Multidimensional dynamic piezoresponse measurements. Unraveling local relaxation behavior in relaxor-ferroelectrics via big data
Abstract
Compositional and charge disorder in ferroelectric relaxors lies at the heart of the unusual properties of these systems, such as aging and non-ergodicity, polarization rotations, and a host of temperature and field-driven phase transitions. However, much information about the field-dynamics of the polarization in the prototypical ferroelectric relaxor (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) remains unprobed at the mesoscopic level. We use a piezoresponse force microscopy-based dynamic multimodal relaxation spectroscopy technique, enabling the study of ferroelectric switching and polarization relaxation at mesoscopic length scales, and carry out measurements on a PMN-0.28PT sample with minimal polishing. Results indicate that beyond a threshold DC bias the average relaxation increases as the system attempts to relax to the previous state. Phenomenological fitting reveals the presence of mesoscale heterogeneity in relaxation amplitudes and clearly suggests the presence of two distinct amplitudes. Independent component analysis reveals the presence of a disorder component of the relaxation, which is found to be strongly anti-correlated with the maximum piezoresponse at that location, suggesting smaller disorder effects where the polarization reversal is large and vice versa. The disorder in the relaxation amplitudes is postulated to arise from rhombohedral and field-induced tetragonal phase in the crystal, with each phase associated with its own relaxationmore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Pennsylvania State Univ., University Park, PA (United States)
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1214472
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 118; Journal Issue: 7; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; relaxor; ferroelectric; PFM; spectroscopy; disorder; relaxor ferroelectrics; atomic force microscopy; relaxation times; polarization; ferroelectric phase transitions
Citation Formats
Vasudevan, Rama K., Zhang, Shujun, Okatan, Mahmut Baris, Jesse, Stephen, Kalinin, Sergei V., and Bassiri-Gharb, Nazanin. Multidimensional dynamic piezoresponse measurements. Unraveling local relaxation behavior in relaxor-ferroelectrics via big data. United States: N. p., 2015.
Web. doi:10.1063/1.4927803.
Vasudevan, Rama K., Zhang, Shujun, Okatan, Mahmut Baris, Jesse, Stephen, Kalinin, Sergei V., & Bassiri-Gharb, Nazanin. Multidimensional dynamic piezoresponse measurements. Unraveling local relaxation behavior in relaxor-ferroelectrics via big data. United States. https://doi.org/10.1063/1.4927803
Vasudevan, Rama K., Zhang, Shujun, Okatan, Mahmut Baris, Jesse, Stephen, Kalinin, Sergei V., and Bassiri-Gharb, Nazanin. 2015.
"Multidimensional dynamic piezoresponse measurements. Unraveling local relaxation behavior in relaxor-ferroelectrics via big data". United States. https://doi.org/10.1063/1.4927803. https://www.osti.gov/servlets/purl/1214472.
@article{osti_1214472,
title = {Multidimensional dynamic piezoresponse measurements. Unraveling local relaxation behavior in relaxor-ferroelectrics via big data},
author = {Vasudevan, Rama K. and Zhang, Shujun and Okatan, Mahmut Baris and Jesse, Stephen and Kalinin, Sergei V. and Bassiri-Gharb, Nazanin},
abstractNote = {Compositional and charge disorder in ferroelectric relaxors lies at the heart of the unusual properties of these systems, such as aging and non-ergodicity, polarization rotations, and a host of temperature and field-driven phase transitions. However, much information about the field-dynamics of the polarization in the prototypical ferroelectric relaxor (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) remains unprobed at the mesoscopic level. We use a piezoresponse force microscopy-based dynamic multimodal relaxation spectroscopy technique, enabling the study of ferroelectric switching and polarization relaxation at mesoscopic length scales, and carry out measurements on a PMN-0.28PT sample with minimal polishing. Results indicate that beyond a threshold DC bias the average relaxation increases as the system attempts to relax to the previous state. Phenomenological fitting reveals the presence of mesoscale heterogeneity in relaxation amplitudes and clearly suggests the presence of two distinct amplitudes. Independent component analysis reveals the presence of a disorder component of the relaxation, which is found to be strongly anti-correlated with the maximum piezoresponse at that location, suggesting smaller disorder effects where the polarization reversal is large and vice versa. The disorder in the relaxation amplitudes is postulated to arise from rhombohedral and field-induced tetragonal phase in the crystal, with each phase associated with its own relaxation amplitude. As a result, these studies highlight the crucial importance of the mixture of ferroelectric phases in the compositions in proximity of the morphotropic phase boundary in governing the local response and further highlight the ability of PFM voltage and time spectroscopies, in conjunction with big-data multivariate analyses, to locally map disorder and correlate it with parameters governing the dynamic behavior.},
doi = {10.1063/1.4927803},
url = {https://www.osti.gov/biblio/1214472},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 7,
volume = 118,
place = {United States},
year = {Wed Aug 19 00:00:00 EDT 2015},
month = {Wed Aug 19 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Understanding Scanning Tunneling Microscopy Contrast Mechanisms on Metal Oxides: A Case Study
journal, October 2013
- Mönig, Harry; Todorović, Milica; Baykara, Mehmet Z.
- ACS Nano, Vol. 7, Issue 11
Memory and topological frustration in nematic liquid crystals confined in porous materials
journal, March 2011
- Araki, Takeaki; Buscaglia, Marco; Bellini, Tommaso
- Nature Materials, Vol. 10, Issue 4
The physics of manganites: Structure and transport
journal, August 2001
- Salamon, Myron B.; Jaime, Marcelo
- Reviews of Modern Physics, Vol. 73, Issue 3
Glassy freezing in relaxor ferroelectric lead magnesium niobate
journal, May 1998
- Levstik, Adrijan; Kutnjak, Zdravko; Filipič, Cene
- Physical Review B, Vol. 57, Issue 18
Electric-field-induced polarization in the ergodic and nonergodic states of PbMg1/3Nb2/3O3 relaxor
journal, November 2001
- Dkhil, B.; Kiat, J. M.
- Journal of Applied Physics, Vol. 90, Issue 9
Chemical ordering in lanthanum-doped lead magnesium niobate relaxor ferroelectrics probed by A1g Raman mode
journal, December 2001
- Jiang, Fuming; Kojima, Seiji; Zhao, Changlei
- Applied Physics Letters, Vol. 79, Issue 24
Freezing of the polarization fluctuations in lead magnesium niobate relaxors
journal, September 1990
- Viehland, Dwight; Jang, S. J.; Cross, L. Eric
- Journal of Applied Physics, Vol. 68, Issue 6
Slow dynamics and ergodicity breaking in a lanthanum-modified lead zirconate titanate relaxor system
journal, January 1999
- Kutnjak, Zdravko; Filipič, Cene; Pirc, Raša
- Physical Review B, Vol. 59, Issue 1
Persistence and memory of polar nanoregions in a ferroelectric relaxor under an electric field
journal, December 2005
- Xu, Guangyong; Gehring, P. M.; Shirane, G.
- Physical Review B, Vol. 72, Issue 21
Local Ordering in Lead-Based Relaxor Ferroelectrics
journal, June 2013
- Goossens, Darren J.
- Accounts of Chemical Research, Vol. 46, Issue 11
PDF Analysis Applied to Crystalline Materials
book, January 2002
- Egami, Takeshi
- Local Structure from Diffraction
Local and long range polar order in the relaxor-ferroelectric compounds and
journal, December 2001
- Dkhil, B.; Kiat, J. M.; Calvarin, G.
- Physical Review B, Vol. 65, Issue 2
Optical and Structural Studies of Long-Range Order Development in Relaxor Ferroelectrics
journal, July 2000
- Fujishiro, Kouji; Iwase, Takeshi; Uesu, Yoshiaki
- Journal of the Physical Society of Japan, Vol. 69, Issue 7
Phonon localization drives polar nanoregions in a relaxor ferroelectric
journal, April 2014
- Manley, M. E.; Lynn, J. W.; Abernathy, D. L.
- Nature Communications, Vol. 5, Issue 1
Direct Observation of the Formation of Polar Nanoregions in Using Neutron Pair Distribution Function Analysis
journal, April 2005
- Jeong, I. -K.; Darling, T. W.; Lee, J. K.
- Physical Review Letters, Vol. 94, Issue 14
Surface Domain Structures and Mesoscopic Phase Transition in Relaxor Ferroelectrics
journal, April 2011
- Kholkin, Andrei; Morozovska, Anna; Kiselev, Dmitry
- Advanced Functional Materials, Vol. 21, Issue 11
Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy
journal, July 2013
- Shvartsman, V. V.; Dkhil, B.; Kholkin, A. L.
- Annual Review of Materials Research, Vol. 43, Issue 1
Spatial distribution of relaxation behavior on the surface of a ferroelectric relaxor in the ergodic phase
journal, October 2009
- Kalinin, S. V.; Rodriguez, B. J.; Jesse, S.
- Applied Physics Letters, Vol. 95, Issue 14
Direct evidence of mesoscopic dynamic heterogeneities at the surfaces of ergodic ferroelectric relaxors
journal, February 2010
- Kalinin, S. V.; Rodriguez, B. J.; Budai, J. D.
- Physical Review B, Vol. 81, Issue 6
Observation of short-lived local polar states induced by applied tip biases in BaTiO 3 -based relaxor ferroelectric ceramics
journal, July 2013
- Li, Qian; Liu, Yun; Cheng, Zhao
- Applied Physics Letters, Vol. 103, Issue 2
Composition and phase dependence of the intrinsic and extrinsic piezoelectric activity of domain engineered (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO3 crystals
journal, August 2010
- Li, Fei; Zhang, Shujun; Xu, Zhuo
- Journal of Applied Physics, Vol. 108, Issue 3
Relaxor-PbTiO 3 single crystals for various applications
journal, August 2013
- Zhang, Shujun; Li, Fei; Luo, Jun
- IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, Vol. 60, Issue 8
Relaxor based ferroelectric single crystals for electro-mechanical actuators
journal, June 1997
- Park, Seung-Eek; Shrout, Thomas R.
- Materials Research Innovations, Vol. 1, Issue 1
Single crystal PMN-PT/Epoxy 1-3 composite for energy-harvesting application
journal, March 2006
- Ren, Kailiang; Liu, Yiming; Geng, Xuecang
- IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 53, Issue 3, p. 631-638
Advances in energy harvesting using low profile piezoelectric transducers
journal, March 2007
- Priya, Shashank
- Journal of Electroceramics, Vol. 19, Issue 1
Large strain transduction utilizing phase transition in relaxor-ferroelectric Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 single crystals
journal, May 2011
- Finkel, Peter; Benjamin, Kim; Amin, Ahmed
- Applied Physics Letters, Vol. 98, Issue 19
Polarization reversal and capacitance-voltage characteristic of epitaxial Pb(Zr,Ti)O3 layers
journal, May 2005
- Pintilie, L.; Lisca, M.; Alexe, M.
- Applied Physics Letters, Vol. 86, Issue 19
Mechanical Polishing Effects Toward Surface Domain Evolution in Pb(Zn1/3Nb2/3)O3-PbTiO3 Single Crystals: Mechanical Polishing Effects Toward Surface Domain Evolution
journal, November 2010
- Wong, Meng Fei; Zeng, Kaiyang
- Journal of the American Ceramic Society, Vol. 94, Issue 4
The band excitation method in scanning probe microscopy for rapid mapping of energy dissipation on the nanoscale
journal, September 2007
- Jesse, Stephen; Kalinin, Sergei V.; Proksch, Roger
- Nanotechnology, Vol. 18, Issue 43
Spectroscopic imaging in piezoresponse force microscopy: New opportunities for studying polarization dynamics in ferroelectrics and multiferroics
journal, July 2012
- Vasudevan, R. K.; Jesse, S.; Kim, Y.
- MRS Communications, Vol. 2, Issue 3
Principal component and spatial correlation analysis of spectroscopic-imaging data in scanning probe microscopy
journal, February 2009
- Jesse, Stephen; Kalinin, Sergei V.
- Nanotechnology, Vol. 20, Issue 8
Nucleation, growth, and control of ferroelectric-ferroelastic domains in thin polycrystalline films
journal, November 2012
- Ivry, Yachin; Scott, James F.; Salje, Ekhard K. H.
- Physical Review B, Vol. 86, Issue 20
Nano-Domain Pinning in Ferroelastic-Ferroelectrics by Extended Structural Defects
journal, July 2014
- Ivry, Yachin; Durkan, Colm; Chu, Daping
- Advanced Functional Materials, Vol. 24, Issue 35
Compatible domain structures and the poling of single crystal ferroelectrics
journal, July 2010
- Tsou, N. T.; Huber, J. E.
- Mechanics of Materials, Vol. 42, Issue 7
Compatible domain arrangements and poling ability in oriented ferroelectric films
journal, February 2010
- Tsou, N. T.; Huber, J. E.
- Continuum Mechanics and Thermodynamics, Vol. 22, Issue 3
Works referencing / citing this record:
Acoustic Detection of Phase Transitions at the Nanoscale
journal, December 2015
- Vasudevan, Rama K.; Khassaf, Hamidreza; Cao, Ye
- Advanced Functional Materials, Vol. 26, Issue 4
Machine Detection of Enhanced Electromechanical Energy Conversion in PbZr 0.2 Ti 0.8 O 3 Thin Films
journal, May 2018
- Agar, Joshua C.; Cao, Ye; Naul, Brett
- Advanced Materials, Vol. 30, Issue 28
Smart machine learning or discovering meaningful physical and chemical contributions through dimensional stacking
journal, August 2019
- Griffin, Lee A.; Gaponenko, Iaroslav; Zhang, Shujun
- npj Computational Materials, Vol. 5, Issue 1
Frontiers in strain-engineered multifunctional ferroic materials
journal, August 2016
- Agar, Joshua C.; Pandya, Shishir; Xu, Ruijuan
- MRS Communications, Vol. 6, Issue 3