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Title: Switching behaviors of graphene-boron nitride nanotube heterojunctions

Journal Article · · Scientific Reports
DOI:https://doi.org/10.1038/srep12238· OSTI ID:1213398
 [1];  [2];  [1];  [1];  [1];  [1];  [1];  [3];  [2];  [1]
  1. Michigan Technological Univ., Houghton, MI (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

High electron mobility of graphene has enabled their application in high-frequency analogue devices but their gapless nature has hindered their use in digital switches. In contrast, the structural analogous, h-BN sheets and BN nanotubes (BNNTs) are wide band gap insulators. Here we show that the growth of electrically insulating BNNTs on graphene can enable the use of graphene as effective digital switches. These graphene-BNNT heterojunctions were characterized at room temperature by four-probe scanning tunneling microscopy (4-probe STM) under real-time monitoring of scanning electron microscopy (SEM). A switching ratio as high as 105 at a turn-on voltage as low as 0.5 V were recorded. Simulation by density functional theory (DFT) suggests that mismatch of the density of states (DOS) is responsible for these novel switching behaviors.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1213398
Journal Information:
Scientific Reports, Vol. 5; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 19 works
Citation information provided by
Web of Science

References (27)

Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Ultrathin Epitaxial Graphite:  2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics journal December 2004
Graphene transistors journal May 2010
Energy Band-Gap Engineering of Graphene Nanoribbons journal May 2007
Chemically Derived, Ultrasmooth Graphene Nanoribbon Semiconductors journal February 2008
Controlling the Electronic Structure of Bilayer Graphene journal August 2006
Direct observation of a widely tunable bandgap in bilayer graphene journal June 2009
Substrate-induced band gap in graphene on hexagonal boron nitride: Ab initio density functional calculations journal August 2007
First-principles study of strain-induced modulation of energy gaps of graphene/BN and BN bilayers journal May 2011
Recent advancements in boron nitride nanotubes journal January 2010
Boron nitride substrates for high-quality graphene electronics journal August 2010
Micrometer-Scale Ballistic Transport in Encapsulated Graphene at Room Temperature journal June 2011
Graphene and boron nitride lateral heterostructures for atomically thin circuitry journal August 2012
In-plane heterostructures of graphene and hexagonal boron nitride with controlled domain sizes journal January 2013
Heteroepitaxial Growth of Two-Dimensional Hexagonal Boron Nitride Templated by Graphene Edges journal January 2014
Effective growth of boron nitride nanotubes by thermal chemical vapor deposition journal October 2008
Patterned Growth of Boron Nitride Nanotubes by Catalytic Chemical Vapor Deposition journal March 2010
Room-Temperature Tunneling Behavior of Boron Nitride Nanotubes Functionalized with Gold Quantum Dots journal June 2013
Field emission and strain engineering of electronic properties in boron nitride nanotubes journal February 2012
Inhomogeneous Electron Gas journal November 1964
Self-Consistent Equations Including Exchange and Correlation Effects journal November 1965
The SIESTA method for ab initio order- N materials simulation journal March 2002
Energy Gap Induced by Friedel Oscillations Manifested as Transport Asymmetry at Monolayer-Bilayer Graphene Boundaries journal February 2014
Very Stable Electron Field Emission from Strontium Titanate Coated Carbon Nanotube Matrices with Low Emission Thresholds journal December 2012
Electronic structure of radially deformed BN and BC 3 nanotubes journal April 2001
Exceptional ballistic transport in epitaxial graphene nanoribbons journal February 2014
Micrometer-scale ballistic transport in encapsulated graphene at room temperature text January 2011

Cited By (4)

Functionalized hexagonal boron nitride nanomaterials: emerging properties and applications journal January 2016
Water purification: oil–water separation by nanotechnology and environmental concerns journal January 2017
Synthesis of boron nitride nanotubes using an oxygen and carbon dual-free precursor journal January 2018
Electronic Structure and Room Temperature of 2D Dilute Magnetic Semiconductors in Bilayer MoS 2 -Doped Mn journal January 2020

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