Determining whether metals nucleate homogeneously on graphite: A case study with copper

Appy, David; Lei, Huaping; Han, Yong; Wang, Cai -Zhuang; Tringides, Michael C.; Shao, Dahai; Kwolek, Emma J.; Evans, J. W.; Thiel, P. A.

doi:10.1103/PhysRevB.90.195406

Title: Determining whether metals nucleate homogeneously on graphite: A case study with copper

Journal Article · Wed Nov 05 00:00:00 EST 2014 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.90.195406· OSTI ID:1225534

Appy, David ^[1]; Lei, Huaping ^[2]; Han, Yong ^[1]; Wang, Cai -Zhuang ^[3]; Tringides, Michael C. ^[1]; Shao, Dahai ^[1]; Kwolek, Emma J. ^[4]; Evans, J. W. ^[1]; Thiel, P. A. ^[1]

Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States); Institute of Solid State Physics, CAS (China)
Ames Lab., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States)

In this study, we observe that Cu clusters grow on surface terraces of graphite as a result of physical vapor deposition in ultrahigh vacuum. We show that the observation is incompatible with a variety of models incorporating homogeneous nucleation and calculations of atomic-scale energetics. An alternative explanation, ion-mediated heterogeneous nucleation, is proposed and validated, both with theory and experiment. This serves as a case study in identifying when and whether the simple, common observation of metal clusters on carbon-rich surfaces can be interpreted in terms of homogeneous nucleation. We describe a general approach for making system-specific and laboratory-specific predictions.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1225534

Alternate ID(s):: OSTI ID: 1180527

Report Number(s):: IS-J-8547; PRBMDO

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 90, Issue 19; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (35)

A comparative STM study of Ru nanoparticles deposited on HOPG by mass-selected gas aggregation versus thermal evaporation Nielsen, R. M.; Murphy, S.; Strebel, C. Surface Science, Vol. 603, Issue 24 https://doi.org/10.1016/j.susc.2009.10.005	journal	December 2009
Metals on graphene: correlation between adatom adsorption behavior and growth morphology Liu, Xiaojie; Wang, C. Z.; Hupalo, M. Physical Chemistry Chemical Physics, Vol. 14, Issue 25 https://doi.org/10.1039/c2cp40527j	journal	January 2012
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Graphite Nanofibers as an Electrode for Fuel Cell Applications Bessel, Carol A.; Laubernds, Kate; Rodriguez, Nelly M. The Journal of Physical Chemistry B, Vol. 105, Issue 6 https://doi.org/10.1021/jp003280d	journal	February 2001
Chemical accuracy for the van der Waals density functional Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos Journal of Physics: Condensed Matter, Vol. 22, Issue 2 https://doi.org/10.1088/0953-8984/22/2/022201	journal	December 2009
Density functional study of graphite bulk and surface properties Ooi, Newton; Rairkar, Asit; Adams, James B. Carbon, Vol. 44, Issue 2 https://doi.org/10.1016/j.carbon.2005.07.036	journal	February 2006
Transition metals on the (0 0 0 1) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology Appy, David; Lei, Huaping; Wang, Cai-Zhuang Progress in Surface Science, Vol. 89, Issue 3-4 https://doi.org/10.1016/j.progsurf.2014.08.001	journal	August 2014
Effects of substrate defect density and annealing temperature on the nature of Pt clusters vapor deposited on the basal plane of highly oriented pyrolytic graphite Howells, A. Solid State Ionics, Vol. 150, Issue 1-2 https://doi.org/10.1016/s0167-2738(02)00263-1	journal	September 2002
Effect of substrate surface defects on the morphology of Fe film deposited on graphite Kholmanov, I. N.; Gavioli, L.; Fanetti, M. Surface Science, Vol. 601, Issue 1 https://doi.org/10.1016/j.susc.2006.09.021	journal	January 2007
Ag nanoparticles on highly ordered pyrolytic graphite (HOPG) surfaces studied using STM and XPS Lopez-Salido, Ignacio; Lim, Dong Chan; Kim, Young Dok Surface Science, Vol. 588, Issue 1-3 https://doi.org/10.1016/j.susc.2005.05.021	journal	August 2005
Morphological evolution during epitaxial thin film growth: Formation of 2D islands and 3D mounds Evans, J. W.; Thiel, P. A.; Bartelt, M. C. Surface Science Reports, Vol. 61, Issue 1-2 https://doi.org/10.1016/j.surfrep.2005.08.004	journal	April 2006
Nucleation and growth of cobalt nanostructures on highly oriented pyrolytic graphite Poon, S. W.; Pan, J. S.; Tok, E. S. Physical Chemistry Chemical Physics, Vol. 8, Issue 28 https://doi.org/10.1039/b604627b	journal	January 2006
Improved description of soft layered materials with van der Waals density functional theory Graziano, Gabriella; Klimeš, Jiří; Fernandez-Alonso, Felix Journal of Physics: Condensed Matter, Vol. 24, Issue 42 https://doi.org/10.1088/0953-8984/24/42/424216	journal	October 2012
Surface Defects and Homogeneous Distribution of Silver Particles on HOPG Stabel, A.; Eichhorst-Gerner, K.; Rabe, J. P. Langmuir, Vol. 14, Issue 25 https://doi.org/10.1021/la9804334	journal	December 1998
Island formation during deposition or etching Bartelt, M. C.; Hannon, J. B.; Schmid, A. K. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 165, Issue 1-3 https://doi.org/10.1016/s0927-7757(99)00419-7	journal	May 2000
In situ TEM investigations of dendritic growth of Au particles on HOPG Anton, R.; Schneidereit, I. Physical Review B, Vol. 58, Issue 20 https://doi.org/10.1103/physrevb.58.13874	journal	November 1998
Mobile metal adatoms on single layer, bilayer, and trilayer graphene: An ab initio DFT study with van der Waals corrections correlated with electron microscopy data Hardcastle, T. P.; Seabourne, C. R.; Zan, R. Physical Review B, Vol. 87, Issue 19 https://doi.org/10.1103/physrevb.87.195430	journal	May 2013
Submonolayer growth of Pb on Cu( 111): surface alloying and de-alloying Nagl, C.; Haller, O.; Platzgummer, E. Surface Science, Vol. 321, Issue 3 https://doi.org/10.1016/0039-6028(94)90189-9	journal	December 1994
A general method for numerically simulating the stochastic time evolution of coupled chemical reactions Gillespie, Daniel T. Journal of Computational Physics, Vol. 22, Issue 4 https://doi.org/10.1016/0021-9991(76)90041-3	journal	December 1976
Van der Waals density functionals applied to solids Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/physrevb.83.195131	journal	May 2011
Metals on Graphene: Interactions, Growth Morphology, and Thermal Stability Liu, Xiaojie; Wang, Cai-Zhuang; Hupalo, Myron Crystals, Vol. 3, Issue 1 https://doi.org/10.3390/cryst3010079	journal	January 2013
Characterisation of the generation of ions in electron beam evaporator for the control of metal deposition processes Lyutovich, A.; Maile, K.; Gusko, A. Surface and Coatings Technology, Vol. 151-152 https://doi.org/10.1016/s0257-8972(01)01580-8	journal	March 2002
Controlled cluster condensation into preformed nanometer-sized pits Hövel, H.; Becker, Th.; Bettac, A. Journal of Applied Physics, Vol. 81, Issue 1 https://doi.org/10.1063/1.364003	journal	January 1997
The role of carbon materials in heterogeneous catalysis Rodríguez-reinoso, Francisco Carbon, Vol. 36, Issue 3 https://doi.org/10.1016/S0008-6223(97)00173-5	journal	January 1998
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Interlayer cohesive energy of graphite from thermal desorption of polyaromatic hydrocarbons Zacharia, Renju; Ulbricht, Hendrik; Hertel, Tobias Physical Review B, Vol. 69, Issue 15 https://doi.org/10.1103/PhysRevB.69.155406	journal	April 2004
First-principles determination of the structural, vibrational and thermodynamic properties of diamond, graphite, and derivatives Mounet, Nicolas; Marzari, Nicola Physical Review B, Vol. 71, Issue 20 https://doi.org/10.1103/PhysRevB.71.205214	journal	May 2005
Scaling analysis of diffusion-mediated island growth in surface adsorption processes Bartelt, M. C.; Evans, J. W. Physical Review B, Vol. 46, Issue 19 https://doi.org/10.1103/PhysRevB.46.12675	journal	November 1992
Parallel Nanoimprint Forming of One-Dimensional Chiral Semiconductor for Strain-Engineered Optical Properties Wang, Yixiu; Jin, Shengyu; Wang, Qingxiao Nano-Micro Letters, Vol. 12, Issue 1 https://doi.org/10.1007/s40820-020-00493-3	journal	August 2020
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020
Chemical accuracy for the van der Waals density functional Klimes, J.; Bowler, D. R.; Michaelides, A. arXiv https://doi.org/10.48550/arxiv.0910.0438	preprint	January 2009
Van der Waals density functionals applied to solids Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos arXiv https://doi.org/10.48550/arxiv.1102.1358	text	January 2011
The interlayer cohesive energy of graphite from thermal desorption of polyaromatic hydrocarbons Zacharia, Renju; Ulbricht, Hendrik; Hertel, Tobias arXiv https://doi.org/10.48550/arxiv.cond-mat/0308451	text	January 2003

Cited By (3)

Point island models for nucleation and growth of supported nanoclusters during surface deposition Han, Yong; Gaudry, Émilie; Oliveira, Tiago J. The Journal of Chemical Physics, Vol. 145, Issue 21 https://doi.org/10.1063/1.4954410	journal	December 2016
Spontaneous selective deposition of iron oxide nanoparticles on graphite as model catalysts de Alwis, Chathura; Leftwich, Timothy R.; Mukherjee, Pinaki Nanoscale Advances, Vol. 1, Issue 12 https://doi.org/10.1039/c9na00472f	journal	January 2019
Adsorption of dysprosium on the graphite (0001) surface: Nucleation and growth at 300 K Kwolek, Emma J.; Lei, Huaping; Lii-Rosales, Ann The Journal of Chemical Physics, Vol. 145, Issue 21 https://doi.org/10.1063/1.4953611	journal	December 2016

Similar Records

Determining whether metals nucleate homogeneously on graphite: A case study with copper

Journal Article · Sat Nov 01 00:00:00 EDT 2014 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1225534

Appy, David; Lei, Huaping; Han, Yong; +6 more

Enhancement of magnetocaloric effect in the Gd₂Al phase by Co alloying

Journal Article · Fri Nov 14 00:00:00 EST 2014 · Journal of Applied Physics · OSTI ID:1225534

Huang, Z. Y.; Fu, H.; Hadimani, R. L.; +4 more

Metal thin film growth on multimetallic surfaces: From quaternary metallic glass to binary crystal

Thesis/Dissertation · Fri Jan 01 00:00:00 EST 2010 · OSTI ID:1225534

Jing, Dapeng

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Determining whether metals nucleate homogeneously on graphite: A case study with copper

Citation Formats

References (35)

Cited By (3)

Similar Records

Related Subjects