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Title: Polypyridyl Ru(ii)-derivatized polypropylacrylate polymer with a terminal water oxidation catalyst. Application of reversible addition–fragmentation chain transfer polymerization

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/C5DT00287G· OSTI ID:1210613
 [1];  [2];  [1];  [1];  [1];  [1];  [1]
  1. Univ. of North Carolina, Chapel Hill, NC (United States)
  2. Univ. of North Carolina, Chapel Hill, NC (United States); Osaka City Univ., Osaka (Japan)
+ Show Author Affiliations

A ruthenium containing poly(propylmethacrylate) derivative was synthesized by RAFT polymerization and end-capped with a catalyst derivative.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001011
OSTI ID:
1210613
Journal Information:
Dalton Transactions, Vol. 44, Issue 18; Related Information: UNC partners with University of North Carolina (lead); Duke University; University of Florida; Georgia Institute of Technology; University; North Carolina Central University; Research Triangle Institute; ISSN 1477-9226
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 15 works
Citation information provided by
Web of Science

References (39)

Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% journal May 2008
Ultrafast Excited-State Energy Migration Dynamics in an Efficient Light-Harvesting Antenna Polymer Based on Ru(II) and Os(II) Polypyridyl Complexes journal October 2001
Solar Fuels and Next Generation Photovoltaics: The UNC-CH Energy Frontier Research Center journal November 2010
Towards artificial photosynthesis: ruthenium–manganese chemistry for energy production journal January 2001
Improving the efficiency of water splitting in dye-sensitized solar cells by using a biomimetic electron transfer mediator journal April 2012
Low-Overpotential Water Oxidation by a Surface-Bound Ruthenium-Chromophore-Ruthenium-Catalyst Assembly journal November 2013
Controlled Electropolymerization of Ruthenium(II) Vinylbipyridyl Complexes in Mesoporous Nanoparticle Films of TiO 2 journal March 2014
Identification of the Different Mechanisms of Activation of a [Ru II (tpy)(bpy)(OH 2 )] 2+ Catalyst by Modified Ruthenium Sensitizers in Supramolecular Complexes journal May 2013
Redox Mediator Effect on Water Oxidation in a Ruthenium-Based Chromophore–Catalyst Assembly journal January 2013
Visible Region Photooxidation on TiO 2 with a Chromophore−Catalyst Molecular Assembly journal October 1999
Nonaqueous Catalytic Water Oxidation journal December 2010
Photoinduced Electron Transfer in a Chromophore–Catalyst Assembly Anchored to TiO 2 journal November 2012
Water-stable, hydroxamate anchors for functionalization of TiO2 surfaces with ultrafast interfacial electron transfer journal January 2010
Proton-Coupled Photoinduced Electron Transfer, Deuterium Isotope Effects, and Fluorescence Quenching in Noncovalent Benzo[a]pyrenetetraol-Nucleoside Complexes in Aqueous Solutions journal May 1995
Sensitization of ultra-long-range excited-state electron transfer by energy transfer in a polymerized film journal September 2012
Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell
  • Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji
  • Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927 https://doi.org/10.1021/ja809108y
journal January 2009
Applications of metal oxide materials in dye sensitized photoelectrosynthesis cells for making solar fuels: let the molecules do the work journal January 2013
Photoinduced Stepwise Oxidative Activation of a Chromophore–Catalyst Assembly on TiO 2 journal June 2011
An Antenna Polymer for Visible Energy Transfer journal October 1997
An Amide-Linked Chromophore–Catalyst Assembly for Water Oxidation journal June 2012
Computer decomposition of the ultraviolet-visible absorption spectrum of the methyl viologen cation radical and its dimer in solution journal January 1983
The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay journal January 2012
Measurement of the extinction coefficient of the methyl viologen cation radical and the efficiency of its formation by semiconductor photocatalysis journal July 1982
Efficiencies of Electron Injection from Excited N3 Dye into Nanocrystalline Semiconductor (ZrO 2 , TiO 2 , ZnO, Nb 2 O 5 , SnO 2 , In 2 O 3 ) Films journal April 2004
Electrochemical and Photoelectrochemical Water Oxidation by Supported Cobalt–Oxo Cubanes journal January 2014
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors journal December 2009
Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes journal August 2012
Effect of water addition on the coupling of homopolymers by click chemistry journal September 2010
Molecular Catalysts for Water Oxidation journal January 2001
Photoelectrochemistry on Ru II -2,2‘-bipyridine-phosphonate-Derivatized TiO 2 with the I 3 - /I - and Quinone/Hydroquinone Relays. Design of Photoelectrochemical Synthesis Cells journal March 2005
Reduction Potentials of One‐Electron Couples Involving Free Radicals in Aqueous Solution journal October 1989
Chemical Approaches to Artificial Photosynthesis. 2 journal October 2005
Interfacial Electron Transfer Dynamics Following Laser Flash Photolysis of [Ru(bpy)2((4,4′-PO3H2)2bpy)]2+ in TiO2 Nanoparticle Films in Aqueous Environments journal February 2011
Energy Transfer in the Inverted Region: Calculation of Relative Rate Constants by Emission Spectral Fitting journal October 1994
Solar water splitting in a molecular photoelectrochemical cell journal November 2013
Design and Use of the Microsoft Excel Solver journal October 1998
Light Harvesting Arrays of Polypyridine Ruthenium(II) Chromophores Prepared by Reversible Addition–Fragmentation Chain Transfer Polymerization journal March 2012
Solar Fuels via Artificial Photosynthesis journal December 2009
Anomalous Reactivity of Ceric Nitrate in Ruthenium “Blue Dimer”-Catalyzed Water Oxidation journal December 2012

Cited By (2)

“Chemistry-on-the-complex”: functional Ru II polypyridyl-type sensitizers as divergent building blocks journal January 2018
Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform journal January 2019

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (homogeneous)
catalysis (heterogeneous)
solar (photovoltaic)
solar (fuels)
photosynthesis (natural and artificial)
hydrogen and fuel cells
electrodes - solar
charge transport
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)