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Title: CO2 Capture Using 2,2-Dialkylpropane-1,3-diamines

Journal Article · · Energy and Fuels
DOI:https://doi.org/10.1021/ef301661h· OSTI ID:1211132

A series of 2,2-dialkylpropane-1,3-diamines were synthesized and evaluated as potential phase-changing CO2 sorbents. In general, these compounds readily absorbed CO2 to form solid carbamate salts, which were relatively insensitive to the presence of moisture. This is one of the key performance attributes phase-changing sorbents must possess. However, these diamines were found to be less thermally stable in air than expected. The main reaction products obtained during heat aging at 150 degrees C appeared to be 1,4,5,6-tetrahydropyrimidine derivatives.

Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
DE-AR0000084
OSTI ID:
1211132
Journal Information:
Energy and Fuels, Vol. 27, Issue 1; ISSN 0887-0624
Country of Publication:
United States
Language:
English

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