PdHx entrapped in covalent triazine framework modulates selectivity in glycerol oxidation [Modulation of palladium activity and stability by a covalent triazine framework]

Chan-Thaw, Carine E.; Villa, Alberto; Wang, Di; Biroli, Alessio; Veith, Gabriel M; Thomas, Arne; Prati, Laura

doi:10.1002/cctc.201500055

Title: PdHx entrapped in covalent triazine framework modulates selectivity in glycerol oxidation [Modulation of palladium activity and stability by a covalent triazine framework]

Journal Article · Thu Jun 25 00:00:00 EDT 2015 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201500055· OSTI ID:1207042

Chan-Thaw, Carine E. ^[1]; Villa, Alberto ^[1]; Wang, Di ^[2]; Biroli, Alessio ^[3]; Veith, Gabriel M ^[4]; Thomas, Arne ^[5]; Prati, Laura ^[1]

Universita di Milano (Italy)
Fritz Haber Institute of the Max Planck Society, Berlin (Germany)
Istituto di Scienze e Tecnologie Molecolari del CNR, Milano (Italy)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Technische Univ. Berlin (Germany). Berlin Institute of Technology

The confinement of a Pd nanoparticle within a nitrogen-containing covalent triazine framework (CTF) material was investigated to understand if the highly tunable CTF chemistry mediates the Pd catalytic properties through an ensemble effect with the CTF nitrogen atoms or a confinement effect within the CTF pores. The results surprisingly demonstrate that the CTF stabilizes the formation of 2.6 nm PdHx particles within the pores. These PdHx particles are very active for the liquid phase oxidation of glycerol due to the in situ formation of H2O2 which catalytically promotes the initial C-C cleavage. In addition the confined particles are stable over many catalytic cycles whereas nanoparticles trapped outside of the pores loose activity rapidly. These results indicate that there is the potential to tune the CTF chemistry to significantly modify the chemistry of the catalytic metals.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1207042

Journal Information:: ChemCatChem, Vol. 7, Issue 14; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 27 works

Citation information provided by
Web of Science

References (30)

Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis Kuhn, Pierre; Antonietti, Markus; Thomas, Arne Angewandte Chemie International Edition, Vol. 47, Issue 18 https://doi.org/10.1002/anie.200705710	journal	April 2008
Ionothermalsynthese von porösen kovalenten Triazin- Polymernetzwerken Kuhn, Pierre; Antonietti, Markus; Thomas, Arne Angewandte Chemie, Vol. 120, Issue 18 https://doi.org/10.1002/ange.200705710	journal	April 2008
Template-Free Tuning of Nanopores in Carbonaceous Polymers through Ionothermal Synthesis Kuhn, Pierre; Forget, Aurélien; Hartmann, Jürgen Advanced Materials, Vol. 21, Issue 8 https://doi.org/10.1002/adma.200802304	journal	February 2009
Functional Materials: From Hard to Soft Porous Frameworks Thomas, Arne Angewandte Chemie International Edition, Vol. 49, Issue 45, p. 8328-8344 https://doi.org/10.1002/anie.201000167	journal	October 2010
Funktionsmaterialien: von harten zu weichen porösen Netzwerken Thomas, Arne Angewandte Chemie, Vol. 122, Issue 45 https://doi.org/10.1002/ange.201000167	journal	October 2010
Solid Catalysts for the Selective Low-Temperature Oxidation of Methane to Methanol Palkovits, Regina; Antonietti, Markus; Kuhn, Pierre Angewandte Chemie International Edition, Vol. 48, Issue 37 https://doi.org/10.1002/anie.200902009	journal	September 2009
Feste Katalysatoren für die selektive Niedertemperaturoxidation von Methan zu Methanol Palkovits, Regina; Antonietti, Markus; Kuhn, Pierre Angewandte Chemie, Vol. 121, Issue 37 https://doi.org/10.1002/ange.200902009	journal	September 2009
Covalent Triazine Framework as Catalytic Support for Liquid Phase Reaction Chan-Thaw, Carine E.; Villa, Alberto; Katekomol, Phisan Nano Letters, Vol. 10, Issue 2 https://doi.org/10.1021/nl904082k	journal	February 2010
Triazine-Based Polymers as Nanostructured Supports for the Liquid-Phase Oxidation of Alcohols Chan-Thaw, Carine E.; Villa, Alberto; Prati, Laura Chemistry - A European Journal, Vol. 17, Issue 3 https://doi.org/10.1002/chem.201000675	journal	November 2010
Influence of Periodic Nitrogen Functionality on the Selective Oxidation of Alcohols Chan-Thaw, Carine E.; Villa, Alberto; Veith, Gabriel M. Chemistry - An Asian Journal, Vol. 7, Issue 2 https://doi.org/10.1002/asia.201100565	journal	December 2011
Oxidation of alcohols with molecular oxygen on platinum metal catalysts in aqueous solutions Mallat, T.; Baiker, A. Catalysis Today, Vol. 19, Issue 2 https://doi.org/10.1016/0920-5861(94)80187-8	journal	March 1994
From Microporous Regular Frameworks to Mesoporous Materials with Ultrahigh Surface Area: Dynamic Reorganization of Porous Polymer Networks Kuhn, Pierre; Forget, Aurélien; Su, Dangsheng Journal of the American Chemical Society, Vol. 130, Issue 40 https://doi.org/10.1021/ja803708s	journal	October 2008
Catalytic hydrogenation of alkadienes and alkynes by palladium catalysts supported on heterocyclic polyamides Michalska, Zofia M.; Ostaszewski, Bogdan; Zientarska, Jolanta Journal of Molecular Catalysis A: Chemical, Vol. 129, Issue 2-3 https://doi.org/10.1016/S1381-1169(97)00212-4	journal	March 1998
Neutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene Hydrogenation Heckenroth, Marion; Kluser, Evelyne; Neels, Antonia Angewandte Chemie International Edition, Vol. 46, Issue 33 https://doi.org/10.1002/anie.200702199	journal	July 2007
Neutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene Hydrogenation Heckenroth, Marion; Kluser, Evelyne; Neels, Antonia Angewandte Chemie, Vol. 119, Issue 33 https://doi.org/10.1002/ange.200702199	journal	August 2007
Size Effects in Electronic and Catalytic Properties of Unsupported Palladium Nanoparticles in Electrooxidation of Formic Acid Zhou, Wei Ping; Lewera, Adam; Larsen, Robert The Journal of Physical Chemistry B, Vol. 110, Issue 27, p. 13393-13398 https://doi.org/10.1021/jp061690h	journal	July 2006
Interaction of Palladium Nano-Crystals with Hydrogen During PECVD Growth of Carbon Nanotubes Wunderlich, Wilfried; Tanemura, Masaki Advances in Solid State Physics https://doi.org/10.1007/978-3-540-44838-9_12	book	July 2003
Transformation of Pd → PdH0.7 nanoparticles inside mesoporous Zr-modified SiO2 films in ambient conditions Saha, Jony; Dandapat, Anirban; De, Goutam Journal of Materials Chemistry, Vol. 21, Issue 31 https://doi.org/10.1039/c1jm10207a	journal	January 2011
Hydrogen induced lattice expansion and crystallinity degradation in palladium nanoparticles: Effect of hydrogen concentration, pressure, and temperature Khanuja, Manika; Mehta, B. R.; Agar, Pragya Journal of Applied Physics, Vol. 106, Issue 9 https://doi.org/10.1063/1.3253733	journal	November 2009
In-situ TEM on (de)hydrogenation of Pd at 0.5–4.5bar hydrogen pressure and 20–400°C Yokosawa, Tadahiro; Alan, Tuncay; Pandraud, Gregory Ultramicroscopy, Vol. 112, Issue 1 https://doi.org/10.1016/j.ultramic.2011.10.010	journal	January 2012
The use of active carbon pretreated at 2173K as a support for palladium catalysts for hydrodechlorination reactions Bonarowska, Magdalena; Raróg-Pilecka, Wioletta; Karpiński, Zbigniew Catalysis Today, Vol. 169, Issue 1 https://doi.org/10.1016/j.cattod.2010.12.039	journal	July 2011
Au on MgAl2O4 spinels: The effect of support surface properties in glycerol oxidation Villa, Alberto; Gaiassi, Aureliano; Rossetti, Ilenia Journal of Catalysis, Vol. 275, Issue 1 https://doi.org/10.1016/j.jcat.2010.07.022	journal	September 2010
Electronic, steric, and temperature effects in the Pd(II)-biquinoline catalyzed aerobic oxidation of benzylic alcohols in water Buffin, Brian P.; Belitz, Nadine L.; Verbeke, Sara L. Journal of Molecular Catalysis A: Chemical, Vol. 284, Issue 1-2 https://doi.org/10.1016/j.molcata.2008.01.020	journal	April 2008
[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen Jurčík, Václav; Schmid, Thibault E.; Dumont, Quentin Dalton Transactions, Vol. 41, Issue 40 https://doi.org/10.1039/c2dt30133d	journal	January 2012
Well-defined alkylpalladium complexes with pyridine-carboxylate ligands as catalysts for the aerobic oxidation of alcohols Melero, Cristóbal; Shishilov, Oleg N.; Álvarez, Eleuterio Dalton Transactions, Vol. 41, Issue 46 https://doi.org/10.1039/c2dt31728a	journal	January 2012
Influence of gold particle size on the aqueous-phase oxidation of carbon monoxide and glycerol Ketchie, W.; Fang, Y.; Wong, M. Journal of Catalysis, Vol. 250, Issue 1 https://doi.org/10.1016/j.jcat.2007.06.001	journal	August 2007
From Renewable to Fine Chemicals Through Selective Oxidation: The Case of Glycerol Prati, Laura; Spontoni, Paolo; Gaiassi, Aureliano Topics in Catalysis, Vol. 52, Issue 3 https://doi.org/10.1007/s11244-008-9165-1	journal	January 2009
Carbon-Supported Gold Nanocatalysts: Shape Effect in the Selective Glycerol Oxidation Wang, Di; Villa, Alberto; Su, Dangsheng ChemCatChem, Vol. 5, Issue 9 https://doi.org/10.1002/cctc.201200535	journal	November 2012
Oxidation of Glycerol to Glycolate by using Supported Gold and Palladium Nanoparticles Sankar, Meenakshisundaram; Dimitratos, Nikolaos; Knight, DavidâW. ChemSusChem, Vol. 2, Issue 12 https://doi.org/10.1002/cssc.200900133	journal	December 2009
Au NPs on anionic-exchange resin as catalyst for polyols oxidation in batch and fixed bed reactor Villa, Alberto; Chan-Thaw, Carine E.; Prati, Laura Applied Catalysis B: Environmental, Vol. 96, Issue 3-4 https://doi.org/10.1016/j.apcatb.2010.03.017	journal	June 2010

Cited By (9)

Covalent Triazine-based Frameworks-Tailor-made Catalysts and Catalyst Supports for Molecular and Nanoparticulate Species Artz, Jens ChemCatChem, Vol. 10, Issue 8 https://doi.org/10.1002/cctc.201701820	journal	March 2018
Sulfur‐Linked Covalent Triazine Frameworks Doped with Coordinatively Unsaturated Cu(I) as Electrocatalysts for Oxygen Reduction Iwase, Kazuyuki; Kamiya, Kazuhide; Miyayama, Masaru ChemElectroChem, Vol. 5, Issue 5 https://doi.org/10.1002/celc.201701361	journal	January 2018
Effect of Building Block Transformation in Covalent Triazine‐Based Frameworks for Enhanced CO ₂ Uptake and Metal‐Free Heterogeneous Catalysis Jena, Himanshu Sekhar; Krishnaraj, Chidharth; Schmidt, Johannes Chemistry – A European Journal, Vol. 26, Issue 7 https://doi.org/10.1002/chem.201905163	journal	December 2019
AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions Bonincontro, Danilo; Lolli, Alice; Villa, Alberto Green Chemistry, Vol. 21, Issue 15 https://doi.org/10.1039/c9gc01283d	journal	January 2019
Recent Advancements in the Synthesis of Covalent Triazine Frameworks for Energy and Environmental Applications Zhang, Ying; Jin, Shangbin Polymers, Vol. 11, Issue 1 https://doi.org/10.3390/polym11010031	journal	December 2018
Development of Covalent Triazine Frameworks as Heterogeneous Catalytic Supports Tahir, Norini; Krishnaraj, Chidharth; Leus, Karen Polymers, Vol. 11, Issue 8 https://doi.org/10.3390/polym11081326	journal	August 2019
Playing with covalent triazine framework tiles for improved CO ₂ adsorption properties and catalytic performance Tuci, Giulia; Iemhoff, Andree; Ba, Housseinou Beilstein Journal of Nanotechnology, Vol. 10 https://doi.org/10.3762/bjnano.10.121	journal	January 2019
Effect of Building Block Transformation in Covalent Triazine‐Based Frameworks for Enhanced CO 2 Uptake and Metal‐Free Heterogeneous Catalysis Jena, Himanshu Sekhar; Krishnaraj, Chidharth; Schmidt, Johannes Chemistry – A European Journal https://doi.org/10.1002/chem.201903926	journal	December 2019
Tailored N-Containing Carbons as Catalyst Supports in Alcohol Oxidation Campisi, Sebastiano; Marzorati, Stefania; Spontoni, Paolo Materials, Vol. 9, Issue 2 https://doi.org/10.3390/ma9020114	journal	February 2016

Similar Records

Sacrificial Synthesis of Supported Ru Single Atoms and Clusters on N‐doped Carbon Derived from Covalent Triazine Frameworks: A Charge Modulation Approach

Journal Article · Sun Dec 20 00:00:00 EST 2020 · Advanced Science · OSTI ID:1207042

Zhang, Zihao; Yao, Siyu; Hu, Xiaobing; +8 more

Influence of fluorination on CO₂ adsorption in materials derived from fluorinated covalent triazine framework precursors

Journal Article · Fri Jul 05 00:00:00 EDT 2019 · Journal of Materials Chemistry. A · OSTI ID:1207042

Yang, Zhenzhen; Wang, Song; Zhang, Zihao; +7 more

Highly Perfluorinated Covalent Triazine Frameworks Derived from a Low-Temperature Ionothermal Approach Towards Enhanced CO₂ Electroreduction

Journal Article · Tue Sep 28 00:00:00 EDT 2021 · Angewandte Chemie (International Edition) · OSTI ID:1207042

Suo, Xian; Zhang, Fengtao; Yang, Zhenzhen; +8 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: PdHx entrapped in covalent triazine framework modulates selectivity in glycerol oxidation [Modulation of palladium activity and stability by a covalent triazine framework]

Citation Formats

References (30)

Cited By (9)

Similar Records

Related Subjects