Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores
Abstract
A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.
- Authors:
-
- Texas A & M Univ., College Station, TX (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) and Center for Gas Separations Relevant to Clean Energy Technologies (CGS), Washington, DC (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1210607
- DOE Contract Number:
- SC0001015
- Resource Type:
- Journal Article
- Journal Name:
- J. Am. Chem Soc.
- Additional Journal Information:
- Journal Volume: 137; Journal Issue: 4; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University
- Country of Publication:
- United States
- Language:
- English
- Subject:
- membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)
Citation Formats
Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. United States: N. p., 2015.
Web. doi:10.1021/ja5123528.
Park, Jihye, Feng, Dawei, & Zhou, Hong-Cai. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. United States. https://doi.org/10.1021/ja5123528
Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. 2015.
"Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores". United States. https://doi.org/10.1021/ja5123528.
@article{osti_1210607,
title = {Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores},
author = {Park, Jihye and Feng, Dawei and Zhou, Hong-Cai},
abstractNote = {A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.},
doi = {10.1021/ja5123528},
url = {https://www.osti.gov/biblio/1210607},
journal = {J. Am. Chem Soc.},
number = 4,
volume = 137,
place = {United States},
year = {Wed Feb 04 00:00:00 EST 2015},
month = {Wed Feb 04 00:00:00 EST 2015}
}
Works referenced in this record:
Mesoporous Materials for Drug Delivery
journal, October 2007
- Vallet-Regí, María; Balas, Francisco; Arcos, Daniel
- Angewandte Chemie International Edition, Vol. 46, Issue 40
Mesoporous Silica Nanoparticles for Intracellular Controlled Drug Delivery
journal, August 2010
- Vivero-Escoto, Juan L.; Slowing, Igor I.; Trewyn, Brian G.
- Small, Vol. 6, Issue 18
Silica-Based Mesoporous Organic–Inorganic Hybrid Materials
journal, May 2006
- Hoffmann, Frank; Cornelius, Maximilian; Morell, Jürgen
- Angewandte Chemie International Edition, Vol. 45, Issue 20
Mesoporous silica nanoparticles in biomedical applications
journal, January 2012
- Li, Zongxi; Barnes, Jonathan C.; Bosoy, Aleksandr
- Chemical Society Reviews, Vol. 41, Issue 7, p. 2590-2605
Chemical Strategies To Design Textured Materials: from Microporous and Mesoporous Oxides to Nanonetworks and Hierarchical Structures
journal, November 2002
- Soler-Illia, Galo J. de A. A.; Sanchez, Clément; Lebeau, Bénédicte
- Chemical Reviews, Vol. 102, Issue 11
Proteins in Mesoporous Silicates
journal, October 2008
- Hudson, Sarah; Cooney, Jakki; Magner, Edmond
- Angewandte Chemie International Edition, Vol. 47, Issue 45, p. 8582-8594
Current status and trends in enzymatic nanoimmobilization
journal, January 2014
- Cipolatti, Eliane P.; Silva, María José A.; Klein, Manuela
- Journal of Molecular Catalysis B: Enzymatic, Vol. 99
Inorganic Materials as Supports for Covalent Enzyme Immobilization: Methods and Mechanisms
journal, September 2014
- Zucca, Paolo; Sanjust, Enrico
- Molecules, Vol. 19, Issue 9
Understanding enzyme immobilisation
journal, January 2009
- Hanefeld, Ulf; Gardossi, Lucia; Magner, Edmond
- Chemical Society Reviews, Vol. 38, Issue 2, p. 453-468
Functionalization of Porous Carbon Materials with Designed Pore Architecture
journal, January 2009
- Stein, Andreas; Wang, Zhiyong; Fierke, Melissa A.
- Advanced Materials, Vol. 21, Issue 3, p. 265-293
Mesoporous Silica Nanoparticles for Drug Delivery and Biosensing Applications
journal, April 2007
- Slowing, I. I.; Trewyn, B. G.; Giri, S.
- Advanced Functional Materials, Vol. 17, Issue 8
Organic Functionalization and Morphology Control of Mesoporous Silicas via a Co-Condensation Synthesis Method
journal, November 2003
- Huh, Seong; Wiench, Jerzy W.; Yoo, Ji-Chul
- Chemistry of Materials, Vol. 15, Issue 22, p. 4247-4256
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
journal, September 2011
- Yoon, Minyoung; Srirambalaji, Renganathan; Kim, Kimoon
- Chemical Reviews, Vol. 112, Issue 2, p. 1196-1231
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks
journal, September 2011
- Wu, Haohan; Gong, Qihan; Olson, David H.
- Chemical Reviews, Vol. 112, Issue 2
Metal–organic frameworks for artificial photosynthesis and photocatalysis
journal, January 2014
- Zhang, Teng; Lin, Wenbin
- Chem. Soc. Rev., Vol. 43, Issue 16
Mesoporous metal–organic frameworks: design and applications
journal, January 2012
- Song, Lifang; Zhang, Jian; Sun, Lixian
- Energy & Environmental Science, Vol. 5, Issue 6
Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012
- Deng, H.; Grunder, S.; Cordova, K. E.
- Science, Vol. 336, Issue 6084, p. 1018-1023
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
journal, May 2008
- Hwang, Young Kyu; Hong, Do-Young; Chang, Jong-San
- Angewandte Chemie International Edition, Vol. 47, Issue 22, p. 4144-4148
Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in Diameter
journal, November 2007
- Park, Young Kwan; Choi, Sang Beom; Kim, Hyunuk
- Angewandte Chemie International Edition, Vol. 46, Issue 43
A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008
- Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
- Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
A Porous Coordination Copolymer with over 5000 m 2 /g BET Surface Area
journal, April 2009
- Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 131, Issue 12
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004
- Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline
- Angewandte Chemie International Edition, Vol. 43, Issue 46
Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010
- Furukawa, H.; Ko, N.; Go, Y. B.
- Science, Vol. 329, Issue 5990, p. 424-428
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010
- Yuan, Daqiang; Zhao, Dan; Sun, Daofeng
- Angewandte Chemie International Edition, Vol. 49, Issue 31, p. 5357-5361
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012
- Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
- Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
- Morris, William; Volosskiy, Boris; Demir, Selcuk
- Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
Extended and functionalized porous iron(iii) tri- or dicarboxylates with MIL-100/101 topologies
journal, January 2014
- Horcajada, Patricia; Chevreau, Hubert; Heurtaux, Daniela
- Chemical Communications, Vol. 50, Issue 52
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005
- Ferey, G.; Mellot-Draznieks, C.; Serre, C.
- Science, Vol. 309, Issue 5743, p. 2040-2042
How Can Proteins Enter the Interior of a MOF? Investigation of Cytochrome c Translocation into a MOF Consisting of Mesoporous Cages with Microporous Windows
journal, August 2012
- Chen, Yao; Lykourinou, Vasiliki; Vetromile, Carissa
- Journal of the American Chemical Society, Vol. 134, Issue 32
Ultrahigh porosity in mesoporous MOFs: promises and limitations
journal, January 2014
- Senkovska, Irena; Kaskel, Stefan
- Chemical Communications, Vol. 50, Issue 54
A Mesoporous Metal−Organic Framework with Permanent Porosity
journal, December 2006
- Wang, Xi-Sen; Ma, Shengqian; Sun, Daofeng
- Journal of the American Chemical Society, Vol. 128, Issue 51
Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand
journal, January 2010
- Zhuang, Wenjuan; Ma, Shengqian; Wang, Xi-Sen
- Chemical Communications, Vol. 46, Issue 29
Strain-Promoted “Click” Modification of a Mesoporous Metal–Organic Framework
journal, November 2012
- Liu, Chong; Li, Tao; Rosi, Nathaniel L.
- Journal of the American Chemical Society, Vol. 134, Issue 46
Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation
journal, January 2015
- Feng, Dawei; Liu, Tian-Fu; Su, Jie
- Nature Communications, Vol. 6, Issue 1
Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks
journal, December 2014
- Feng, Dawei; Wang, Kecheng; Wei, Zhangwen
- Nature Communications, Vol. 5, Issue 1
Postsynthetic modification of metal–organic frameworks
journal, January 2009
- Wang, Zhenqiang; Cohen, Seth M.
- Chemical Society Reviews, Vol. 38, Issue 5
Stepwise Synthesis of Metal–Organic Frameworks Replacement of Structural Organic Linkers
journal, July 2011
- Burnett, Brandon J.; Barron, Paul M.; Hu, Chunhua
- Journal of the American Chemical Society, Vol. 133, Issue 26, p. 9984-9987
Postsynthetic modification of metal–organic frameworks—a progress report
journal, January 2011
- Tanabe, Kristine K.; Cohen, Seth M.
- Chem. Soc. Rev., Vol. 40, Issue 2
Synthesis and characterization of isostructural cadmium zeolitic imidazolate frameworks via solvent-assisted linker exchange
journal, January 2012
- Karagiaridi, Olga; Bury, Wojciech; Sarjeant, Amy A.
- Chemical Science, Vol. 3, Issue 11, p. 3256-3260
Opening ZIF-8: A Catalytically Active Zeolitic Imidazolate Framework of Sodalite Topology with Unsubstituted Linkers
journal, October 2012
- Karagiaridi, Olga; Lalonde, Marianne B.; Bury, Wojciech
- Journal of the American Chemical Society, Vol. 134, Issue 45, p. 18790-18796
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012
- Kim, Min; Cahill, John F.; Fei, Honghan
- Journal of the American Chemical Society, Vol. 134, Issue 43
Postsynthetic ligand exchange as a route to functionalization of ‘inert’ metal–organic frameworks
journal, January 2012
- Kim, Min; Cahill, John F.; Su, Yongxuan
- Chem. Sci., Vol. 3, Issue 1, p. 126-130
Control over Catenation in Pillared Paddlewheel Metal–Organic Framework Materials via Solvent-Assisted Linker Exchange
journal, February 2013
- Bury, Wojciech; Fairen-Jimenez, David; Lalonde, Marianne B.
- Chemistry of Materials, Vol. 25, Issue 5
Tandem Postsynthetic Metal Ion and Ligand Exchange in Zeolitic Imidazolate Frameworks
journal, June 2012
- Fei, Honghan; Cahill, John F.; Prather, Kimberly A.
- Inorganic Chemistry, Vol. 52, Issue 7
Reversible Ligand Exchange in a Metal–Organic Framework (MOF): Toward MOF-Based Dynamic Combinatorial Chemical Systems
journal, April 2013
- Gross, Adam F.; Sherman, Elena; Mahoney, Sky L.
- The Journal of Physical Chemistry A, Vol. 117, Issue 18
Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals
journal, January 2013
- Hirai, Kenji; Chen, Kebi; Fukushima, Tomohiro
- Dalton Transactions, Vol. 42, Issue 45
Postsynthetic Exchanges of the Pillaring Ligand in Three-Dimensional Metal–Organic Frameworks
journal, March 2013
- Jeong, Seok; Kim, Dongwook; Song, Xiaokai
- Chemistry of Materials, Vol. 25, Issue 7
Opening Metal–Organic Frameworks Vol. 2: Inserting Longer Pillars into Pillared-Paddlewheel Structures through Solvent-Assisted Linker Exchange
journal, August 2013
- Karagiaridi, Olga; Bury, Wojciech; Tylianakis, Emmanuel
- Chemistry of Materials, Vol. 25, Issue 17
Enhancing Proton Conduction in a Metal–Organic Framework by Isomorphous Ligand Replacement
journal, January 2013
- Kim, SiRim; Dawson, Karl W.; Gelfand, Benjamin S.
- Journal of the American Chemical Society, Vol. 135, Issue 3
Stepwise Ligand Exchange for the Preparation of a Family of Mesoporous MOFs
journal, May 2013
- Li, Tao; Kozlowski, Mark T.; Doud, Evan A.
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11688-11691
Solvent-assisted linker exchange (SALE) and post-assembly metallation in porphyrinic metal–organic framework materials
journal, January 2013
- Takaishi, Shinya; DeMarco, Erica J.; Pellin, Michael J.
- Chemical Science, Vol. 4, Issue 4, p. 1509-1513
Tailored crystalline microporous materials by post-synthesis modification
journal, January 2013
- Valtchev, Valentin; Majano, Gerardo; Mintova, Svetlana
- Chem. Soc. Rev., Vol. 42, Issue 1
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement
journal, January 2014
- Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga
- Chem. Soc. Rev., Vol. 43, Issue 16
Substitution reactions in metal–organic frameworks and metal–organic polyhedra
journal, January 2014
- Han, Yi; Li, Jian-Rong; Xie, Yabo
- Chem. Soc. Rev., Vol. 43, Issue 16
Enhancing CO 2 Separation Ability of a Metal-Organic Framework by Post-Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates
journal, December 2013
- Hong, Dae Ho; Suh, Myunghyun Paik
- Chemistry - A European Journal, Vol. 20, Issue 2
Combinational Synthetic Approaches for Isoreticular and Polymorphic Metal–Organic Frameworks with Tuned Pore Geometries and Surface Properties
journal, February 2014
- Jeong, Seok; Kim, Dongwook; Shin, Sunyoung
- Chemistry of Materials, Vol. 26, Issue 4
Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks
journal, March 2014
- Karagiaridi, Olga; Bury, Wojciech; Mondloch, Joseph E.
- Angewandte Chemie International Edition, Vol. 53, Issue 18
Molecular Encapsulation beyond the Aperture Size Limit through Dissociative Linker Exchange in Metal–Organic Framework Crystals
journal, August 2014
- Morabito, Joseph V.; Chou, Lien-Yang; Li, Zhehui
- Journal of the American Chemical Society, Vol. 136, Issue 36
Interplay of Linker Functionalization and Hydrogen Adsorption in the Metal–Organic Framework MIL-101
journal, August 2014
- Szilágyi, Petra Ágota; Weinrauch, Ingrid; Oh, Hyunchul
- The Journal of Physical Chemistry C, Vol. 118, Issue 34
Cation exchange at the secondary building units of metal–organic frameworks
journal, January 2014
- Brozek, C. K.; Dincă, M.
- Chem. Soc. Rev., Vol. 43, Issue 16
Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation
journal, May 2014
- Liu, Tian-Fu; Zou, Lanfang; Feng, Dawei
- Journal of the American Chemical Society, Vol. 136, Issue 22
Generic Postfunctionalization Route from Amino-Derived Metal−Organic Frameworks
journal, April 2010
- Savonnet, Marie; Bazer-Bachi, Delphine; Bats, Nicolas
- Journal of the American Chemical Society, Vol. 132, Issue 13
Magnetite Nanoparticle-Induced Fluorescence Quenching of Adenosine Triphosphate–BODIPY Conjugates: Application to Adenosine Triphosphate and Pyrophosphate Sensing
journal, September 2013
- Yu, Cheng-Ju; Wu, Su-Mei; Tseng, Wei-Lung
- Analytical Chemistry, Vol. 85, Issue 18
Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery
journal, September 2009
- Taylor-Pashow, Kathryn M. L.; Della Rocca, Joseph; Xie, Zhigang
- Journal of the American Chemical Society, Vol. 131, Issue 40