skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Bi flux-dependent MBE growth of GaSbBi alloys

Journal Article · · Journal of Crystal Growth

The incorporation of Bi in GaSb1-xBix alloys grown by molecular beam epitaxy is investigated as a function of Bi flux at fixed growth temperature (275 °C) and growth rate (1 μm h⁻¹). The Bi content is found to vary proportionally with Bi flux with Bi contents, as measured by Rutherford backscattering, in the range 0 < x ≤ 4.5%. The GaSbBi samples grown at the lowest Bi fluxes have smooth surfaces free of metallic droplets. The higher Bi flux samples have surface Bi droplets. The room temperature band gap of the GaSbBi epitaxial layers determined from optical absorption decreases linearly with increasing Bi content with a reduction of ~32 meV/%Bi.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
EP/G004447/2; EP/H021388/1; AC02-05CH11231
OSTI ID:
1209828
Alternate ID(s):
OSTI ID: 1208644
Journal Information:
Journal of Crystal Growth, Journal Name: Journal of Crystal Growth Vol. 425 Journal Issue: C; ISSN 0022-0248
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English
Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

References (20)

Near infrared photoluminescence observed in dilute GaSbBi alloys grown by liquid phase epitaxy journal January 2012
Low- and high-energy photoluminescence from GaSb 1− x Bi x with 0 < x ≤ 0.042 journal November 2014
Composition dependence of photoluminescence of GaAs1−xBix alloys journal July 2009
Liquid phase epitaxy and photoluminescence characterization of p-type GaSb layers grown from Bi based melts journal January 1995
Surface morphology and Bi incorporation in GaSbBi(As)/GaSb films journal March 2014
Band gap of GaAs1−xBix, 0<x<3.6% journal June 2003
Mechanisms of droplet formation and Bi incorporation during molecular beam epitaxy of GaAsBi journal January 2013
Heterojunction bipolar transistors implemented with GaInNAs materials journal July 2002
Growth of GaSb 1−x Bi x by molecular beam epitaxy
  • Wang, Shumin; Saha Roy, Ivy; Shi, Peixiong
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 30, Issue 2 https://doi.org/10.1116/1.3672025
journal March 2012
Giant Spin-Orbit Bowing in GaAs 1 x Bi x journal August 2006
Kinetically limited growth of GaAsBi by molecular-beam epitaxy journal January 2012
Valence-band anticrossing in mismatched III-V semiconductor alloys journal January 2007
Growth and properties of GaSbBi alloys journal September 2013
Growth and characterization of GaSb bulk crystals with low acceptor concentration journal July 1996
Structural investigation of GaAs1−xBix/GaAs multiquantum wells journal September 2008
Effect of molecular beam epitaxy growth conditions on the Bi content of GaAs1−xBix journal May 2008
Theoretical and experimental studies of electronic band structure for GaSb 1− x Bi x in the dilute Bi regime journal August 2014
N incorporation in GaInNSb alloys and lattice matching to GaSb journal January 2013
Optical absorption by dilute GaNSb alloys: Influence of N pair states journal July 2013
Temperature dependence of the band gap of GaSb 1−x Bi x alloys with 0 < x ≤ 0.042 determined by photoreflectance journal December 2013

Similar Records

Bi-induced band gap reduction in epitaxial InSbBi alloys
Journal Article · Mon Nov 24 00:00:00 EST 2014 · Applied Physics Letters · OSTI ID:1209828

Bi-induced band gap reduction in epitaxial InSbBi alloys
Journal Article · Mon Nov 24 00:00:00 EST 2014 · Applied Physics Letters · OSTI ID:1209828

Microstructure and surface morphology of InAsSbBi grown by molecular beam epitaxy
Journal Article · Fri Sep 06 00:00:00 EDT 2019 · Journal of Applied Physics · OSTI ID:1209828