Materials Data on Na2PdF4 by Materials Project
Na2PdF4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Na1+ is bonded to six F1- atoms to form a mixture of distorted edge and corner-sharing NaF6 octahedra. The corner-sharing octahedra tilt angles range from 64–68°. There are a spread of Na–F bond distances ranging from 2.29–2.49 Å. Pd2+ is bonded in a square co-planar geometry to four F1- atoms. All Pd–F bond lengths are 2.01 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded to three equivalent Na1+ and one Pd2+ atom to form a mixture of distorted edge and corner-sharing FNa3Pd trigonal pyramids. In the second F1- site, F1- is bonded to three equivalent Na1+ and one Pd2+ atom to form a mixture of edge and corner-sharing FNa3Pd tetrahedra.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1207147
- Report Number(s):
- mp-3622
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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