31P-Edited Diffusion-Ordered 1H NMR Spectroscopy for the Isolation and Identification of Organophosphorus Compounds Related to Chemical Weapons Agents and their Degradation Products

Mayer, B P; Valdez, C A; Hok, S; Chinn, S C; Hart, B R

doi:10.1021/ac302788x

Title: 31P-Edited Diffusion-Ordered 1H NMR Spectroscopy for the Isolation and Identification of Organophosphorus Compounds Related to Chemical Weapons Agents and their Degradation Products

Journal Article · Tue Sep 25 00:00:00 EDT 2012 · Analytical Chemistry

DOI:https://doi.org/10.1021/ac302788x· OSTI ID:1226214

Mayer, B P; Valdez, C A; Hok, S; Chinn, S C; Hart, B R

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Research Organization:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-07NA27344

OSTI ID:: 1226214

Report Number(s):: LLNL-JRNL-585213

Journal Information:: Analytical Chemistry, Vol. 84, Issue 23; ISSN 0003-2700

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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Application of high performance liquid chromatography coupled to on-line solid-phase extraction-nuclear magnetic resonance spectroscopy for the analysis of degradation products of V-class nerve agents and nitrogen mustard Mazumder, Avik; Kumar, Ajeet; Purohit, Ajay K. Journal of Chromatography A, Vol. 1217, Issue 17 https://doi.org/10.1016/j.chroma.2010.02.071	journal	April 2010
Determination of Trace Amounts of Chemical Warfare Agent Degradation Products in Decontamination Solutions with NMR Spectroscopy Koskela, Harri; Rapinoja, Marja-Leena; Kuitunen, Marja-Leena Analytical Chemistry, Vol. 79, Issue 23 https://doi.org/10.1021/ac0713196	journal	December 2007
On-Flow Pulsed Field Gradient Heteronuclear Correlation Spectrometry in Off-Line LC−SPE−NMR Analysis of Chemicals Related to the Chemical Weapons Convention Koskela, Harri; Ervasti, Mia; Björk, Heikki Analytical Chemistry, Vol. 81, Issue 3 https://doi.org/10.1021/ac802407t	journal	January 2009
Structural Characterization of Chemical Warfare Agent Degradation Products in Decontamination Solutions with Proton Band-Selective ¹ H− ³¹ P NMR Spectroscopy Koskela, Harri; Hakala, Ullastiina; Vanninen, Paula Analytical Chemistry, Vol. 82, Issue 12 https://doi.org/10.1021/ac100867x	journal	May 2010
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DOSY-NOESY: Diffusion-Ordered NOESY Gozansky, Elliott K.; Gorenstein, David G. Journal of Magnetic Resonance, Series B, Vol. 111, Issue 1 https://doi.org/10.1006/jmrb.1996.0066	journal	April 1996
A Three-Dimensional DOSY–HMQC Experiment for the High-Resolution Analysis of Complex Mixtures Barjat, Hervé; Morris, Gareth A.; Swanson, Alistair G. Journal of Magnetic Resonance, Vol. 131, Issue 1 https://doi.org/10.1006/jmre.1997.1332	journal	March 1998
Constant time gradient HSQC-iDOSY: practical aspects: Constant time gradient HSQC-iDOSY McLachlan, A. S.; Richards, J. J.; Bilia, A. R. Magnetic Resonance in Chemistry, Vol. 47, Issue 12 https://doi.org/10.1002/mrc.2518	journal	September 2009
The qualitative probing of hydrogen bond strength by diffusion-ordered NMR spectroscopy Kapur, Gurpreet S.; Cabrita, Eurico J.; Berger, Stefan Tetrahedron Letters, Vol. 41, Issue 37 https://doi.org/10.1016/S0040-4039(00)01188-6	journal	September 2000
Probing the Molecular Interaction of Chymotrypsin with Organophosphorus Compounds by ³¹ P Diffusion NMR in Aqueous Solutions Segev, Omri; Columbus, Ishay; Ashani, Yacov The Journal of Organic Chemistry, Vol. 70, Issue 1 https://doi.org/10.1021/jo0485942	journal	January 2005
Reversible, High Molecular Weight Palladium and Platinum Coordination Polymers Based on Phosphorus Ligands Paulusse, Jos M. J.; Huijbers, Jeroen P. J.; Sijbesma, Rint P. Macromolecules, Vol. 38, Issue 15 https://doi.org/10.1021/ma050561g	journal	July 2005
Internally Referenced Diffusion Coefficient−Formula Weight (D-FW) Analysis of ³¹ P Diffusion-Ordered NMR Spectroscopy (DOSY) Kagan, Gerald; Li, Weibin; Hopson, Russell Organic Letters, Vol. 11, Issue 21 https://doi.org/10.1021/ol9019106	journal	September 2009
Toward a Small Molecule, Biomimetic Carbonic Anhydrase Model: Theoretical and Experimental Investigations of a Panel of Zinc(II) Aza-Macrocyclic Catalysts Koziol, Lucas; Valdez, Carlos A.; Baker, Sarah E. Inorganic Chemistry, Vol. 51, Issue 12 https://doi.org/10.1021/ic300526b	journal	June 2012
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