skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Vibrational Spectral Signatures of Crystalline Cellulose Using High Resolution Broadband Sum Frequency Generation Vibrational Spectroscopy (HR-BB-SFG-VS)

Journal Article · · Cellulose

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Contributing Organization:
Washington State University, Richland, Washington; Pacific Northwest National Laboratory, Richland, Washington; Chinese Academy of Sciences, Beijing, China; State University of New York, Buffalo, New York; Georgia Institute of Technology, Atlanta, Georgia; University of Tennessee, Knoxville, Tennessee; Michigan State University, East Lansing, Michigan
OSTI ID:
1220800
Report Number(s):
NREL/JA-2700-64626
Journal Information:
Cellulose, Vol. 22, Issue 3
Country of Publication:
United States
Language:
English

References (58)

Vibrational Sum-Frequency Spectroscopy for Trace Chemical Detection on Surfaces at Stand-Off Distances journal March 2013
Native Cellulose: A Composite of Two Distinct Crystalline Forms journal January 1984
Selective Detection of Crystalline Cellulose in Plant Cell Walls with Sum-Frequency-Generation (SFG) Vibration Spectroscopy journal July 2011
Quantification of crystalline cellulose in lignocellulosic biomass using sum frequency generation (SFG) vibration spectroscopy and comparison with other analytical methods journal July 2012
Structure and Interactions of Plant Cell-Wall Polysaccharides by Two- and Three-Dimensional Magic-Angle-Spinning Solid-State NMR journal February 2011
Imaging Cellulose Using Atomic Force Microscopy book January 2012
Versatile derivatives of carbohydrate-binding modules for imaging of complex carbohydrates approaching the molecular level of resolution journal October 2006
Size, shape, and arrangement of native cellulose fibrils in maize cell walls journal December 2013
Nanostructure of cellulose microfibrils in spruce wood journal November 2011
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications journal June 2010
The confirmation of existences of cellulose IIII, IIIII, IVI, and IVII by the X-ray method journal January 1975
Undirectional degradation of valonia cellulose microcrystals subjected to cellulase action journal May 1985
Biomass Recalcitrance: Engineering Plants and Enzymes for Biofuels Production journal February 2007
Almost Pure Iα Cellulose in the Cell Wall of Glaucocystis journal October 1999
Solid-state CP/MAS carbon-13 NMR study of cellulose polymorphs journal July 1989
Cellulose microfibril orientation in onion (Allium cepa L.) epidermis studied by atomic force microscopy (AFM) and vibrational sum frequency generation (SFG) spectroscopy journal December 2013
Vibrational sum-frequency-generation (SFG) spectroscopy study of the structural assembly of cellulose microfibrils in reaction woods journal June 2014
Surface and Interface Spectroscopy of High Explosives and Binders: HMX and Estane journal April 2006
Characterization of crystalline cellulose in biomass: Basic principles, applications, and limitations of XRD, NMR, IR, Raman, and SFG journal October 2013
Crystalline cellulose: structure and hydrogen bonds journal May 2010
Atomic Force Microscopy Characterization of Cellulose Nanocrystals journal March 2010
CP/MAS -NMR spectroscopy applied to structure and interaction studies on cellulose I journal October 1999
Cellulose polymorphism study with sum-frequency-generation (SFG) vibration spectroscopy: identification of exocyclic CH2OH conformation and chain orientation journal April 2013
Sum-Frequency-Generation Vibration Spectroscopy and Density Functional Theory Calculations with Dispersion Corrections (DFT-D2) for Cellulose Iα and Iβ journal May 2013
Probing crystal structure and mesoscale assembly of cellulose microfibrils in plant cell walls, tunicate tests, and bacterial films using vibrational Sum Frequency Generation (SFG) spectroscopy journal January 2014
Infrared spectra of crystalline polysaccharides. II. Native celluloses in the region from 640 to 1700 cm.1 journal September 1959
Vibrational Polarization Spectroscopy of CH Stretching Modes of the Methylene Group at the Vapor/Liquid Interfaces with Sum Frequency Generation journal June 2004
C−H Stretching Vibrations of Methyl, Methylene and Methine Groups at the Vapor/Alcohol ( n = 1−8) Interfaces journal July 2005
Molecular ordering of cellulose after extraction of polysaccharides from primary cell walls of Arabidopsisthaliana: a solid-state CP/MAS 13C NMR study journal April 2002
Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy journal July 2003
Crystalline modifications of cellulose. Part II. A study with plane-polarized infrared radiation journal November 1958
Infrared spectra of the crystalline modifications of cellulose journal August 1956
Relation of certain infrared bands to cellulose crystallinity and crystal latticed type. Part I. Spectra of lattice types I, II, III and of amorphous cellulose journal May 1964
Solid-State 13C NMR Investigation of Molecular Ordering in the Cellulose of Apple Cell Walls journal July 1994
Crystal Structure and Hydrogen-Bonding System in Cellulose Iβ from Synchrotron X-ray and Neutron Fiber Diffraction journal August 2002
Crystal Structure and Hydrogen Bonding System in Cellulose I α from Synchrotron X-ray and Neutron Fiber Diffraction journal November 2003
Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance journal January 2010
Monitoring Meso-Scale Ordering of Cellulose in Intact Plant Cell Walls Using Sum Frequency Generation Spectroscopy journal August 2013
Effects of Plant Cell Wall Matrix Polysaccharides on Bacterial Cellulose Structure Studied with Vibrational Sum Frequency Generation Spectroscopy and X-ray Diffraction journal May 2014
Ring current enhanced vibrational circular dichroism in the carbon-hydrogen bond stretching motions of sugars journal April 1986
Plant Biomass Characterization: Application of Solution- and Solid-State NMR Spectroscopy book April 2013
Solid-state NMR characterization of switchgrass cellulose after dilute acid pretreatment journal January 2010
New Method for Determining the Degree of Cellulose I Crystallinity by Means of FT Raman Spectroscopy journal June 2005
Surface properties probed by second-harmonic and sum-frequency generation journal February 1989
Toward a Systems Approach to Understanding Plant Cell Walls journal December 2004
Orientation of cellulose microcrystals by strong magnetic fields journal August 1992
Surface Nonlinear Vibrational Spectroscopy of Energetic Materials:  HMX journal February 2007
Vibrational circular dichroism (VCD) studies on disaccharides in the CH region: toward discrimination of the glycosidic linkage position journal January 2007
Structure of Cellulose Microfibrils in Primary Cell Walls from Collenchyma journal November 2012
Infrared spectrum and crystal structure of cellulose journal July 1957
Capturing inhomogeneous broadening of the –CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS) journal August 2013
Unique determination of the –CN group tilt angle in Langmuir monolayers using sum-frequency polarization null angle and phase journal October 2013
Communication: Spectroscopic phase and lineshapes in high-resolution broadband sum frequency vibrational spectroscopy: Resolving interfacial inhomogeneities of “identical” molecular groups journal December 2011
Quantitative spectral and orientational analysis in surface sum frequency generation vibrational spectroscopy (SFG-VS) journal April 2005
Enzymatic hydrolysis of cellulosic biomass journal July 2011
Cellulose Microcrystal Film of High Uniaxial Orientation journal October 1997
Mapping molecular orientation and conformation at interfaces by surface nonlinear optics journal May 1999
Structural Models for Some Liquid Crystalline Cellulose Derivatives journal November 1985

Cited By (4)

Strengths, challenges, and opportunities for hydrothermal pretreatment in lignocellulosic biorefineries journal October 2017
Amorphous cellulose thin films journal February 2020
High-resolution broadband sum frequency generation vibrational spectroscopy using intrapulse interference journal January 2018
Flexible pulse shaping for sum frequency microspectroscopies journal December 2019