Probing the Mechanism of High Capacitance in 2D Titanium Carbide Using In Situ X-Ray Absorption Spectroscopy

Lukatskaya, Maria R.; Bak, Seong-Min; Yu, Xiqian; Yang, Xiao-Qing; Barsoum, Michel W.; Gogotsi, Yury

doi:10.1002/aenm.201500589

Title: Probing the Mechanism of High Capacitance in 2D Titanium Carbide Using In Situ X-Ray Absorption Spectroscopy

Journal Article · Thu May 28 00:00:00 EDT 2015 · Advanced Energy Materials (Online)

DOI:https://doi.org/10.1002/aenm.201500589· OSTI ID:1212194

Lukatskaya, Maria R.; Bak, Seong-Min; Yu, Xiqian; Yang, Xiao-Qing; Barsoum, Michel W.; Gogotsi, Yury ^[1]

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - BASIC ENERGY SCIENCES

OSTI ID:: 1212194

Journal Information:: Advanced Energy Materials (Online), Vol. 5, Issue 15; ISSN 1614-6840

Publisher:: Wiley

Country of Publication:: United States

Language:: ENGLISH

References (26)

Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
A Sandwich-Like Hierarchically Porous Carbon/Graphene Composite as a High-Performance Anode Material for Sodium-Ion Batteries Yan, Yang; Yin, Ya-Xia; Guo, Yu-Guo Advanced Energy Materials, Vol. 4, Issue 8 https://doi.org/10.1002/aenm.201301584	journal	January 2014
Reversibility and Growth Behavior of Surface Oxide Films at Ruthenium Electrodes Hadz̄i-Jordanov, S. Journal of The Electrochemical Society, Vol. 125, Issue 9 https://doi.org/10.1149/1.2131698	journal	January 1978
Hydrous Ruthenium Oxide as an Electrode Material for Electrochemical Capacitors Zheng, J. P. Journal of The Electrochemical Society, Vol. 142, Issue 8 https://doi.org/10.1149/1.2050077	journal	January 1995
Direct synthesis of electroactive mesoporous hydrous crystalline RuO2 templated by a cationic surfactant Oh, Si Hyoung; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 19 https://doi.org/10.1039/b926734d	journal	January 2010
Block‐Copolymer‐Templated Synthesis of Electroactive RuO ₂ ‐Based Mesoporous Thin Films Sassoye, Capucine; Laberty, Christel; Le Khanh, Hung Advanced Functional Materials, Vol. 19, Issue 12 https://doi.org/10.1002/adfm.200801831	journal	June 2009
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Two-Dimensional Materials: 25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials (Adv. Mater. 7/2014) Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7 https://doi.org/10.1002/adma.201470041	journal	February 2014
The New Skinny in Two-Dimensional Nanomaterials Koski, Kristie J.; Cui, Yi ACS Nano, Vol. 7, Issue 5 https://doi.org/10.1021/nn4022422	journal	May 2013
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M. Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm500641a	journal	March 2014
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang Nature, Vol. 516, Issue 7529 https://doi.org/10.1038/nature13970	journal	November 2014
MXene: a promising transition metal carbide anode for lithium-ion batteries Naguib, Michael; Come, Jérémy; Dyatkin, Boris Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64 https://doi.org/10.1016/j.elecom.2012.01.002	journal	March 2012
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries Naguib, Michael; Halim, Joseph; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja405735d	journal	October 2013
Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries Liang, Xiao; Garsuch, Arnd; Nazar, Linda F. Angewandte Chemie International Edition, Vol. 54, Issue 13 https://doi.org/10.1002/anie.201410174	journal	February 2015
High capacitance of surface-modified 2D titanium carbide in acidic electrolyte Dall'Agnese, Yohan; Lukatskaya, Maria R.; Cook, Kevin M. Electrochemistry Communications, Vol. 48 https://doi.org/10.1016/j.elecom.2014.09.002	journal	November 2014
Solving the Capacitive Paradox of 2D MXene using Electrochemical Quartz-Crystal Admittance and In Situ Electronic Conductance Measurements Levi, Mikhael D.; Lukatskaya, Maria R.; Sigalov, Sergey Advanced Energy Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aenm.201400815	journal	August 2014
Towards the mechanism of electrochemical hydrogen storage in nanostructured carbon materials Jurewicz, K.; Frackowiak, E.; Béguin, F. Applied Physics A, Vol. 78, Issue 7 https://doi.org/10.1007/s00339-003-2418-8	journal	April 2004
In situ Mn K-edge X-ray absorption spectroscopic studies of anodically deposited manganese oxide with relevance to supercapacitor applications Chang, Jeng-Kuei; Lee, Ming-Tsung; Tsai, Wen-Ta Journal of Power Sources, Vol. 166, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.01.036	journal	April 2007
In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors Nam, Kyung-Wan; Kim, Min Gyu; Kim, Kwang-Bum The Journal of Physical Chemistry C, Vol. 111, Issue 2 https://doi.org/10.1021/jp063130o	journal	January 2007
In Situ Ru K-Edge X-Ray Absorption Fine Structure Studies of Electroprecipitated Ruthenium Dioxide Films with Relevance to Supercapacitor Applications Mo, Yibo; Antonio, Mark R.; Scherson, Daniel A. The Journal of Physical Chemistry B, Vol. 104, Issue 42 https://doi.org/10.1021/jp002355a	journal	October 2000
NEXAFS investigations of transition metal oxides, nitrides, carbides, sulfides and other interstitial compounds Chen, J. G. Surface Science Reports, Vol. 30, Issue 1-3 https://doi.org/10.1016/S0167-5729(97)00011-3	journal	January 1997
Role of Surface Structure on Li-Ion Energy Storage Capacity of Two-Dimensional Transition-Metal Carbides Xie, Yu; Naguib, Michael; Mochalin, Vadym N. Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja501520b	journal	April 2014
Lithium Storage in Amorphous TiO[sub 2] Nanoparticles Borghols, Wouter J. H.; Lützenkirchen-Hecht, Dirk; Haake, Ullrich Journal of The Electrochemical Society, Vol. 157, Issue 5 https://doi.org/10.1149/1.3332806	journal	January 2010
The electronic structure and ionic diffusion of nanoscale LiTiO2 anatase Borghols, W. J. H.; Lützenkirchen-Hecht, D.; Haake, U. Physical Chemistry Chemical Physics, Vol. 11, Issue 27 https://doi.org/10.1039/b823142g	journal	January 2009
Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries Liang, Xiao; Garsuch, Arnd; Nazar, Linda F. Angewandte Chemie, Vol. 127, Issue 13 https://doi.org/10.1002/ange.201410174	journal	February 2015

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Multifunctional Nanocomposites with High Strength and Capacitance Using 2D MXene and 1D Nanocellulose Tian, Weiqian; VahidMohammadi, Armin; Reid, Michael S. Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201902977	journal	August 2019
MXene-on-Paper Coplanar Microsupercapacitors Kurra, Narendra; Ahmed, Bilal; Gogotsi, Yury Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601372	journal	September 2016
On‐Chip MXene Microsupercapacitors for AC‐Line Filtering Applications Jiang, Qiu; Kurra, Narendra; Maleski, Kathleen Advanced Energy Materials https://doi.org/10.1002/aenm.201901061	journal	May 2019
Fluorine-Free Synthesis of High-Purity Ti ₃ C ₂ T _x (T=OH, O) via Alkali Treatment Li, Tengfei; Yao, Lulu; Liu, Qinglei Angewandte Chemie International Edition, Vol. 57, Issue 21 https://doi.org/10.1002/anie.201800887	journal	April 2018
High-Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors Wang, Zhiyu; Qin, Si; Seyedin, Shayan Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201802225	journal	August 2018
Recent progress in layered transition metal carbides and/or nitrides (MXenes) and their composites: synthesis and applications Hong Ng, Vincent Ming; Huang, Hui; Zhou, Kun Journal of Materials Chemistry A, Vol. 5, Issue 7 https://doi.org/10.1039/c6ta06772g	journal	January 2017
Flexible Ti ₃ C ₂ T _x /PEDOT:PSS films with outstanding volumetric capacitance for asymmetric supercapacitors Li, Lu; Zhang, Na; Zhang, Mingyi Dalton Transactions, Vol. 48, Issue 5 https://doi.org/10.1039/c8dt04374d	journal	January 2019
Ti ₃ C ₂ MXene quantum dot-encapsulated liposomes for photothermal immunoassays using a portable near-infrared imaging camera on a smartphone Cai, Guoneng; Yu, Zhenzhong; Tong, Ping Nanoscale, Vol. 11, Issue 33 https://doi.org/10.1039/c9nr05797h	journal	January 2019
Interlayer engineering of Ti ₃ C ₂ T _x MXenes towards high capacitance supercapacitors Hu, Minmin; Cheng, Renfei; Li, Zhenjiang Nanoscale, Vol. 12, Issue 2 https://doi.org/10.1039/c9nr08960h	journal	January 2020
Scalable nanomanufacturing of inkjet-printed wearable energy storage devices Huang, Tao-Tse; Wu, Wenzhuo Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta05239a	journal	January 2019
High-Voltage Symmetric Supercapacitor Based on 2D Titanium Carbide (MXene, Ti ₂ CT _x )/Carbon Nanosphere Composites in a Neutral Aqueous Electrolyte Melchior, Sharona A.; Raju, Kumar; Ike, Innocent S. Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.0401803jes	journal	January 2018
A hydrofluoric acid-free synthesis of 2D vanadium carbide (V ₂ C) MXene for supercapacitor electrodes Guan, Yunfeng; Jiang, Song; Cong, Ye 2D Materials, Vol. 7, Issue 2 https://doi.org/10.1088/2053-1583/ab6706	journal	January 2020

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