Na3Ti2(PO4)(3) as a sodium-bearing anode for rechargeable aqueous sodium-ion batteries

Journal Article · Tue Jul 01 00:00:00 EDT 2014 · Electrochemistry Communications

DOI:https://doi.org/10.1016/j.elecom.2014.04.003· OSTI ID:1211032

Li, Z; Ravnsbaek, DB; Xiang, K; Chiang, YM

Na3Ti2(PO4)(3) synthesized as fine carbon-coated powders is demonstrated for the first time to be a suitable sodium-bearing anode material for rechargeable aqueous sodium-ion batteries (ANaBs). Importantly, Na3Ti2(PO4)(3) is found to be stable in deoxygenated water, enabling use of this material in aqueous systems. As a sodiated anode, it allows use of sodium-depleted cathode materials that require supply of sodium-ions from the anode. As an example, we demonstrate for the first time the use of olivine FePO4 as a cathode in an ANaB. (C) 2014 Elsevier B.V. All rights reserved.

• Sponsoring Organization: USDOE Advanced Research Projects Agency - Energy (ARPA-E)
• DOE Contract Number: DE-AR0000065
• OSTI ID: 1211032
• Journal Information: Electrochemistry Communications, Vol. 44; ISSN 1388-2481
• Country of Publication: United States
• Language: English