Pore-controlled formation of 0D metal complexes in anionic 3D metal-organic frameworks

Zhang, MW; Bosch, M; Zhou, HC

doi:10.1039/c4ce02261k

Title: Pore-controlled formation of 0D metal complexes in anionic 3D metal-organic frameworks

Journal Article · Thu Jan 01 00:00:00 EST 2015 · CrystEngComm

DOI:https://doi.org/10.1039/c4ce02261k· OSTI ID:1211273

Zhang, MW; Bosch, M; Zhou, HC

The host-guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD. The PCN-514 series contains crystallographically identifiable metal complexes trapped in the pores, where their formation is controlled by the size and shape of the MOF pores. A change in the structure and pore size of PCN-518 indicates that the existence of guest molecules may reciprocally affect the formation of host MOFs.

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Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: DE-AR0000249

OSTI ID:: 1211273

Journal Information:: CrystEngComm, Vol. 17, Issue 5; ISSN 1466-8033

Country of Publication:: United States

Language:: English

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