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Title: Materials Data on Sm2TmS4 by Materials Project

Abstract

TmSm2S4 crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. Tm3+ is bonded in a 8-coordinate geometry to eight equivalent S2- atoms. There are four shorter (2.73 Å) and four longer (3.05 Å) Tm–S bond lengths. Sm+2.50+ is bonded to eight equivalent S2- atoms to form a mixture of distorted corner, edge, and face-sharing SmS8 hexagonal bipyramids. There are a spread of Sm–S bond distances ranging from 2.82–3.05 Å. S2- is bonded in a 6-coordinate geometry to two equivalent Tm3+ and four equivalent Sm+2.50+ atoms.

Authors:
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Contributing Org.:
MIT; UC Berkeley; Duke; U Louvain
OSTI Identifier:
1207139
Report Number(s):
mp-36150
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Resource Type:
Data
Resource Relation:
Related Information: https://materialsproject.org/citing
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; crystal structure; Sm2TmS4; S-Sm-Tm

Citation Formats

The Materials Project. Materials Data on Sm2TmS4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1207139.
The Materials Project. Materials Data on Sm2TmS4 by Materials Project. United States. https://doi.org/10.17188/1207139
The Materials Project. 2020. "Materials Data on Sm2TmS4 by Materials Project". United States. https://doi.org/10.17188/1207139. https://www.osti.gov/servlets/purl/1207139.
@article{osti_1207139,
title = {Materials Data on Sm2TmS4 by Materials Project},
author = {The Materials Project},
abstractNote = {TmSm2S4 crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. Tm3+ is bonded in a 8-coordinate geometry to eight equivalent S2- atoms. There are four shorter (2.73 Å) and four longer (3.05 Å) Tm–S bond lengths. Sm+2.50+ is bonded to eight equivalent S2- atoms to form a mixture of distorted corner, edge, and face-sharing SmS8 hexagonal bipyramids. There are a spread of Sm–S bond distances ranging from 2.82–3.05 Å. S2- is bonded in a 6-coordinate geometry to two equivalent Tm3+ and four equivalent Sm+2.50+ atoms.},
doi = {10.17188/1207139},
url = {https://www.osti.gov/biblio/1207139}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jul 20 00:00:00 EDT 2020},
month = {Mon Jul 20 00:00:00 EDT 2020}
}