General features of the dissociative recombination of polyatomic molecules
Journal Article
·
· EPJ Web of Conferences
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Universite de Paris-Sud, Orsay (France). 2Laboratoire Aimé Cotton du CNRS; Univ. College London (United Kingdom). Dept. of Physics and Astronomy.
We discuss some aspects of a simple expression for the low-energy dissociative recombination cross section that applies when the recombination process is dominated by the indirect mechanism. In most previous applications, this expression has been applied to capture into vibrationally excited Rydberg states with the assumption that capture is always followed by prompt dissociation. Here we consider the dissociative recombination of larger polyatomic ions and electrons. More specifically, we consider capture into electronically core-excited Rydberg states, and begin to assess its potential importance for larger systems.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1209111
- Journal Information:
- EPJ Web of Conferences, Vol. 84; ISSN 2100-014X
- Publisher:
- EDP SciencesCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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