UV-Vis Spectroscopy as a Tool for Safeguards; Instrumentation installation and fundamental data collection
- Argonne National Lab. (ANL), Argonne, IL (United States)
Two spectrophotometric process monitors, one optimized for high concentration (approximately 10 g/L) and one for trace levels (approximately 10 ppm),were developed at Argonne and installed at the SRS H-Canyon facility for field testing. These systems were built of Commercial-Off-The-Shelf components utilizing a custom, facility-specific hardware interface. The systems directly provide a qualitative measurement of process chemistry (i.e. valence state). With appropriate calibrations the systems could provide quantitative data. Laboratory tests were performed to determine the spectrophotometric molar absorptivity coefficients for relevant actinide and transition metals of interest.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP)
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1221970
- Report Number(s):
- ANL/NE-15/7; 120663; TRN: US1500426
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL PROTECTION
SAVANNAH RIVER PLANT
TRANSITION ELEMENTS
CONCENTRATION RATIO
ABSORPTIVITY
INSTALLATION
MONITORS
SAFEGUARDS
SPECTROPHOTOMETERS
OPTICAL SPECTROMETERS
ULTRAVIOLET SPECTROMETERS
ACTINIDES
CANYONS
QUALITATIVE CHEMICAL ANALYSIS
EQUIPMENT INTERFACES
VALENCE
Actinide chemistry
Nuclear Safeguards
Process Monitoring
98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL PROTECTION
SAVANNAH RIVER PLANT
TRANSITION ELEMENTS
CONCENTRATION RATIO
ABSORPTIVITY
INSTALLATION
MONITORS
SAFEGUARDS
SPECTROPHOTOMETERS
OPTICAL SPECTROMETERS
ULTRAVIOLET SPECTROMETERS
ACTINIDES
CANYONS
QUALITATIVE CHEMICAL ANALYSIS
EQUIPMENT INTERFACES
VALENCE
Actinide chemistry
Nuclear Safeguards
Process Monitoring