Fluorogel Elastomers with Tunable Transparency, Elasticity, ShapeMemory, and Antifouling Properties**
Abstract
Omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti-biofouling behavior, while maintaining cytocompatiblity.
- Authors:
- Publication Date:
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1210964
- DOE Contract Number:
- DE-AR0000326
- Resource Type:
- Journal Article
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 17; Journal ID: ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Yao, X, Dunn, SS, Kim, P, Duffy, M, Alvarenga, J, and Aizenberg, J. Fluorogel Elastomers with Tunable Transparency, Elasticity, ShapeMemory, and Antifouling Properties**. United States: N. p., 2014.
Web. doi:10.1002/anie.201310385.
Yao, X, Dunn, SS, Kim, P, Duffy, M, Alvarenga, J, & Aizenberg, J. Fluorogel Elastomers with Tunable Transparency, Elasticity, ShapeMemory, and Antifouling Properties**. United States. https://doi.org/10.1002/anie.201310385
Yao, X, Dunn, SS, Kim, P, Duffy, M, Alvarenga, J, and Aizenberg, J. 2014.
"Fluorogel Elastomers with Tunable Transparency, Elasticity, ShapeMemory, and Antifouling Properties**". United States. https://doi.org/10.1002/anie.201310385.
@article{osti_1210964,
title = {Fluorogel Elastomers with Tunable Transparency, Elasticity, ShapeMemory, and Antifouling Properties**},
author = {Yao, X and Dunn, SS and Kim, P and Duffy, M and Alvarenga, J and Aizenberg, J},
abstractNote = {Omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti-biofouling behavior, while maintaining cytocompatiblity.},
doi = {10.1002/anie.201310385},
url = {https://www.osti.gov/biblio/1210964},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 17,
volume = 53,
place = {United States},
year = {Tue Mar 18 00:00:00 EDT 2014},
month = {Tue Mar 18 00:00:00 EDT 2014}
}
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Works referenced in this record:
Designing materials for biology and medicine
journal, April 2004
- Langer, Robert; Tirrell, David A.
- Nature, Vol. 428, Issue 6982
Antifouling Coatings: Recent Developments in the Design of Surfaces That Prevent Fouling by Proteins, Bacteria, and Marine Organisms
journal, September 2010
- Banerjee, Indrani; Pangule, Ravindra C.; Kane, Ravi S.
- Advanced Materials, Vol. 23, Issue 6, p. 690-718
Methods for Reducing Biofouling of Moored Optical Sensors
journal, June 2004
- Manov, Derek V.; Chang, Grace C.; Dickey, Tommy D.
- Journal of Atmospheric and Oceanic Technology, Vol. 21, Issue 6
A review of tissue-engineered skin bioconstructs available for skin reconstruction
journal, July 2009
- Shevchenko, Rostislav V.; James, Stuart L.; James, S. Elizabeth
- Journal of The Royal Society Interface, Vol. 7, Issue 43
Effect of Surface Wettability on the Adhesion of Proteins
journal, August 2004
- Sethuraman, Ananthakrishnan; Han, Mina; Kane, Ravi S.
- Langmuir, Vol. 20, Issue 18
Whole-Teflon microfluidic chips
journal, May 2011
- Ren, K.; Dai, W.; Zhou, J.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 20
Hydrogels in Biology and Medicine: From Molecular Principles to Bionanotechnology
journal, June 2006
- Peppas, N. A.; Hilt, J. Z.; Khademhosseini, A.
- Advanced Materials, Vol. 18, Issue 11
Hydrogels for tissue engineering: scaffold design variables and applications
journal, November 2003
- Drury, Jeanie L.; Mooney, David J.
- Biomaterials, Vol. 24, Issue 24
Organogels and their use in drug delivery — A review
journal, February 2008
- Vintiloiu, Anda; Leroux, Jean-Christophe
- Journal of Controlled Release, Vol. 125, Issue 3
Functional Supramolecular Polymers
journal, February 2012
- Aida, T.; Meijer, E. W.; Stupp, S. I.
- Science, Vol. 335, Issue 6070
Solvent-Resistant Photocurable “Liquid Teflon” for Microfluidic Device Fabrication
journal, March 2004
- Rolland, Jason P.; Van Dam, R. Michael; Schorzman, Derek A.
- Journal of the American Chemical Society, Vol. 126, Issue 8, p. 2322-2323
Optically Transparent, Amphiphilic Networks Based on Blends of Perfluoropolyethers and Poly(ethylene glycol)
journal, October 2008
- Hu, Zhaokang; Chen, Liang; Betts, Douglas E.
- Journal of the American Chemical Society, Vol. 130, Issue 43
Photocurable Amphiphilic Perfluoropolyether/Poly(ethylene glycol) Networks for Fouling-Release Coatings
journal, February 2011
- Wang, Yapei; Betts, Douglas E.; Finlay, John A.
- Macromolecules, Vol. 44, Issue 4
The Antifouling and Fouling-Release Perfomance of Hyperbranched Fluoropolymer (HBFP)−Poly(ethylene glycol) (PEG) Composite Coatings Evaluated by Adsorption of Biomacromolecules and the Green Fouling Alga Ulva
journal, March 2005
- Gudipati, Chakravarthy S.; Finlay, John A.; Callow, James A.
- Langmuir, Vol. 21, Issue 7
Structure and Surface Properties of Liquid Crystalline Fluoroalkyl Polyacrylates: Role of the Spacer
journal, November 2001
- Corpart, Jean-Marc; Girault, Sylvie; Juhué, Didier
- Langmuir, Vol. 17, Issue 23
Molecular Aggregation Structure and Surface Properties of Poly(fluoroalkyl acrylate) Thin Films
journal, June 2005
- Honda, Koji; Morita, Masamichi; Otsuka, Hideyuki
- Macromolecules, Vol. 38, Issue 13
Surface properties and structures of diblock copolymer and homopolymer with perfluoroalkyl side chains
journal, March 2005
- Nishino, Takashi; Urushihara, Yoshimasa; Meguro, Masashi
- Journal of Colloid and Interface Science, Vol. 283, Issue 2
Challenges of shape memory polymers: A review of the progress toward overcoming SMP's limitations
journal, November 2008
- Rousseau, Ingrid A.
- Polymer Engineering & Science, Vol. 48, Issue 11
Shape Memory Polymer Research
journal, August 2009
- Mather, Patrick T.; Luo, Xiaofan; Rousseau, Ingrid A.
- Annual Review of Materials Research, Vol. 39, Issue 1
Adaptive fluid-infused porous films with tunable transparency and wettability
journal, April 2013
- Yao, Xi; Hu, Yuhang; Grinthal, Alison
- Nature Materials, Vol. 12, Issue 6
Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity
journal, September 2011
- Wong, Tak-Sing; Kang, Sung Hoon; Tang, Sindy K. Y.
- Nature, Vol. 477, Issue 7365, p. 443-447
Friction and lubrication of hydrogels—its richness and complexity
journal, January 2006
- Gong, Jian Ping
- Soft Matter, Vol. 2, Issue 7
Surface-Grafted, Covalently Cross-Linked Hydrogel Brushes with Tunable Interfacial and Bulk Properties
journal, July 2011
- Li, Ang; Benetti, Edmondo M.; Tranchida, Davide
- Macromolecules, Vol. 44, Issue 13
Dangling Chain Elastomers as Repeatable Fibrillar Adhesives
journal, September 2009
- Sitti, Metin; Cusick, Brian; Aksak, Burak
- ACS Applied Materials & Interfaces, Vol. 1, Issue 10
In Pursuit of Zero: Polymer Brushes that Resist the Adsorption of Proteins
journal, June 2009
- Hucknall, Angus; Rangarajan, Srinath; Chilkoti, Ashutosh
- Advanced Materials, Vol. 21, Issue 23, p. 2441-2446
Friction and Lubrication of Hydrogels: Its Richness and Complexity
journal, October 2006
- Gong, Jian Ping
- ChemInform, Vol. 37, Issue 41
Works referencing / citing this record:
External Stimuli Responsive Liquid‐Infused Surfaces Switching between Slippery and Nonslippery States: Fabrications and Applications
journal, January 2020
- Lou, Xiaoding; Huang, Yu; Yang, Xian
- Advanced Functional Materials, Vol. 30, Issue 10
Superwettability-Based Interfacial Chemical Reactions
journal, December 2018
- Wu, Yuchen; Feng, Jiangang; Gao, Hanfei
- Advanced Materials, Vol. 31, Issue 8
Earthworm-Inspired Rough Polymer Coatings with Self-Replenishing Lubrication for Adaptive Friction-Reduction and Antifouling Surfaces
journal, June 2018
- Zhao, Huaixia; Sun, Qiangqiang; Deng, Xu
- Advanced Materials, Vol. 30, Issue 29
Enabling and Localizing Omnidirectional Nonlinear Deformation in Liquid Crystalline Elastomers
journal, July 2018
- Auguste, Anesia D.; Ward, Jeremy W.; Hardin, James O.
- Advanced Materials, Vol. 30, Issue 35
Designing Liquid‐Infused Surfaces for Medical Applications: A Review
journal, August 2018
- Howell, Caitlin; Grinthal, Alison; Sunny, Steffi
- Advanced Materials, Vol. 30, Issue 50
Textured Organogel Films Showing Unusual Thermoresponsive Dewetting, Icephobic, and Optical Properties
journal, November 2018
- Urata, Chihiro; Hönes, Roland; Sato, Tomoya
- Advanced Materials Interfaces, Vol. 6, Issue 2
Biofilm Bridges Forming Structural Networks on Patterned Lubricant‐Infused Surfaces
journal, May 2019
- Lei, Wenxi; Bruchmann, Julia; Rüping, Jan Lars
- Advanced Science, Vol. 6, Issue 13
Recent Advances in Bioinspired Gel Surfaces with Superwettability and Special Adhesion
journal, July 2019
- Zhang, Pengchao; Zhao, Chuangqi; Zhao, Tianyi
- Advanced Science, Vol. 6, Issue 18
Amphiphilic poly(ether sulfone) membranes for oil/water separation: Effect of sequence structure of the modifier
journal, June 2016
- Zhang, Guangfa; Jiang, Jingxian; Zhang, Qinghua
- AIChE Journal, Vol. 63, Issue 2
Superspreading on Immersed Gel Surfaces for the Confined Synthesis of Thin Polymer Films
journal, February 2016
- Zhang, Pengchao; Zhang, Feilong; Zhao, Chuangqi
- Angewandte Chemie, Vol. 128, Issue 11
Self-Healable Organogel Nanocomposite with Angle-Independent Structural Colors
journal, July 2017
- Zhou, Jinming; Han, Peng; Liu, Meijin
- Angewandte Chemie International Edition, Vol. 56, Issue 35
Emerging Applications of Bioinspired Slippery Surfaces in Biomedical Fields
journal, July 2018
- He, Wenqing; Liu, Peng; Zhang, Jianqiang
- Chemistry - A European Journal, Vol. 24, Issue 56
Non‐Tacky Fluorinated and Elastomeric STEM Networks
journal, February 2019
- Cuthbert, Julia; Martinez, Michael R.; Sun, Mingkang
- Macromolecular Rapid Communications, Vol. 40, Issue 10
Designing Bioinspired Anti-Biofouling Surfaces based on a Superwettability Strategy
journal, February 2016
- Zhang, Pengchao; Lin, Ling; Zang, Dongmian
- Small, Vol. 13, Issue 4
Effect of the texture geometry on the slippery behavior of liquid-infused nanoporous surfaces
journal, October 2018
- Cui, Jinhua; Zhu, Hongxia; Tu, Zhiqiang
- Journal of Materials Science, Vol. 54, Issue 3
Design of anti-icing surfaces: smooth, textured or slippery?
journal, January 2016
- Kreder, Michael J.; Alvarenga, Jack; Kim, Philseok
- Nature Reviews Materials, Vol. 1, Issue 1
Adaptive and freeze-tolerant heteronetwork organohydrogels with enhanced mechanical stability over a wide temperature range
journal, June 2017
- Gao, Hainan; Zhao, Ziguang; Cai, Yudong
- Nature Communications, Vol. 8, Issue 1
Oil-Impregnated Hydrocarbon-Based Polymer Films
journal, August 2018
- Mukherjee, Ranit; Habibi, Mohammad; Rashed, Ziad T.
- Scientific Reports, Vol. 8, Issue 1
Infused polymers for cell sheet release
journal, May 2016
- Juthani, Nidhi; Howell, Caitlin; Ledoux, Haylea
- Scientific Reports, Vol. 6, Issue 1
Tunable surface topography in fluoropolymers using photo-embossing
journal, January 2016
- Kommeren, S.; Sullivan, T.; Bastiaansen, C. W. M.
- RSC Advances, Vol. 6, Issue 73
Mechanism of the formation of microphase separated water clusters in a water-mediated physical network of perfluoropolyether tetraol
journal, January 2018
- Deshpande, Ashwini A.; Torris A. T., Arun; Pahari, Swagata
- Soft Matter, Vol. 14, Issue 12
Development of multifunctional liquid-infused materials by printing assisted functionalization on porous nanocomposites
journal, January 2018
- He, Wenqing; Liu, Peng; Jiang, Jieke
- Journal of Materials Chemistry A, Vol. 6, Issue 9
Biomimetic self-slippery and transferable transparent lubricant-infused functional surfaces
journal, January 2018
- Wang, Zelinlan; Guo, Zhiguang
- Nanoscale, Vol. 10, Issue 42
Thermo-reversible self-healing in a fluorous crosslinked copolymer
journal, January 2018
- Padhan, Anil K.; Mandal, Debaprasad
- Polymer Chemistry, Vol. 9, Issue 23
A stable solid slippery surface with thermally assisted self-healing ability
journal, January 2018
- Meng, Xiangfu; Wang, Zubin; Wang, Lili
- Journal of Materials Chemistry A, Vol. 6, Issue 34
Liquid gating elastomeric porous system with dynamically controllable gas/liquid transport
journal, February 2018
- Sheng, Zhizhi; Wang, Honglong; Tang, Yongliang
- Science Advances, Vol. 4, Issue 2
Immobilized liquid layers: A new approach to anti-adhesion surfaces for medical applications
journal, March 2016
- Sotiri, Irini; Overton, Jonathan C.; Waterhouse, Anna
- Experimental Biology and Medicine, Vol. 241, Issue 9
Antifouling and Fouling-Release Performance of Photo-Embossed Fluorogel Elastomers
journal, November 2019
- Kommeren, Sander; Guerin, Andrew J.; Dale, Marie L.
- Journal of Marine Science and Engineering, Vol. 7, Issue 11, p. 419
Fluorinated Polymers as Smart Materials for Advanced Biomedical Applications
journal, February 2018
- Cardoso, Vanessa; Correia, Daniela; Ribeiro, Clarisse
- Polymers, Vol. 10, Issue 2
Superspreading on Immersed Gel Surfaces for the Confined Synthesis of Thin Polymer Films
journal, February 2016
- Zhang, Pengchao; Zhang, Feilong; Zhao, Chuangqi
- Angewandte Chemie International Edition, Vol. 55, Issue 11
Self-Healable Organogel Nanocomposite with Angle-Independent Structural Colors
journal, July 2017
- Zhou, Jinming; Han, Peng; Liu, Meijin
- Angewandte Chemie, Vol. 129, Issue 35
Biofilm Bridges Forming Structural Networks on Patterned Lubricant‐Infused Surfaces
text, January 2019
- Lei, Wenxi; Bruchmann, Julia; Rüping, Jan Lars
- Karlsruhe
Infused polymers for cell sheet release
journal, May 2016
- Juthani, Nidhi; Howell, Caitlin; Ledoux, Haylea
- Scientific Reports, Vol. 6, Issue 1
Fluorinated Polymers as Smart Materials for Advanced Biomedical Applications
journal, February 2018
- Cardoso, Vanessa; Correia, Daniela; Ribeiro, Clarisse
- Polymers, Vol. 10, Issue 2