New ionic liquids based on complexation of dipropylsulfide and AlCl3 for electrochodeposition of aluminum

Fang, Youxing; Jiang, Xueguang; Dai, Sheng; Sun, Xiao-Guang

doi:10.1039/C5CC05233E

Title: New ionic liquids based on complexation of dipropylsulfide and AlCl3 for electrochodeposition of aluminum

Journal Article · Tue Jul 14 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC05233E· OSTI ID:1212368

Fang, Youxing ^[1]; Jiang, Xueguang ^[1]; Dai, Sheng ^[1]; Sun, Xiao-Guang ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.

A new kind of ionic liquid based on complexation of dipropyl sulfide (DPS) and AlCl₃ has been prepared. The equivalent concentration of AlCl3 in the ionic liquid is as high as 2.3 M. More importantly, it is highly fluidic and exhibits an ambient ionic conductivity of 1.25 x 10^-4 S cm^-1. This new ionic liquid can be successfully used as an electrolyte for electrodeposition of aluminum.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Work for Others (WFO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1212368

Journal Information:: ChemComm, Vol. 51, Issue 68; ISSN 1359-7345

Country of Publication:: United States

Language:: English

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Cited by: 40 works

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References (17)

Catalysis in Ionic Liquids Pârvulescu, Vasile I.; Hardacre, Christopher Chemical Reviews, Vol. 107, Issue 6 https://doi.org/10.1021/cr050948h	journal	June 2007
Ionic Liquids: Solvents for the Electrodeposition of Metals and Semiconductors Endres, Frank ChemPhysChem, Vol. 3, Issue 2 https://doi.org/10.1002/1439-7641(20020215)3:2<144::AID-CPHC144>3.0.CO;2-#	journal	February 2002
Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene Liao, Qing Journal of The Electrochemical Society, Vol. 144, Issue 3 https://doi.org/10.1149/1.1837510	journal	January 1997
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Electrodeposition of aluminium from nonaqueous organic electrolytic systems and room temperature molten salts Zhao, Yuguang; VanderNoot, T. J. Electrochimica Acta, Vol. 42, Issue 1 https://doi.org/10.1016/0013-4686(96)00080-1	journal	January 1997
Ionic Liquids for Clean Technology Seddon, Kenneth R. Journal of Chemical Technology & Biotechnology, Vol. 68, Issue 4 https://doi.org/10.1002/(SICI)1097-4660(199704)68:4<351::AID-JCTB613>3.0.CO;2-4	journal	April 1997
Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4− and comparison with imidazolium based systems Abood, Hadi M. A.; Abbott, Andrew P.; Ballantyne, Andrew D. Chemical Communications, Vol. 47, Issue 12 https://doi.org/10.1039/c0cc04989a	journal	January 2011
Bicyclic imidazolium ionic liquids as potential electrolytes for rechargeable lithium ion batteries Sun, Xiao-Guang; Liao, Chen; Shao, Nan Journal of Power Sources, Vol. 237 https://doi.org/10.1016/j.jpowsour.2013.02.061	journal	September 2013
Kinetic and Thermodynamic Parameters of the Li/Li ⁺ Couple in the Room Temperature Ionic Liquid N -Butyl- N -methylpyrrolidinium Bis(trifluoromethylsulfonyl) Imide in the Temperature Range 298−318 K: A Theoretical and Experimental Study Using Pt and Ni Electrodes Wibowo, Rahmat; Ward Jones, Sarah E.; Compton, Richard G. The Journal of Physical Chemistry B, Vol. 113, Issue 36 https://doi.org/10.1021/jp906128t	journal	September 2009
Biocatalysis in Ionic Liquids van Rantwijk, Fred; Sheldon, Roger A. Chemical Reviews, Vol. 107, Issue 6, p. 2757-2785 https://doi.org/10.1021/cr050946x	journal	June 2007
Determination of the Lewis acidity of ionic liquids by means of an IR spectroscopic probe Yang, Ya-li; Kou, Yuan Chemical Communications, Issue 2 https://doi.org/10.1039/b311615h	journal	January 2004
Donor-acceptor properties of ambient-temperature chloroaluminate melts Zawodzinski, Thomas A.; Osteryoung, Robert A. Inorganic Chemistry, Vol. 28, Issue 9 https://doi.org/10.1021/ic00308a024	journal	May 1989
Molecular vibrations and force fields of alkyl sulfides—XIV. Infrared spectra of ethyl isopropyl, propyl isopropyl, butyl isopropyl and diisopropyl sulfides Ohsaku, Masaru; Murata, Hiromu; Shiro, Yuji Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 33, Issue 3-4 https://doi.org/10.1016/0584-8539(77)80058-5	journal	January 1977
Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis Wilkes, John S.; Levisky, Joseph A.; Wilson, Robert A. Inorganic Chemistry, Vol. 21, Issue 3 https://doi.org/10.1021/ic00133a078	journal	March 1982
An AlCl3 based ionic liquid with a neutral substituted pyridine ligand for electrochemical deposition of aluminum Fang, Youxing; Yoshii, Kazuki; Jiang, Xueguang Electrochimica Acta, Vol. 160 https://doi.org/10.1016/j.electacta.2015.02.020	journal	April 2015
Electrodeposition of Aluminum from 1,3-Dimethyl-2-Imidazolidinone/AlCl3 baths Endo, Atsushi; Miyake, Masao; Hirato, Tetsuji Electrochimica Acta, Vol. 137 https://doi.org/10.1016/j.electacta.2014.06.044	journal	August 2014
Aluminium electrodeposition under ambient conditions Abbott, Andrew P.; Harris, Robert C.; Hsieh, Yi-Ting Phys. Chem. Chem. Phys., Vol. 16, Issue 28 https://doi.org/10.1039/C4CP01508H	journal	January 2014

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Direct Electrochemical Deposition of Lithium from Lithium Oxide in a Highly Stable Aluminium-Containing Solvate Ionic Liquid Zhang, Baoguo; Yao, Yu; Shi, Zhongning ChemElectroChem, Vol. 5, Issue 22 https://doi.org/10.1002/celc.201800997	journal	September 2018
Synthesis and Characterization of Bromoaluminate Ionic Liquids Hog, Michael; Schneider, Marius; Krossing, Ingo Chemistry - A European Journal, Vol. 23, Issue 41 https://doi.org/10.1002/chem.201700105	journal	June 2017
An Investigation of the Symmetric and Asymmetric Cleavage Products in the System Aluminum Trihalide/1-Butylimidazole Hog, Michael; Schneider, Marius; Studer, Gauthier Chemistry - A European Journal, Vol. 23, Issue 46 https://doi.org/10.1002/chem.201701553	journal	July 2017
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Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates Biancalana, Lorenzo; Bresciani, Giulio; Chiappe, Cinzia Physical Chemistry Chemical Physics, Vol. 20, Issue 7 https://doi.org/10.1039/c7cp07289a	journal	January 2018
High Coulombic efficiency aluminum-ion battery using an AlCl ₃ -urea ionic liquid analog electrolyte Angell, Michael; Pan, Chun-Jern; Rong, Youmin Proceedings of the National Academy of Sciences, Vol. 114, Issue 5 https://doi.org/10.1073/pnas.1619795114	journal	January 2017
Electrodeposition of Al, Al-Li Alloy, and Li from an Al-Containing Solvate Ionic Liquid under Ambient Conditions Zhang, Baoguo; Shi, Zhongning; Shen, Lingling Journal of The Electrochemical Society, Vol. 165, Issue 9 https://doi.org/10.1149/2.0211809jes	journal	January 2018

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