skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Non-precious metal catalysts prepared from precursor comprising cyanamide

Patent ·
OSTI ID:1224451

Catalyst comprising graphitic carbon and methods of making thereof; said graphitic carbon comprising a metal species, a nitrogen-containing species and a sulfur containing species. A catalyst for oxygen reduction reaction for an alkaline fuel cell was prepared by heating a mixture of cyanamide, carbon black, and a salt selected from an iron sulfate salt and an iron acetate salt at a temperature of from about 700.degree. C. to about 1100.degree. C. under an inert atmosphere. Afterward, the mixture was treated with sulfuric acid at elevated temperature to remove acid soluble components, and the resultant mixture was heated again under an inert atmosphere at the same temperature as the first heat treatment step.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-06NA25396
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
Patent Number(s):
9,169,140
Application Number:
13/239,109
OSTI ID:
1224451
Resource Relation:
Patent File Date: 2011 Sep 21
Country of Publication:
United States
Language:
English

References (40)

Carbon-based composite electrocatalysts for low temperature fuel cells patent December 2009
Method for manufacturing carbon fibers, method for manufacturing electron-emitting device using the same, method for manufacturing electronic device, method for manufacturing image display device, and information display reproduction apparatus using the same patent-application December 2005
Metal-Free Vertically-Aligned Nitrogen-Doped Carbon Nanotube Catalyst for Fuel Cell Cathodes patent-application July 2010
Method for Producing Nitrogen-Doped Carbon Nanotubes patent-application November 2010
Electrocatalysts Using Porous Polymers and Method of Preparation patent-application November 2011
Synthesis and Evaluation of Heat-treated, Cyanamide-derived Non-precious Catalysts for Oxygen Reduction journal January 2009
Effect of the Pre-Treatment of Carbon Black Supports on the Activity of Fe-Based Electrocatalysts for the Reduction of Oxygen journal March 1999
Oxygen Reduction Catalysts for Polymer Electrolyte Fuel Cells from the Pyrolysis of Iron Acetate Adsorbed on Various Carbon Supports journal February 2003
Efficient access to bamboo-like carbon micro and nanofibres by pyrolysis of zinc cyanamide journal August 2001
Zinc cyanamide, Zn(CN2) journal April 2001
Effect of sulfur as a growth promoter for CNx nanostructures as PEM and DMFC ORR catalysts journal April 2010
Impact of Loading in RRDE Experiments on Fe–N–C Catalysts: Two- or Four-Electron Oxygen Reduction? journal January 2008
Influence of Aromatic Groups Incorporated in Long-Chain Alkanethiol Self-Assembled Monolayers on Gold journal June 2000
Biocompatibility and Toxicological Studies of Carbon Nanotubes Doped with Nitrogen journal August 2006
Preparation of carbon alloy catalysts for polymer electrolyte fuel cells from nitrogen-containing rigid-rod polymers journal September 2010
A Non-Precious Electrocatalyst for Oxygen Reduction Based on Simple Heat-Treated Precursors journal January 2008
Cyanamide-derived non-precious metal catalyst for oxygen reduction journal December 2010
Oxygen reduction catalysts for polymer electrolyte fuel cells from the pyrolysis of FeII acetate adsorbed on 3,4,9,10-perylenetetracarboxylic dianhydride journal January 1999
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction journal February 2009
Synthesis of g-C3N4 Nanoparticles in Mesoporous Silica Host Matrices journal July 2005
Influence of Sulfur on the Pyrolysis of CoTMPP as Electrocatalyst for the Oxygen Reduction Reaction journal January 2009
Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction journal January 1989
Organic dyestuffs as catalysts for fuel cells book January 1976
A New Fuel Cell Cathode Catalyst journal March 1964
Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction journal July 2009
Molecular Oxygen Reduction in PEM Fuel Cells:  Evidence for the Simultaneous Presence of Two Active Sites in Fe-Based Catalysts journal August 2002
Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction journal March 2010
Influence of Nitrogen Doping on Oxygen Reduction Electrocatalysis at Carbon Nanofiber Electrodes journal March 2005
Non-metal Catalysts for Dioxygen Reduction in an Acidic Electrolyte journal July 2006
pH-effect on oxygen reduction activity of Fe-based electro-catalysts journal October 2009
Nitrogen-doped carbon nanotubes as a cathode catalyst for the oxygen reduction reaction in alkaline medium journal March 2010
Development of high performance carbon composite catalyst for oxygen reduction reaction in PEM Proton Exchange Membrane fuel cells journal August 2008
Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis journal January 1995
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells journal February 2010
Oxygen electrocatalysis in alkaline electrolyte: Pt(hkl), Au(hkl) and the effect of Pd-modification journal August 2002
Efficient electrocatalytic oxygen reduction over metal free-nitrogen doped carbon nanocapsules journal January 2011
On the mechanism of possible influence of heteroatoms of nitrogen, boron and phosphorus in a carbon matrix on the catalytic activity of carbons in electron transfer reactions journal January 2000
Effect of Nitrogen Concentration on Capacitance, Density of States, Electronic Conductivity, and Morphology of N-Doped Carbon Nanotube Electrodes journal October 2009
Non-precious metal oxygen reduction catalyst for PEM fuel cells based on nitroaniline precursor journal April 2008
Efficient Metal-Free Oxygen Reduction in Alkaline Medium on High-Surface-Area Mesoporous Nitrogen-Doped Carbons Made from Ionic Liquids and Nucleobases journal January 2011