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Title: Photochemical Nitrogen Conversion to Ammonia in Ambient Conditions with FeMoS-Chalcogels

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/ja512491v· OSTI ID:1210448
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Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001059
OSTI ID:
1210448
Journal Information:
Journal of the American Chemical Society, Vol. 137; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University
Country of Publication:
United States
Language:
English

References (49)

Substrate Interactions with the Nitrogenase Active Site journal March 2005
Mechanism of Molybdenum Nitrogenase journal January 1996
Mechanism of Mo-Dependent Nitrogenase journal June 2009
Intermediates Trapped during Nitrogenase Reduction of N⋮N, CH 3 −NNH, and H 2 N−NH 2 journal November 2005
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia journal December 2010
Unification of reaction pathway and kinetic scheme for N2 reduction catalyzed by nitrogenase journal March 2012
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco) journal September 2013
On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase journal September 2013
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors journal December 2009
Solar Fuels via Artificial Photosynthesis journal December 2009
Photocatalyst releasing hydrogen from water journal March 2006
Nitrogenase MoFe-Protein at 1.16 A Resolution: A Central Ligand in the FeMo-Cofactor journal September 2002
Assembly of Nitrogenase MoFe Protein † journal April 2008
Substrate Interaction at an Iron-Sulfur Face of the FeMo-cofactor during Nitrogenase Catalysis journal October 2004
How many metals does it take to fix N2? A mechanistic overview of biological nitrogen fixation journal November 2006
Electronic properties of single- and double-MoFe3S4 cubane-type clusters journal September 1983
Borohydride, Azide, and Chloride Anions As Terminal Ligands on Fe/Mo/S Clusters. Synthesis, Structure and Characterization of [(Cl 4 -cat)(PPr 3 ) MoFe 3 S 4 (X) 2 ] 2 (Bu 4 N) 4 and [(Cl 4 -cat)(PPr 3 )MoFe 3 S 4 (PPr 3 )(X)] 2 (Bu 4 N) 2 (X = N 3 - , BH 4 - , Cl - ) Double-Fused Cubanes. NMR Reactivity Studies of [(Cl 4 -cat)(PPr 3 ) MoFe 3 S 4 (BH 4 ) 2 ] 2 (Bu 4 N) 4 journal May 2006
Synthesis, structural characterization, and properties of new single and double cubanes containing the MoFe3S4 structural unit and molybdenum-bound polycarboxylate ligands. Clusters with a molybdenum-coordination environment similar to that in the iron-molybdenum cofactor of nitrogenase journal January 1995
Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase journal May 1984
ATP- and Iron−Protein-Independent Activation of Nitrogenase Catalysis by Light journal October 2010
Light-Driven Uncoupling of Nitrogenase Catalysis from ATP Hydrolysis journal September 2011
ATP-Uncoupled, Six-Electron Photoreduction of Hydrogen Cyanide to Methane by the Molybdenum–Iron Protein journal May 2012
Synthesis, structural characterization, and electronic properties of the tetraphenylphosphonium salts of the mixed terminal ligand cubanes Fe4S4(Et2Dtc)n(X)4-n2- (X = Cl-, PhS-) (n = 1, 2). Two different modes of ligation on the [Fe4S4]2+ core journal August 1985
Synthesis, molecular structure, and reactions of bis(tetraphenylphosphonium) hexakis(.mu.-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2[Fe4(SPh)6Cl4]. Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S4(Cl)2(SC6H5)2]2- "Cubane"-type clusters journal April 1982
Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex journal June 2013
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center journal December 2005
DINITROGEN FIXATION CATALYZED BY THE REDUCED SPECIES OF [Fe 4 S 4 (SPh) 4 ] 2− AND [Mo 2 Fe 6 S 8 (SPh) 9 ] 3− journal August 1982
Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand journal May 2011
Catalytic conversion of nitrogen to ammonia by an iron model complex journal September 2013
Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand journal June 2014
Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store journal October 2012
Photoinduced oxidative nitrogen fixation reactions on semiconductor suspensions journal December 1989
Photolysis of Water and Photoreduction of Nitrogen on Titanium Dioxide journal October 1977
New Avenues in Dinitrogen Fixation Research journal July 2001
Nitrogen Photofixation on Nanostructured Iron Titanate Films journal January 2003
Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction journal June 2013
A non-metal system for nitrogen fixation journal March 2004
Porous Semiconducting Gels and Aerogels from Chalcogenide Clusters journal July 2007
Spongy chalcogels of non-platinum metals act as effective hydrodesulfurization catalysts journal May 2009
Synthetic Analogues of the Active Sites of Iron−Sulfur Proteins journal October 2003
Biomimetic Multifunctional Porous Chalcogels as Solar Fuel Catalysts journal May 2011
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) journal January 1985
Handbook of Ion Chromatography book September 2004
Determination of ammonia and Kjeldahl nitrogen by indophenol method journal January 1976
The berthelot or indophenol reaction and its use in the analytical chemistry of nitrogen. A review journal January 1984
Interference in determination of ammonia with the hypochlorite-alkaline phenol method of Berthelot journal January 1982
Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9] journal May 1982
Ligand substitution reactions of iron–molybdenum–sulphur cubane-like cluster dimers; selective halide incorporation journal January 1980
Darstellung und Struktur von Na4Ge2S6 � 14H2O und Na4Sn2S6 � 14H2O journal November 1972

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Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
solar (photovoltaic)
solar (fuels)
photosynthesis (natural and artificial)
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electrodes - solar
defects
charge transport
spin dynamics
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materials and chemistry by design
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synthesis (novel materials)
synthesis (self-assembly)