong, Yuxiang; McCullough, Kevin J. The Journal of Organic Chemistry, Vol. 62, Issue 18 https://doi.org/10.1021/jo9701795	journal	September 1997
A Laser Induced Fluorescence-Based Instrument for In-Situ Measurements of Atmospheric Formaldehyde Hottle, John R.; Huisman, Andrew J.; DiGangi, Joshua P. Environmental Science & Technology, Vol. 43, Issue 3 https://doi.org/10.1021/es801621f	journal	February 2009
Products of the Gas-Phase Reactions of O3 with Alkenes Atkinson, Roger.; Tuazon, Ernesto C.; Aschmann, Sara M. Environmental Science & Technology, Vol. 29, Issue 7 https://doi.org/10.1021/es00007a025	journal	July 1995
Secondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO ₃ ) Ng, N. L.; Kwan, A. J.; Surratt, J. D. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4117-2008	journal	January 2008
Atmospheric oxidation capacity sustained by a tropical forest Lelieveld, J.; Butler, T. M.; Crowley, J. N. Nature, Vol. 452, Issue 7188 https://doi.org/10.1038/nature06870	journal	April 2008
Airborne measurement of OH reactivity during INTEX-B Mao, J.; Ren, X.; Brune, W. H. Atmospheric Chemistry and Physics, Vol. 9, Issue 1 https://doi.org/10.5194/acp-9-163-2009	journal	January 2009
First measurements of H2O2 and organic peroxides surface fluxes by the relaxed eddy-accumulation technique Valverde-Canossa, J.; Ganzeveld, L.; Rappenglück, B. Atmospheric Environment, Vol. 40 https://doi.org/10.1016/j.atmosenv.2006.03.038	journal	January 2006
Gas-Phase Ozonolysis of Alkenes: Formation of OH from Anti Carbonyl Oxides Kroll, Jesse H.; Donahue, Neil M.; Cee, Victor J. Journal of the American Chemical Society, Vol. 124, Issue 29 https://doi.org/10.1021/ja0266060	journal	July 2002
α-pinene photooxidation under controlled chemical conditions – Part 1: Gas-phase composition in low- and high-NO _x environments Eddingsaas, N. C.; Loza, C. L.; Yee, L. D. Atmospheric Chemistry and Physics, Vol. 12, Issue 14 https://doi.org/10.5194/acp-12-6489-2012	journal	January 2012
An Iodide-Adduct High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer: Application to Atmospheric Inorganic and Organic Compounds Lee, Ben H.; Lopez-Hilfiker, Felipe D.; Mohr, Claudia Environmental Science & Technology, Vol. 48, Issue 11 https://doi.org/10.1021/es500362a	journal	May 2014
An online ultra-high sensitivity Proton-transfer-reaction mass-spectrometer combined with switchable reagent ion capability (PTR+SRI−MS) Jordan, A.; Haidacher, S.; Hanel, G. International Journal of Mass Spectrometry, Vol. 286, Issue 1 https://doi.org/10.1016/j.ijms.2009.06.006	journal	September 2009
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene Paulot, F.; Crounse, J. D.; Kjaergaard, H. G. Science, Vol. 325, Issue 5941 https://doi.org/10.1126/science.1172910	journal	August 2009

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